Monster: Johan Liebert, the title character, is always perfectly dressed, well-spoken, blends in perfectly with high society and is a smart intellectual.
The Major from Hellsing is a textbook example: he dresses immaculately, always ready for A Glass of Chianti, is well-read, refined, eloquent, frighteningly intelligent, but... He's insane and has "EVIL" written on him in two-foot letters. In blood.
Creed from Black Cat is definitely shown to be one of the more "cultured" characters in the series. He appears to be the only character in the series that bothers taking a bath (which is filled with rose petals, no less), dresses in sleek, black leather, drinks A Glass of Chianti (with a rose in it), speaks in a much more formal manner, plays the organ well, is skilled with large scale oil painting, carving gold statues, etc.
M'Quve from Mobile Suit Gundam is a ruthless Smug Snake under the orders of PrincessKyciliaZabi, whom he's fiercely devoted to. He's also an extremely cultured, polite, soft-spoken man who adores art and souvenirs. His last thoughts as he died in battle were of both his Princess and an old porcelain vase that he wanted to offer to her as a gift.
Backstory claims the same about Gihren Zabi, who apparently enjoys dancing, opera, horticulture and various other types of arts and sciences. For a guy who fancied himself as Hitler's reincarnation, Gihren was as cultured as he was (supposedly) intellectual.
Paptimus Scirocco of Mobile Suit Zeta Gundam carries himself this way, being well mannered and courteous to all those around him (even those he despises). He also has a thing for old traditions, such as signing contracts in blood (not that he finds them binding, unlike his superior Jamitov Hymen).
Mashemyre Cello of Mobile Suit Gundam ZZ thinks of himself as this, but in reality he's a bumbling idiot with a thing for roses and an obsession with Haman Karn.
Treize Kushrenada of Mobile Suit Gundam Wing was the poster child of this trope during his time as a villain. His cultured elements are covered in the Cultured Badass section, while his wicked elements constitute his leading the Specials (essentially the State Security of Wing) in subjugating the colonies and parts of the Earth, his indirectly assassinating the UESA leadership when they were on the verge of a peace settlement and then leading OZ in conquering the Earthsphere in the name of their Romefellar masters. Naturally he has a Face-Heel Turn later on, when he realizes that his actions only made the world turn for the worst, but for a time Treize was a particularly ruthless Gundam villain.
Crocodile from One Piece. Drinks wine while the Straw Hats are imprisoned (in addition to a No, Mr. Bond, I Expect You to Dine scene with Vivi), names his criminal organization after Renaissance architecture, and dresses in a fashion akin to a mafia ringleader.
Black Butler's Sebastian Michaelis is the perfect butler: he can cook the finest cuisine from any country, perform beautifully on the violin, and recite quotes from virtually any body of literature. Oh, by the way, he's a demon.
Since this is from manga and anime, to be clear: drag-your-soul-to-Hell demon, not "generic supernatural creature" demon.
Aizen of Bleach uses very long words, even longer plans and as a scientist is second only to Urahara (which continuously annoys him, and somewhat justified too, as Urahara plays a vital role in his defeat). As well, during his time in Soul Society, he was an instructor in calligraphy.
Proist, the eventual Big Bad of the 2005 Gaiking series. She has a thing for Antonin Dvorak's New World Symphony—spoken of its 2nd movement: “While the culture of the Earth is barbaric, this song by that composer Dvorak is magnificent.” When things get serious, she acknowledges that this movement is no longer adequately suited to the moment, and starts up the more dramatic 4th movement. Her personal Eldritch Abomination is even named after the composer himself. Also, she arranges meetings with rebellious subordinates during teatime, and coolly responds to having a reckless (and unexpected) guest draw a sword on her by asking him how many sugars he wants in his tea.
Invoked by Yahiro Saiga of Special A. He's not actually thatbad, but with his love of opera, fine clothing and dining he certainly looks like an example.
Adolf K. Weissman from K, wears fancy-looking clothes and frequently dances around his room with an inanimate woman wearing a fox mask. The few glimpses we get of him suggest he is quite unhinged and malevolent. This is later revealed to have been the Colorless King controlling him at the time, and not his own actions.
Shogo Makishima, the sociopathic villain from Psycho-Pass, is seen reading Shakespeare and 1984 in his spare time; and he's very knowledgeable in philosophy, music and literature.
Frieza uses very polite, eloquent language rather than the more tough-talking style of most of the other villains in both the original Japanese version of Dragon Ball Z and in the dubbed version of Dragon Ball Kai. He also view most problems and situations in an intellectual and sophisticated manner and in one scene he can be seen even drinking wine.
The Top of The Flash's Rogues Gallery is an incredible genius who is, among other things, a wine connoisseur. This has made him a pariah among the other, more blue-collar Rogues.
The Fiddler, as well, was a classically trained violinist and musical virtuoso who sometimes claimed he was Doing It for the Art.
This was lampshaded once when Deadshot asked him why, if he was classically trained and had a genuine Strad violin, why he called himself the Fiddler, like "...an inbred hick".
Weather Wizard also fancies himself something of an intellectual.
The Shade. A Victorian era gentleman who has stopped aging thanks to his darkness superpowers, he is droll, well-dressed, cultivates roses, and enjoys fine art and food. Though he only did crime because he was Bored With Immortality, and eventually did a Heel-Face Turn.
Doctor Doom had five Rembrandts. Then he had one burned because he didn't like it.
V is a Villain Protagonist with a good cause, and he applies this trope to himself, quoting the line, "Please allow me to introduce myself, I'm a man of wealth and taste," from the Rolling Stones's "Sympathy for the Devil." He plays the piano, writes his own songs, grows roses, has an enormous vocabulary (most of it starting with "V")...
He has a reason - his art collection is 'rescued' from the Culture Police, and his over-eloquent theatrics are meant to be a contrast to the bland and menacing fascist government.
Vandal Savage is an astute intellectual who is thousands of years old. He also hunts down his descendants so he can eat them.
The Penguin, one of Batman's major villains is usually portrayed as being this. As are Ra's al Ghul and the Scarecrow.
The Penguin character was deconstructed in Batman Returns, where he's revealed to be the grotesquely inbred sire of a wealthy family who dumped him in the river and left him for dead when he was still a baby. Although obviously intelligent and certainly no stranger to fine clothes, this version of the Penguin is quite vulgar, with thuggish manners and distasteful sexual appetites. The character is also portrayed in this manner in the Arkham City video game. He clearly thinks he's Wicked Cultured though.
Sin City: Manute speaks in a very polite and eloquent manner. He seems to have little regard for hookers and "the dregs of Sin City". When Dwight implies Manute's only serving the Big Bad because she slept with him (her usual MO), Manute finds the suggestion vulgar and insulting. Mere sex is no reason to follow anyone.
Magneto in Ultimate X-Men. Despite his disdain for humanity, he has his minions steal all of the greatest works of art that they can before he begins a scheme intended to wipe out the entire human race, reasoning that humanity's only worthwhile creations (to paraphrase his terminology) deserve better than to be destroyed with their makers.
Lord Cedric from W.I.T.C.H. has two passions: ancient books and deception. Fittingly, his home on Earth doubles as a bookshop with a preference for ancient books and he has many contacts among booksellers, and has deceived people from the very first story until his death, with one victim falling in his deception in spite of being forewarned to not trust him (Cedric even described exactly what the poor victim was thinking).
The eponymous protagonist of Diabolik is a mercyless murderer and an Impossible Thief, but is also a fine collector of arts, has created a collection from his most beautiful loots, and took offense at Ginko thinking he'd steal a priceless but objectively horrible golden statue.
One scene in Mortalitydeliberately invoked this trope for ProfessorMoriarty, with a glass of wine in hand (which he fractures because of his angry grip on it). Overall, the fic paints him as very upper-class and as intellectual as he is meant to be.
Colonel Moran gets his moments as well, particularly at the Tankerville Club.
Jewel Of Darkness: At the climax of the Jump City Arc, Midnight takes the time before initiating her master plan to toast it with her minions. And a later flashback shows her attending a production of "Faust" with Slade and reading "The Count of Monte Cristo" while waiting for it to start.
Hivefled's portrayal of the Grand Highblood has him as this trope; he's far more eloquent and less foul-mouthed than Gamzee, capable of carrying out elaborate plans, deeply religious, always very polite when Leaning on the Fourth Wall, and a great painter. His best work was painted in the blood of a lover he murdered, and when speaking to the readers he implies he plans to rape and torture them to death in the same way he did two and a half thousand teenage trolls and attempted to do to his own children.
The Silence of the Lambs Hannibal Lecter typifies this trope like no other; a cultured and refined genius as well as a homicidal cannibal. Some of his more cultured actions include his charcoal drawings of Florence that he uses to decorate his cell (done from memory), killing and eating an untalented flautist in the Baltimore Symphony Orchestra to improve its sound, and listening to Bach's "Goldberg Variations" while removing a man's face. His conversations are rife with references to classical works from Shakespeare to Marcus Aurelius, and much more. Wine-lovers note how his "nice Chianti" is a rustic choice for such a sophisticate (only in the film; in the book it was an Amarone). This combined with his mispronunciation of the name suggest to some that he's being facetious and is further mocking Agent Starling's rustic roots.
Se7en: John Doe. He uses the works of William Shakespeare, Milton, Chaucer, Dante, the Marquis de Sade and St. Thomas Aquinas, among others, as inspirations for his crimes.
Magneto always enjoy a good game of chess with Xavier or listening to classical music.
Sebastian Shaw in the opening of X-Men: First Class. He assures a terrified boy (who would grow up to be Magneto) that he doesn't share the ridiculous Nazi prejudice against Jews. For some reason, the boy doesn't seem to be reassured. Later in the scene, the camera shifts, and we see that Shaw's office includes a torture chamber...
The Pin in the neo-noir film Brick. Something of a subversion, as outside of his basement office, he's clearly quite shy and eager to be liked.
Alex of A Clockwork Orange - the only thing he loves more than rape and "the old ultra-violence" is Beethoven's music. His gang, and youth culture in general, garb themselves in perverted trappings of aristocracy, such as top hats, walking sticks and codpieces.
Cutler Beckett, in contrast to the monstrous Hector Barbossa and Davy Jones, presents himself as a cultured villain, sipping tea aboard his ship before going into battle.
In the first movie, Barbossa himself affects this in contrast to his crew, when he asks Elizabeth not to use long words, but then responds to her demand that they leave with "I'm disinclined to acquiesce to your request. Means 'no'." As well, in the fourth movie, Barbossa quotes William Ernest Henley's Invictus when describing his cutting off his leg to escape from Blackbeard's trap.
Davy Jones also happens to be a passionate musician, venting his centuries of anger and bitterness and lamenting the betrayal of his "lost" love by playing his steam-blowing pipe organ at regular intervals.
Jack Sparrow has also proven to be relatively cultured on occasion (though his wickedness varies). For example, during his encounter with Koehlner and Twigg in the Fort Charles prison, Jack makes a reference to Dante's Divine Comedy when commenting on the two pirates' "fortunes". Also, he's said to have learned his swordsmanship from an Italian master, and so knows the classical nuances of fencing (thus his commentary to Will Turner during their duel).
The Merovingian from The Matrix Reloaded. He owns a restaurant, an S&M fetishist nightclub, lives in a grand mansion, and has a beautiful wife. His manner is that of a smug Frenchman and he effortlessly rebuffs the heroes upon their first encounter. As he points out during their first meeting, even swears in French sound beautiful.
Sigfried in the Get Smart movie fits this very well (whereas the original in the TV show was Affably Evil). He is essentially The Mean Brit as a Bond villain and is paradoxically, calm and cultured while being Chaotic Evil. This is particularly apparent at the end when he is in his car listening to and conducting the same music being played by an orchestra in which he has placed a bomb which will kill the president and everyone else inside.
Rotti Largo from Repo! The Genetic Opera has a love for Italian culture, dressing in suits from Milan and hosting his own opera.
Casanova Frankenstein, in Mystery Men, who is so smart and sophisticated that Captain Amazing asks him how to pluralize words while they are bantering.
Amazing: Well, we've always been each other's greatest nemesises... nemesisi... nemesi... what's the plural on that?
Count Dooku, who notably uses a fencing grip on his lightstaber, and actually salutes Yoda with it at the start of their duel.
His master Palpatine/Darth Sidious has shades of this as well — Ian McDiarmid, who played him, has said that Palpatine's only redeeming feature is that he is a patron of the arts, particularly weird alien operas.
Scanners: Darryl Revok has a really nice apartment with some modern art here and there.
Many, manyJames Bond villains have taste and class, often used to contrast against the somewhat less (though still quite) cultured secret agent:
Karl Stromberg from The Spy Who Loved Me and Hugo Drax from Moonraker don't skimp on the decor, as we can see from the latter's fancy villa◊. Imported, brick by brick, from France to California (he bought the Eiffel Tower too, but was refused an export permit). The former is often seen sitting around his dining table in his underwater mansion, eating expensively and listening to Bach.
General Chang from Star Trek VI: The Undiscovered Country is definitely this. The man could barely get through a given day without gratuitous Shakespeare quoting; even when trying to smash the Enterprise.
John Harrison/Khan in Into Darkness is quite well spoken and even paraphrases Moby-Dick when he beams Kirk, Carol and Scotty off the Vengeance.
Harrison: No ship should go down with out her captain.
Gordon Gekko in Wall Street wears trend-setting, custom-made clothes, collects art, and dates an interior decorator.
Nearly every character portrayed by German actor Sky du Mont (e.g. Sandor Szavost in Stanley Kubrick's movie Eyes Wide Shut).
Klytus from the 1980 Flash Gordon manages this by speaking in the arch, refined tones of Peter Wyngarde, and holding a hankerchief to his face during an execution.
Subverted by Otto in A Fish Called Wanda, an assassin who believes himself to be well-educated and tasteful, but is in fact a thuggish moron.
Agent Stansfield in Leon/The Professional has a love of classical music and hard drugs.
Stansfield: You're a Mozart fan. I love him too. I looooove Mozart! He was Austrian, you know. But for this kind of work, (imitates playing the piano) he's a little bit light. So I tend to go for the heavier guys. Check out Brahms. He's good too. (proceeds to slaughter the family)
Col. Hans Landa of Inglourious Basterds is witty and articulate in at least four languages, often engages in philosophic debates with his quarries, and prides himself on having a deep understanding of the human psyche. One of the first things he does in the movie is massacre a family of Jewish people.
Christopher Lee as Lord Summerisle in The Wicker Man. He plays the piano, lives in a castle, sings folk songs, is the go-to guy on local history, wears nice suits...
''"A heathen, conceivably, but not - I hope - an unenlightened one.
In The Abominable Dr. Phibes, the Villain Protagonist is an award-winning concert organist, holds two degrees from prestigious European universities (including one in theology), and enjoys composing poetry and ballroom dancing to music supplied by the clockwork band he has built. He's utterly mad and spends the movie brutally murdering a whole bunch of innocent people.
In The Film of the SeriesS.W.A.T., the tipoff to the identity of The Mole is that, while the other officers take their leisure playing with their children or drinking beer and watching TV, he spends it drinking champagne in a restaurant with a sommelier.
Cobb from Following is well-dressed, witty, urbane, and philosophical about the fact that he's a career burglar.
Cobb: You take it away to show them what they had.
Benedict, The Dragon in Last Action Hero, is much more cultured than his mobster boss and frequently irritated by the latter's ignorance.
Moriarty in Sherlock Holmes: A Game of Shadows, in addition to being a mathematician, chess player and former boxer, is portrayed as a fan of opera, listening to a phonograph of Schubert whilst torturing Holmes with a meat hooknote The song in question was Die Forelle (The Trout), which Moriarty used for an elaborate analogy of the rivalry between him and Holmes (i.e. he thinks of himself as the fisherman and Holmes the trout). Thus the meat hook.. His Dragon, Moran, also qualifies, as he expresses disappointment when one of Moriarty's schemes gets in the way of his plans to see a performance of Don Giovanni.
Justin Hammer in Iron Man 2 is clearly trying to do this to impress Ivan Vanko. Like with everything else, he just winds up looking like a doofus.
Ulysses Diello the treacherous valet turned spy in 5 Fingers (1952) convinces his German controller that he is an English gentleman of the most elegant and decadent sort.
Loki in The Avengers shows great knowledge of Midgardian history, noting that humans love to follow strong leaders, you know, like Hitler. In Thor: The Dark World he's shown to be an avid reader. His mother Frigga sends him books to his prison cell to appease him, you know, like Hitler except with books not countries.
Veteran character actor Terry-Thomas' roles were almost always cultured, upper-class rogues and scoundrels.
He's not really suave, but the psychopathic killer of the terrible 80s horror movie "Mortuary" listens to classical music.
Most Forsaken in The Wheel of Time fit this trope perfectly. Not surprising, given that they are from a much more civilized time where they were among the highest ranked scholars and wizards in the world. Ishamael/Moridin is probably the most obvious; a handsome, well-dressed man who lives in his own elegant palace in the middle of the Blight and is fond of chatting metaphysics with his Archenemy in-between attempts to kill each other, all in spite of being a nihilistic Omnicidal Maniac. Asmodean (a passionate musician who was already a renowned performer as a child) and Graendal (a former psychologist who actually has fairly sophisticated tastes, as much as she'd like you to think she's a vapid hedonist) are up there too.
Lung Tien Lien from the Temeraire series. She is an albino dragon the size of two houses, but she would much rather discuss your doom over a cup of tea after a pleasant afternoon of reciting poetry.
Marquise Isabelle de Merteuil from Les Liaisons dangereuses. She's obviously the most cultured, clever and deepest character of the book (Valmont also counts, but he's her villain sidekick). Her choice to pursue a career in evilness was heavily influenced by the philosophers she read. She would probably protect intellectuals and free speech if she wasn't too occupied ruining other persons' lives.
Headmaster Maximilian Nero of H.I.V.E. fits this, believing that evil should always be intelligent in its design and stylish in its execution.
Left Behind seems to be aiming for this with Nicholae Carpathia.
Havelock Vetinari of Discworld, though he's more of a ruthless pragmatist than evil. He's extremely intelligent and cultured, but also an ascetic with no vices. In particular, his hobby of reading the equivalent of classical music, because actual instruments are just too unrefined. Vetinari was also a trained Assassin, which, on the Discworld, is a gentleman's calling.
The Dragon King of Arms in Feet of Clay. A vampire over five hundred years old, he was in charge of Ankh-Morpork's heraldry. As Vimes points out, from a vampire's point of view this is much like following the pedigree of one's pets.
Captain Nemo of Twenty Thousand Leagues Under the Sea conducted most of his discussions with Dr. Arronax in his fantastic library, decorated with the finest original and replica art, a catalog of priceless biological specimens, and his massive organ, on which he played music by the foremost composers. Only a borderline example, because Nemo isn't entirely a villain.
In William King's Warhammer 40,000Space Wolf novel Wolfblade, when Torin fills Ragnor in on the ambitions and conflicts of the Naviagator Houses, he observes of one particularly ambitious and ruthless one:
a great patron of the arts — all the great lords are.
Captain Hook of Peter Pan is generally portrayed as cultured, and often something of an Anti-Villain. Peter, by contrast, is a feral tyrant, ruling by whim but setting strict rules for the Lost Boys. (In some adaptations this is taken farther: Peter is incapable of learning or memory, and murders the Lost Boys if they don't follow his rules.)
Perturabo, in Angel Exterminatus, proves to have a surprising amount of classical education and a remarkable gift for designing beautiful architecture, given that his Legion's combat specialisation is to sit in a muddy trench hurling bombs at buildings. He's quite bitter about how everyone just thinks of him as Siege Guy and assume he has no appreciation for culture.
Several Dean Koontz villains are (or fancy themselves as) this.
The Phantom of the Opera. Despite being a homicidal maniac, he has decidedly highbrow hobbies. This is carried over to the Lloyd-Webber show.
In Kim Newman's Swellhead, part of the Diogenes Club series, there's a heavy subversion; the villain is massively intelligent and knows everything, but a) his cultural leanings are decidedly cheesy (he likes Burt Bacharach, and has muzak versions of MOR songs playing in his Elaborate Underground Base) and b) he is actually defeated by his lack of knowledge of the younger generation's pop culture. Not "as a consequence of"; By. After failing to name the singer who had a hit with "I Should Be So Lucky", his head explodes. Or, if you prefer, goes pop.
Lucius Malfoy from Harry Potter. He's well dressed and well spoken, and he's also implied to be heavily involved in wizarding cultural affairs (on the board of Hogwarts, donates to St. Mungo's). And damn, is his pimp cane◊ awesome or what?
Lord Voldemort, especially in his younger years. His teachers saw him as an eloquent, brilliant and polite student. In truth, he used his refined manners to manipulate people (his behaviour towards Hepzibah Smith is a wonderful example). And when he wanted to duel with Harry in "The Goblet of Fire"... He insistet that two opponents should bow before each other.
A less morally ambiguous example is Smug SnakePrince Xizor. He's the head of the vast crime syndicate Black Sun, he sits at the Emperor's feet closer than anyone but Vader, co-owns and dines at the most exclusive restaurant on Coruscant, and in general is just fabulously wealthy and lets it show. There's mention that he forgave some debtor when presented with a thousand-year-old miniature tree, and he muses that values it more than rare gems and would not give it up even if he had to sell the rest of his finincial and criminal empire.
Trioculus. In addition to the pseudo-Latin name, he actually interrupts his pursuit of our heroes to go hunting.
Jerec of Jedi Knight: Dark Forces II is revealed to enjoy classical music from around the galaxy, even pieces written by traitors to the empire.
The Imperial war criminal Kardue'sai'Malloc (the horned alien in the Mos Eisley cantina) is an obsessive collector of music: not only does he own a treasure-trove of rare recordings, but he spent many years following some of the greatest musicians of the age in the hope of attending a performance, and only settled on Tatooine when the artist he'd been hoping to witness there was arrested and executed. After being captured by Boba Fett, Malloc ensures that his collection is donated to a museum.
Most/many of Anne Rice's vampires are this. Lestat, at least in the Interview with the Vampire film, twice puts blood in a glass and offers it to Louis, Armand loves his sparkly rings, Claudia is a well-read, impeccably dressed child who plays Mozart and Liszt. Marius takes this to slightly squicky levels, being a wealthy painter in Renaissance Venice who just happens to keep a sort of harem of pubescent boys. Gabrielle, while spending most of her immortality wandering around in jungles, was a marquise and the only literate member of her provincial noble pre-Revolutionary French noble family.
Rice even explores this through Lestat's voice in The Vampire Lestat, as he muses that it's not surprising Louis thought he was lying about his Blue Blood: Louis was a member of the American nouveau riche who put on what they imagined were aristocratic airs, while Lestat came from "a long line of Barons who threw chicken bones over their shoulders" and slept with their hunting dogs.
Rice has lots of fun with this. For all his sophistication, Lestat learned English from reading cheesy, low-brow pulp detective dime novels, and loves slang because of it. He describes his own way of speaking as Sam Spade-ish.
Hannibal Lecter is depicted as a highly intelligent and cultured man, with refined ("even rarefied", as the novel Hannibal puts it) tastes. He shops at exclusive high-end stores and wouldn't miss a good opera for the world.
He prefers to eat the rude.
Blood Meridian: Judge Holden is an erudite, patient, eloquent, philosophizing, multi-talented, poly-lingual, murdering, manipulative, megalomaniac pedophile.
In Vladimir Nabokov's Lolita, Humbert Humbert is a well-educated, cultured professor of French poetry. He is also a pedophile who marries a woman planning to kill her so he can molest her 12-year-old daughter.
A few of Redwall's less barbaric villains; Tsarmina Greeneyes, Ungatt Trunn, Ublaz Madeyes, Vilaya, Vilu Daskar and Badrang come to mind.
Several characters from The Count of Monte Cristo, starting with the Count himself, who has impeccable taste and if not an outright villain, is a ruthless Well-Intentioned Extremist. There's also the bandit leader, Luigi Vampa, who is a polite, nice guy who reads Caesar's Commentaries for fun. He's also a strong believer in punctuality, and if a ransom is not paid on time, he will calmly stab the kidnappee to death or shoot them in the head. And there's also Benedetto, a young career criminal who has no trouble posing as a cultured aristocrat.
The robot Erasmus in Legends of Dune believes himself to be cultured, while at the same time performing inhumane experiments on his human slaves. Only one human has the guts to tell him that his music sucks and his attempts to be civil are not fooling anyone. While he initially enjoys these arguments, he eventually gets fed up and throws her baby from a high balcony.
In Night Watch, Zavulon (or Zabulon) always appears wearing a suit and rarely shows anger. However, he is a scheming bastard who would be considered an outright villain if not for this world's Grey and Gray Morality. His Dusk appearance, however, is that of a demon (the author even felt the need to mention his spiked penis). The Movie version shows him more as an anarchist wearing black leather and a bandana.
The Dresden Files' Nicodemus, the host and compatriot of a fallen angel, definitely qualifies. He's the scariest and evilest creature in a series full of scary, evil creatures who far outstrip him in raw power, but he does it with impeccable taste.
Gentleman Marcone comes off as this, but it will likely never be confirmed because he's, well, Marcone.
Although he's a terrifying Body Horror (it's implied that he "Re Made" himself by choice), the gangster Mr. Motley of Perdido Street Station is definitely this. He's well informed about what's going on in the avant garde art scene and has this very Sophisticated as Hell way of speaking in which in a cultured voice and with Big Words, he talks about things like his philosophy on life and which of his rivals he plans to kill.
In Sherlock Holmes, Holmes insists that all of the incredibly successful criminals are well-rounded, usually in the aristocratic arts. His nemesis Professor Moriarty definitely fits the bill.
In the Gentleman Bastard series, Capa Barsavi of Camorr was once a professor of literature and rhetoric. One of his former students, Jaffrim Rodanov, is a pirate captain who loves to discuss classical theatre when he can find someone who shares his interest. Depending on where you draw the "wicked"-line, Locke, Jean and Sabetha can just as easily make the cut too.
Lynn Flewelling apparently is in love with them.. "Nightrunners" gives us first Lord Mardus. Gentleman, with high intellect and large interests, which are just as broad as the ones of one main character. Extraordinarily well mannered. Polite even to the prisoner he plans to bloodily sacrifice. Really, if you didn't know he aspires becoming the Avatar of a God of Destruction you'd really like him. Later Ulan (who starts out not really a villian but extremely pragmatic. And sadly if the main characters achieved their goal his clan would suffer, soLater it turns out that not only HE is responsible for the mess of Seregil's life, he also doesn't hesitate supporting rather nasty experiments just to prolong his life. ... and then we met Yakobin. Nice fellow. Has a good taste of tea. And dislikes beatin up his sleves more than neccessary - actually he is REALLY civilized and intelligent. Oh, have I mentioned he is an alchemist who creates child-like clones of you to brew some medicine of them and kills them when they wont fit your expectiations? Just to make you suffer the whole creation process once again?. The Tamír triad again gives us Nyrin. Court wizard. Soft spoken. Well mannered. Handsome. Apparently a good lover if you happen to be his mistress. Oh... and aspiring ruling from the shadows. And more or less directly responsible for countless assassinations of female members of the royal blood line.
Flashman villain John Charity Spring was on the Oxford don career path before getting booted out and seeking an alternate career in the slave trade. Spring is a brilliant classical scholar who constantly throws Gratuitous Latin tags into his conversation, but he's also a psychopath with a Hair-Trigger Temper. While there isn't a Good Is Dumb contrast (since Flashman is a Villain Protagonist), there is a contrast in intellect, since Flashman is Book Dumb and while he's an Omniglot when it comes to learning to speak living languages, he could never pick up Ancient Greek and Latin.
General Zaroff from "The Most Dangerous Game" is your typical aristocratic big game hunter, with an eloquent manner and a taste for the final things in life. He's also a depraved serial killer.
Scaramouche: The Marquis is an honorable, educated, well-read noble. He is also a ruthless killer.
Vlad the Impaler in Count and Countess. Cruel, sadistic, and ruthless in his quest to "free Christendom," he is nevertheless learned in the history of past civilizations and can refer back to Scripture off the top of his head. And he likes traditional Romanian dance.
After concluding his Dead Person Impersonation in the first novel by forging a will from his impersonee leaving everything to himself, Villain Protagonist Tom Ripley of the Ripliad novels lives the good life in a French chateau, becoming a talented dabbler in art (both as an expert and as a painter), music, and fine cuisine. In between entertaining guests, he likes to amuse himself by carrying out odd jobs for gangsters, and once in a while (i.e. at least once per novel) kills the odd person who gets too close to exposing his past
Sort of Real Life, since it's reality TV, but Joe & Bill (a.k.a. Team Guido) from The Amazing Race. They were relatively old, gay, had lived all over Europe, spoke several European languages and were overall kind of prissy. Needless to say, the other teams did not like them. Although they did give reason to, most famously because one of them shoved somebody's mother and reduced the daughter to tears.
The "Cultured" part definitely applied to them (they were even the first team to wear matching outfits), but, in retrospect, they weren't really that "Wicked". It was mainly three teams who were complaining about them, and the things they were complaining about are now considered basic strategies that every team is expected to know. Meaning these days, Joe & Bill come of as innovators, while the other three teams appear to be whining about a team actually trying to win. The only really wicked thing Team Guido did was trying to block said three teams from getting on their plane, which led to the aforementioned shoving incident, somehow shoving a woman who was standing behind them.
Farscape: Scorpius, though he wasn't particularly attractive (not to a human audience, anyway). Quite apart from his well-cultivated manners and sideline interest in growing crystherium flowers, his time spent travelling the galaxy has given him an in-depth knowledge of many, many cultures; he's even managed to learn the complex and translator microbe-immune language of the Scarrans and the Diagnosans.
Not particularly attractive to a human audience? You don't get onto the internet often, do you?
In one appearance, he quotes A Christmas Carol to a guard who doesn't catch the reference, and in another he references The Cask of Amontillado. This may intersect with Small Reference Pools, however, as both are generally read in High Schools.
Oz has Nino Schibetta, imprisoned Mafia Don and the first leader of the Italian gang. He is one of the most, if not the most powerful inmate in all of Oz, and is not only Affably Evil but Wicked Cultured personified. He is fluent in Italian (though it may be because he's implied to be an Italian immigrant), dresses fairly sharp, knows his wine and gourmet cuisine, and is hinted to be a fan of classical music. He is also a fan of inflicting Cruel and Unusual Death on his enemies.
In Smallville, both Lionel and Lex Luthor are examples of this.
In Knight Rider (classic), the main assassin in the episode "Deadly Knightshade" is one of the more obvious examples.
Benjamin Linus of LOST is an extremely polite and gracious host to his many captives, going so far as to feed one of them a beachside breakfast with a real knife and fork. He even plays Rachmaninoff's "Prelude in C-Sharp Minor" on his piano shortly before the Barracks are stormed by Charles Widmore's mercenary strike force... and before he is informed of their breaching of security and promptly reveals a shotgun hidden within his piano bench.
Used and also subverted by members of the Conspiracy on The X-Files:
Cancer Man/CGB Spender/Cigarette Smoking Man is something of a self-learned intellectual with an amazing capacity for reciting facts and quotations, but we find out in one episode ("Musings of a Cigarette Smoking Man") that all he really wants to do is write airport novels about the lone rogue going up against massive conspiracies... it is made pretty clear that he has to tell the truth about what he knows, but the only way to do this without sacrificing everything is to frame it as bad fiction that gets rejected by publishers. So CGB Spender is a ruthless villain with a facade of culture whose actual personal interests are a subversion of the archetype this trope describes.
On The IT Crowd, the German cannibal plays the cello beautifully.
Although Santos from the Argentinian series Los Simuladores is not evil, he is incredibly calm and cultured, and runs a shady business of The Plan with information gathered via "unorthodox" methods.
Lodz on Carnivàle was erudite, charming, and persuasive. He was also remarkably evil and showed some signs of Nazi sympathies.
Played straight with most of the Wolfram and Hart villains. They're normally a bunch of attractive, human (although occasionally soulless) lawyers who play golf, (sometimes with the devil) go to fancy parties (and get butchered) and drink wine. They're usually played as a contrast with the rougher, lower-class heroes. In fact, when Lindsey leaves W&H, he immediately goes back to his roots in a poor, Southern family.
The Wire: Brother Mouzone is a Badass Bookworm who dresses in the traditional Nation of Islam suit and bowtie, and reads heavy and serious intellectual books and magazines between gang killings. Stringer Bell was desperately trying to climb out of the gutter and get to this trope, before he was killed by Mouzone and Omar Little. The police are stunned when they search his apartment and find an immaculate office that wouldn't look out of place on Wall Street.
McNulty: "Who the fuck was I chasing?"
Quite a few of the bad guys on the various Law & Order series.
Half of the killers on Columbo, which is why they all underestimate the rumpled, blue-collar detective.
Supernatural: Crowley, Crowley, Crowley, Crowley, and CROWLEY
In Cracker, Albie Kinsella (Robert Carlyle) resents how he thinks people view him as an uncultured and uneducated thug. He makes a point of this when he kills his second victim, a professor, who had dismissed him as such in public, when he recognises the music the professor was playing as Mozart and asked him if he was surprised he knew that (which he was). He both hates that people think of him as scum (in his mind) and blames them when he in turn acts like murdering scum. Unfortunately his first murder was a hotheaded attack on a shopkeeper over being ripped off by 4 pence. In other words he's a Deconstruction of the Trope, a working class killer who both shows signs of being cultured yet is at the same time is becoming every bad thing he thinks society views him as being.
Albie: Ya treat us like scum we start actin' like scum.
System Lord Ba'al from Stargate SG-1. Part of his ascendancy to Magnificent Bastardry was that he wasn't just a Large Ham; he could also churn out charm by the bucket and became almost an expert on human high culture. In one of the DVD movies, he forgoes the "Kneel Before Zod" speech and actually invites himself to lunch with the President in the Rose Garden at the White House! What a guy!
Stargate Atlantis: In "Condemned", the team goes to a planet whose leaders struck a deal with the Wraith. The Wraith who regularly visits the planet enjoys fine cuisine and wines, despite the fact that they provide no nourishment for him. He considers himself a more enlightened and civilized Wraith than his brethren for allowing the planet to live in peace (instead of being constantly submitted to genocidal harvests) in exchange for a small but steady food supply. He admits he does enjoy his dinners with the magistrate, to whom he is courteous and polite, but since he's still a life-sucking monster this is capped off with things like the Wraith pointing out that the previous cook was tastier than his meals, and he threatens to annihilate the whole planet unless they give him more people to feed on so he can "provide" for his Wraith friends.
Blade: Marcus van Sciver is known throughout Detroit as a patron of the arts and a proponent for the city's cultural revival. At the same time, he's a vicious bloodsucking mastermind, whose goal is to overthrow the vampiric aristocracy. Being British helps. He gets Krista to sleep with him after killing her brother and forcibly turning her by telling a sob story about his late wife.
In an episode of Star Trek: The Next Generation, several characters are trapped in a malfunctioning holodeck, surrounded by holographic gangsters from Picard's noir holonovel. The man in charge of gangsters (a Lawyer-Friendly CameoKasper Gutman) is well-dressed and well-spoken. Crusher gets sick of it and asks why he insists on treating them well before shooting them. He replies that without civility, we may as well be animals.
Also, the self-aware Moriarty holodeck program. Seriously, the holodeck can create some really cultured foes.
This phenomenon is very common in Soap Operas. Many arch-villains have been featured in this way, including vaguely Italian mobsters Stefano DiMera from Days of Our Lives and Carlo Hesser from One Life to Live, Swedish-born drug smuggler and arms dealer James Stenbeck from As the World Turns and cut-throat businessman Roger Thorpe from Guiding Light. Such wickedly cultured hallmarks of these characters include the almost painfully stereotypical wearing of finely-tailored suits and the drinking of expensive cognac.
Some of the villains on Alias fall into this category. Sark is fond of Chateau Pétrus (one of the world's rarest and most expensive wines). Also, in one episode, the protagonists drug a bad guy's Cristal at a performance of the London Philharmonic (he goes there on the third Saturday of every month).
Cersei Lannister is able to match wits with Ned Stark during a subtext-laden conversation about Ned's education as oppposed to his brother's, and understands enough about the military realities of the North to lecture her son Joffrey on the impossibility of occupying the North directly. She's also plotting to kill the King.
Averted with Joffrey, however. He's just Ax-Crazy and clearly has no interest in culture.
Elementary's version of Moriarty, like most of them, definitely fits this trope. She first appears on the screen impeccably restoring artwork (and is implied to have personally created duplicates of well-known paintings so convincing that they fooled the museum curators), is never dressed in anything less than the most impeccable clothing, and manages to put on a Fake American accent, amongst manyotherthings, convincing enough to fool Holmes (and everyone else in the show).
Dr. Hannibal Lecter, as he appears in Hannibal, is as fitting an example as his literary and film counterparts, if not more so because the series is set before his discovery and incarceration by the FBI. He enjoys the finest wines and coffees (going so far as to create a custom beer reserve that's brewed in Cabernet Merlot barrels to impart a wine flavour), enjoys the local opera, has gorgeous artworks on display in his home and office and wears very expensive and stylish suits. It all stems from Hannibal's God Complex and his innate need to demonstrate his superiority over others.
Karabraxos from the Doctor Who episode Time Heist, who has classical music playing in the private vault.
Gorgeous George first started playing up the gimmick in the 1940s. Okay, so he was more of a Sissy Villain, but he did wear perfume and employ a butler, and entered rings to Elgar's Pomp and Circumstance.
Many British wrestlers, especially British wrestlers wrestling in other parts of the world, from Sir Alan Garfield to Wade Barrett.
Triple H, during his early years in WWE. He'll still lapse into it a bit on occasion, such as when he recently quoted H.P. Lovecraft.
Angel Orsini, Prodigette, prefers to wind down with polite company in a well tailored suit with a cigar dipped in cognac. When that isn't possible though, she'll settle for working off stress on any hapless victims within arm's reach.
Cody Rhodes has been using this as his gimmick since 2010. It's really more of a "metrosexual" gimmick (perfect teeth and fingernails, etc.), but he's also known for his rather snobbish New England accent (despite being from Texas!) and occasional Sesquipedalian Loquaciousness.
Aaron "The Idol" Stevens, ladies man, is gone. Damien Sandow's entire gimmick, the "Intellectual Savior of the Unwashed Masses" is this. When he and Cody Rhodes formed a tag team, it was called the Rhodes Scholars.
A few of Agent 47's targets in Hitman fall under this heading, though they are particularly rare. The most obvious is Don Fernando Delgado, a drug baron who also produces several highly-regarded wines, plays the cello as a hobby, and collects rare butterflies.
President Shinra of Final Fantasy VII is seen listening to classical music while the Sector 7 Slums are destroyed. Also, Genesis of Crisis Core quotes incessantly from the play Loveless.
Ultimecia of Final Fantasy VIII has a definite sense of luxury and style, even if her fashion sense is a bit odd. Her castle has a large chandelier, a pipe organ, an impressive wine cellar, and an art gallery with pieces she either collected or painted herself.
Dark Oppressors in Nexus War are supposed to be like this. It doesn't exactly get reflected well in their skillset, but the sort of players that get attracted to the game mean that it gets played straight anyway.
Mad artist Sander Cohen of BioShock covers dead bodies (and sometimes living Splicers) in plaster and poses them as statues, chains poor Fitzpatrick to a piano rigged with dynamite and makes him play until he blows up, sends you on a quest to kill his fellow artists and take pictures of their corpses to add to his latest masterpiece, and in one spontaneous fit of rage sics multiple waves of Splicers on you to Tchaikovsky's "Waltz of the Flowers". His artistic success amounts largely to riding the wave of Ryan's current moods, but that is a surprisingly good number he has Fitzpatrick playing (until Fitzpatrick misses too many notes).
Andrew Ryan too, with his pursuit of objectivist philosophy as an end unto itself, and his beliefs that all artists should be free to express their dreams without fear of censorship. Even his passion for Art Deco architecture is obvious in the appearance of Rapture, despite being built thirty years after Art Deco was all the rage.
General Viggo in Fur Fighters tries to come across like this, he succeeds right up until the end when he cracks.
The Gravemind from Halo always speaks in trochaic heptameter. He explained to Cortana in Human Weakness that he simply grew fond of poetry after he consumed enough poets from different races and cultures.
The Spy from Team Fortress 2 initially appears this way, especially in his Meet the Spy video. It kind of falls apart in-game, though, when he winds up shouting insults like a 12 year old and laughing until he snorts.
Heavy, meanwhile, definitely counts. He has a Ph.D in Russian lit. and enjoys himself a nice peach bellini. This, in-between screaming at the top of his lungs, chewing through people with a giant minigun, and telling stories about choking an Engineer with his own wrench as if it were some kind of bawdy anecdote.
Between bouts of administering "accidental" not-medicine and blowing up hearts For Science!, Medic's a violinist.
The Engineer, to Blutarch Mann's personal care attendant, regarding a painting in Blutarch's mansion: "Say, ain't that an originalKicasso?" He also has eleven doctorates to explain his building skills.
Ganondorf. One particular example would be in The Legend of Zelda: Ocarina of Time, wherein he is playing the organ while awaiting Link's arrival at the castle to rescue Princess Zelda.
Donovan Hock from the "Kasumi's Stolen Memories" DLC is also an example, being a ruthless criminal who owns several rare sculptures, including the Lady Liberty's head and Michelangelo's David. Hock even shouts a Big "NO!" if Shepard shoots one of his precious sculptures.
Relius Clover in BlazBlue while being utterly ruthless, conducts himself with extreme suave style, dresses very well, his hobby is watching opera shows, and the things he dislikes are just 'disorganized book shelves'. He doesn't use crude language while showing off just how deprived evil he is, as opposed to Hazama.
Conrad Marburg, The Dragon in Alpha Protocol. One mission requires the protagonist to infiltrate his villa, which is decorated from floor to ceiling in neoclassic art and has classical music playing loudly in a number of the rooms.
Emperor Zinyak of Saints Row IV has an affinity for wine, Shakespeare, opera, and even DJs the Steelport simulation's classical music radio station.
In Vampire: The Requiem, most Invictus vampires are presented this way, as are the Ordo Dracul and Clan Mekhet; just how evil they are depends on the individual and one's point of view. In the previous edition, Clans Ventrue and Toreador were even more cultured, and the classier Lasombra and Tzmisice really reveled in the Wicked Cultured part.
The Gunstar version of the Magnus in Shards of the Exalted Dream, as a sort of motonic physics Expy of Hannibal Lecter, revels in this trope. When people come in to ask him questions about Primordial metaphysics (which, when you're engaged in reshaping one into a war engine, is sort of a big deal), he tends to provide less unpleasant unforeseen consequences when advising people who discuss philosophy with him or sing him an aria from the latest opera.
The Dark Eldar, naturally, carry themselves with the same sophistication and grace of their good counterparts the Craftworld Eldar, but they're also soul-sucking monsters who consider torture, rape and violence to be fun past-times.
A number of fallen Primarchs were remarkably well-educated - Horus, Magnus, Fulgrim, and even Perturabo qualified in different ways, with Fulgrim and Horus as patrons of the arts, Perturabo as an architect and classical scholar, and Magnus as a remarkably erudite Warp-scholar. Of all four, Horus was the only one whose corruption came about without involving it - Magnus delved too deep into the Warp and succumbed to Pride, ultimately being deceived and stranded on the tender mercies of Tzeentch; Fulgrim's art was corrupted into a lust for sensation, leading to the Emperor's Children devolving from artists and musicians into drug-addicts and hedonists; and Perturabo's resentment at being continually thwarted in his desire to build something out of marble and graceful curves rather than stone and razorwire led him to loathe most of his brethren and ultimately fall to Chaos.
Doc Scratch of Homestuck is perpetually dressed in a white tuxedo, lives in an art deco apartment in a mansion, speaks with perfect grammar and near-unflappable politeness, enjoys playing pranks and board games with children, and is an excellent host to his guests. He just so happens to also be The Dragon to an Eldritch Abomination, with the stated objective of bringing about the end of his universe so that his master may feed on reality's corpse.
He also kicked off the "Make her pay" subplot, which resulted in one person confined to a wheelchair, one dead, one blind, and one losing an arm and eye as well as being despised by everyone she ever liked.
Mordecai Heller from Lackadaisy can be considered this.
Both Dr. Diabolik and his daughter Jadis, in the Whateley Universe. Jadis Diabolik is only a high school sophomore, and already feared throughout Whateley Academy. She quotes Shakespeare and Yeats, and knows who is the finest butcher in all of New York City. However, do not make her mad at you.
In Tales of MU, Embries and The Man both qualify. The former has a gloriously-decorated office and snazzy attire, a silver tongue, and a tea set of which he is very fond. He is also an ancient dragon with a taste for human flesh. The Man is a demon who devours the hearts of virgins monthly to sustain himself and impregnated and abandoned the main character's mother twice. He wears a snazzy pinstriped suit and waxes philosophic (sometimes in High Draconic) when speaking with his daughter, however, and like Embries is a master of seduction.
Toyed with in To Boldly Flee with Christopher Clodd/The Executor: He seems to be a connoisseur of the arts, but it's eventually revealed that he actually considers bad films, such as "Manos" The Hands of Fate, or the filmography of Uwe Boll, to massively influential "good" films, believing that fame is fleeting, while infamy is forever.
Azula from Avatar: The Last Airbender was well-versed in her nation's military history. She was very eloquent, manipulative and recognized the weaknesses of her foes with ease. It is possible that she outmatched even her father in terms of strategical skills, since the Firelord relied very much on his counselors.
Zaheer from Season 3 of The Legend of Korra is well versed in Air Nomad history and lore, despite not being an Air Nomad himself. These philosophies help him greatly when he gains Airbending via Harmonic Convergence.
Daggermouth, an animatronic robot catfish (and later from a Show Within a Show) is portrayed as one as well.
The Ultra-Humanite in Justice League donates money to public television, enjoys classical music, and once reprogrammed a childrens' toy to tell them the story of the Nutcracker. He's also an insanewhitetalkinggorilla.
PBS Announcer:This program was made possible by a grant from the Ultra-Humanite and Viewers Like You.
Possibly Vandal Savage, as well. He's smart, but his level of culture is arguable; Wonder Woman certainly feels he's exactly as barbaric as the caveman he ultimately is.
"Hereafter" confirms it when Superman looks over his library. "Self-help books? You don't seem like the type." To be fair, at that point Vandal had been by himself for 30,000 years, so he was half crazy from boredom and guilt by the time Supes reached him.
Sideshow Bob and his brother Cecil Terwilliger. Not surprising, as the voice actorsnote Kelsey Grammer and David Hyde Pierce respectively portrayed the cultured (but not wicked) Crane brothers on Frasier.
Cecil: Perhaps a glass of Bordeaux? I have the '82 Chateau Latour and a rather indifferent Rauzan-Ségla. Bob: I've been in prison, Cecil. I'll be happy just as long as it doesn't taste like orange drink fermented under a radiator. Cecil: That would be the Latour, then.
All things considered, Beast Wars Megatron certainly fits the bill. From his aristocratic accent to his quoting Earth literature, one doesn't doubt that if it had been possible for him to sip a nice chilled glass of red, BW Megatron would have been. Perhaps while doing the Slouch of Villainy in his command-chair or soaking in his energon hot tub.
The fact that he bathes with a rubber ducky manages to reduce his cultured aura not one bit, impressively.
Also he strokes his T-rex head arm while in his robot form, the same way James Bond villain Blofeld caresses his pet cat.
The Megatron in Transformers Animated was obviously inspired by his predecessor. He drinks oil out of a barrel crushed into the shape of a chalice.
The Grand Duke in Rock-A-Doodle is not just a evil owl who spits black magic and wears a Dracula cape; he also enjoys embroidery and plays a demonic organ that controls the weather. Being voiced by the urbane Christopher Plummer helps.
Phantom Limb from The Venture Bros. is a definite example, once called out for having sold out his villainous principles for high culture accoutrements such as dealing in stolen art instead of 'the old stuff'. (In the same episode, he laments how many of his fellow art thieves want to steal the Mona Lisa, for no other reason than it's a famous painting, and not because they appreciate it as art.)
Played with in Exo Squad. Phaeton is highly articulate and literate enough to have a quote from Dante inscribed in the entrance to his bunker. On the other hand, he is NOT a fan of art, which he (quite passionately) declares to be "a useless Terran pastime".
This leads to a hilarious moment where Exo Trooper Wolf Bronski, by no means cultured himself, is attempting to save paintings Phaeton has ordered destroyed. During the fights, he yells at the Neo Sapiens, calling them Philistines. Then he turns to the woman with him and asks "Hey, what's a Philistine?"