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Anime and Manga
- Gilgamesh from Fate/Zero is ridiculously good-looking and has A+ Charisma, but is a major Jerkass and a part of the Big Bad Duumvirate.
- Griffith in Berserk is so Bishonen it hurts. He's also the major Big Bad of the series.
- Ryoki from Hot Gimmick.
- Also Azusa, who is an attractive model that tries to have his friend gang-raped as revenge for something she didn't even do.
- Aizen of Bleach.
- Monster: Johan Liebert
- Apos of Mnemosyne
- Rumiko Takahashi uses the variation Hot Guys are moronic buffoons, characters such as Mendou, Rei and Tatewaki Kuno are good examples. Rei is probably the best example as the Cute Monster Guy is so dumb he can only say a few words very slowly. Due to the art style they often don't look that much more attractive then the other characters.
- Andrea of Gankutsuou.
- Sasuke of Naruto, at least after he Took a Level in Jerkass.
- Light Yagami, particularly later on in Death Note.
- Dio Brando from Jo Jos Bizarre Adventure.
- Nakago of Fushigi Yuugi and it's nearly deconstructed in a last minute Alas, Poor Villain scene showing his origin story.
- Paul, the resident Jerkass trainer from Pokémon.
- Miyabi from Rosario To Vampire.
- Iason Mink of Ai no Kusabi is incredibly cruel but he is also incredibly irresistible.
- Cruelly deconstructed in Sakura Gari, where the unearthly gorgeous Souma is a massive bastard... but he turns out to have an extremely complex reason to be an asshole. And his physical beauty brought him lots of abuse.
- Black Butler
- Tsukiyama is this in the first manga of Tokyo Ghoul where he is portrayed as a very attractve guy whom mutilates and eats other people and ghoul.
- Animal House and Revenge of the Nerds definitely qualify.
- Animal House tries to have it both ways. The opposite number of Omega House's Gregg Marmalard is clearly Eric Stratton, who's just as handsome as Gregg is but is clearly intended to be the Designated Hero. But if you consider Gregg's "good" counterpart to be John Blutarski (who does ultimately succeed in wooing Mandy Pepperidge away from him, after all), then this trope is played straight.
- Shallow Hal.
- Cruel Intentions: Both lead characters are played up as being very attractive, and both are rotten to the core. However, the film's climax features some character development for the male as he develops actual, honest feelings for the genuinely wholesome girl he was chasing for most of the film.
- Joren of Stone Mountain in Tamora Pierce's Protector of the Small books, a misogynist asshole who goes to any length possible to get Kel out of knight training. According to Pierce he was based off of someone she knew in college.
- Galad Damodred of The Wheel of Time was one of these. He was never evil per say but he would do what he thought was good, regardless of who got hurt. He got better in Book 13.
- On the less sympathetic side, there's Rahvin.
- In the second book of Kat Richardson's Greywalker series, the main character Harper immediately distrusts the really good-looking guy — she's right. Several other times played straight in this series. Harper winds up deeply in love with a guy who's not handsome.
- Agatha Christie seems to have believed this very much. If a handsome man is introduced in a book of hers, he will be either the killer, the accomplice or otherwise immoral. Note that this is restricted to men whose attractiveness is spelled out: other characters might be handsome too, but the fact being mentioned is a sure sign that we're looking at a gigolo, a blackmailer or just a bastard. This is so prevalent in her writing that in the one book where a handsome man isn't a complete bastard (he's loyal and caring, but he still might be a gigolo), the killer turns out to be the other handsome man. This may be writer on board as Christie's first husband was a good-looking jerk.
- Averted, however, in Death Comes At The End, in which a handsome suitor to the heroine of the story is a good (though not faultless) man. She ultimately realizes, however, that he is not the one she wants to marry. It's also notable that the murderer is the only one of the patriarch's sons not to be described in the story as handsome, although the other two handsome sons are jerks.
- Richard Carey in Murder In Mesopotamia is another aversion.
- Dr. Mark Ahriman of False Memory. Handsome, successful psychiatrist who mind rapes (and sometimes literally rapes) his patients, sending some out to kill people and driving others to creative suicide for his own entertainment.
- Keifer Porter of A Brother's Price was noted for being cruel, dim-witted, and exceptionally beautiful. On the other hand, Jerin Whistler, who ends up marrying Keifer's widows, subverts this. He's noted in-universe for his beauty, and also for his intelligence and kind nature. Jerin even manages to help Trini deal with her aversion to men caused by Keifer brutalizing her before she was of age for marital relations anyway.
- A Song of Ice and Fire plays with Beauty Equals Goodness quite a bit, resulting in a few straight examples of this trope.
- Joffrey Baratheon inherited his parents' stunning looks, but is physically and emotionally abusive to his family and fiancee and governs the realm with terrible petty decisions.
- Gerold Dayne, also known as "Darkstar," has the traditional Valyrian beauty of the Daynes but is arrogant, mean-spirited, has a "cruel tongue," and is eager to make a name from himself distinct from that of his family. He's also not above nearly killing Myrcella, maiming her in the process if it means accomplishing that. For bonus points, Arianne describes the trademark Purple Eyes of House Dayne as looking black from a distance on him.
- Jaime Lannister, whose shining beauty is consistently praised throughout the series, pushes an eight-year-old boy out the window for catching him engaging in incest in his first appearance. His Character Development into becoming a slightly better person is juxtaposed with his increasing scruffiness.
- Downplayed with Loras Tyrell, whose trademark Tyrell good looks have garnered him plenty of In-Universe fangirls. He's arrogant and cocky, but isn't really a terrible person. And then he gets several major injuries attacking Dragonstone — having boiling oil poured on his face included — so it remains to be seen whether he'll live to subvert or invert this trope or not.
- The series also inverts this by having more unattractive guys as more decent, such as Ned Stark or Tyrion Lannister, but also averts this by having good-lucking nice guys such as Garlan Tyrell and Robb Stark.
- In the Heralds of Valdemar series, Herald Talia's abusive father and brother were quite attractive, and as a result she's wary around handsome men; the man she falls in love with is repeatedly described as homely.
- Christian Grey from Fifty Shades of Grey is described as amazing attractive by his love-slave girlfriend Anastasia Steele, and of course he is cruel, domineering, abusive jerk. Their relationship is portrayed as S&M, but since it completely misses the entire "Safe, Sane and Consensual" thing, he's really just a Domestic Abuser.
- Sawyer on the first couple of seasons of LOST.
- Nathan Petrelli and Sylar throughout Heroes.
- Chuck Bass in Gossip Girl.
- Stephan Urkelle of Family Matters first appearance was a self-absorbed prick who couldn't care less about Carl's friend getting shot. However, as Steve began modifying and perfecting the formula to create him (Boss Sauce), Stephan become a suave and kind-hearted gentleman. Essentially, a cool and slightly less intelligent version of Steve.
- Some of the guys that Laura becomes interested in usually end up being jerks who just want to sleep with her.
- Damon Salvatore of The Vampire Diaries.
- Jeff on Community, although he gets slightly better over time.
- Angel and Spike in Buffy the Vampire Slayer. They've both spent a good amount of their lives torturing, murdering and even raping various people, and never reform completely, but it doesn't seem to detract from their sexual appeal. They dress a lot more stylishly than either Xander or Riley and, judging by the reactions of other characters in-universe, they are supposed to be more physically attractive.
- Eric from True Blood, especially after he took a level in sexy in seasons two and three.
- And Bill and Jason have had their moments of complete bastardry, too.
- Prevalent in Supernatural. As a general rule, while a character's level of attractiveness doesn't determine how "good" they will be, the less attractive male characters seem to form better romantic relationships.
- While Sam and Dean might basically be good people (at least, when Sam hasn't gone darkside) they both manipulate women for sex and have a tendency to self-obsess and act like major jerkasses to everybody around them. If you were a random bar-frequenting woman in the Supernatural universe and they hadn't saved your life, you'd be forgiven for thinking they were bastards. It's worth noting however that Sam averted this entirely before he became a Hunter again in the series pilot, instead having been in a stable and loving relationship with Jessica at the time.
- Castiel isn't sexually manipulative towards women, but that might have more to do with his general cluelessness about human behaviour, his devotion to his faith, and disinterest in the matter. The sexual chemistry with Meg seems to be based around violence, and he once accidentally burnt somebody's eyes out and forgot to fix them, although it seems like he could have done so easily. So he's probably not the best boyfriend material, either.
- Bobby is comparatively less attractive but was able to maintain a stable and loving marriage for many years.
- While Samuel Winchester, Senior (the grandfather) is morally ambiguous, his marriage and commitment to his family seems a lot stronger than John's.
- The only notable exception to the rule is Jimmy (Castiel's vessel), who is very pretty and was (before he became involved in angel business) a devoted and loving father and husband. And the actor who plays him is probably cuter when he plays Cas, anyway.
- Almost every female demon, ever.
- The Big Bang Theory. The series's Official Couple is pretty much set up to be the classic 'Nice Guy nerd courting the Prom Queen'. As such, almost, but not all, rival love interests who happen to be attractive, or at least arguably more attractive than Leonard, tend to be complete and utter assholes, who treat Penny terribly. The exceptions being Stuart (who goes from slightly adorkable Nice Guy to almost a parody of the Adorkable Woobie types), Zack (who despite fitting the mold, he's an example of Good Is Dumb), and her recent British study partner Leonard was jealous of, who was wiling to play along with Leonard's attempt to scare him off.
- IWRG luchador El Guapo Siniestro was of this opinion, and if his name didn't give it away, based this view on himself. Mr. México and Poder Méxica had some fun getting him shaved.
- Yu Han-Sung from Tower of God.
- Captain Hammer from Doctor Horribles Sing Along Blog.
- Family Guy:
- An episode of has Peter becoming a jerk after plastic surgery turns him into one of the beautiful people, because being handsome means that he can screw the rules. On the other hand, considering who we're talking about, the appearance boost may not be to blame.
- Jeff Fecalman, Brenda Quagmire's abusive boyfriend.
- Clone High's very own JFK.
- X-Men: Evolution used an art style that made most characters attractive. However, according to some fans, the most attractive characters are Pietro, Gambit, and Avalanche. While Gambit and Avalanche both have lines they won't cross and times of heroics, they still had strong shades of criminal level jerkery. However, Pietro takes the cake. Sociopathic disregard for human life? Check. Starscream level cowardice? Check. Draco level smugness? Check. Pretty white hair and bishonen level attractivness according to girl fans? Check.
- The jock Duncan took Jerk Jock gig even further when he attacked the Morlocks with guns and bombs.
- The Dark Ace from Storm Hawks.
- Justin and Alejandro in Total Drama in spades. Also Duncan, Scott and Lightning to a degree.
- Gordon Gibble of Kick Buttowski.
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Anime and Manga
- Eiichiro Oda appears pretty fond of it. Especially Nami and Boa often use their looks to get work done for them or get through with absurd actions.
- Asuka Langley Soryu from Neon Genesis Evangelion. In spades. However, in her case, it's a brutal deconstruction of this trope: she's a hot bitch, yeah, yet not only she doesn't get away with her antics (Touji is annoyed to no end by her, Shinji puts up with it because he's deeply fucked up, Rei is indifferent most of the time, etc.), but she's subjected to an horrifying Break the Haughty process that reveals her terrible Dark and Troubled Past.
- Lust from Fullmetal Alchemist, all the way down to being a female Draco in Leather Pants. Then again, she is created after the Lust sin.
- Actually, it depends on which canon you're following. She plays it straight in the manga and Brotherhood, but in the first anime series she's a shitload more sympathetic.
- Yui of Fushigi Yuugi, though in her case it's more because she's been badly manipulated and emotionally abused by Nakago, mentioned above.
- Pick a female villain in the James Bond franchise, any female villain.
Live Action TV
- Power Rangers: Barring Rita, most of the humanoid female villains could qualify.
- Laurie from That '70s Show
- Alex Barnes a/k/a Alicia Bannister from The Sentinel. Although beautiful, she was a thief, a multiple murderer, and generally AxCrazy. Also Lyla, Maya. . . really, most of the women Jim & Blair get with—they're all gorgeous, and all thoroughly nasty pieces of work.
- Saffron (or whatever her real name is) from Firefly, who was a thief, a swindler, and who tried to kill Mal by leaving him naked in the desert.
- As a possible example of this trope, there's one Nodwick strip in which a villainess explains her face (and gender) is always hidden because only hot evil chicks are allowed to show they're evil.
- Double lampshaded because at first they just think it's because she was horribly disfigured in an accident, but then she mentions that even before the accident, a woman who was "nothing special" would have been a pretty good catch compared to her.
- In Teen Girl Squad, Cheerleader is considered the hottest out of the group in-universe. She's also the meanest.