Bang Shishigami of Blazblue is treated as an imbecile by most of the cast, and indeed his ham-fisted attempts at heroics are usually caused by him misjudging situations and people. Heck, he once picked a fight with Tager because, in his own words, Tager looked like the kind of guy who would do something evil one day. He's also pretty much the weakest person in-universe, with even Carl Clover being more powerful than him. However, he has this amazing ability to get serious when he needs to. In the first game, he fought Hakumen to the point where Hakumen called him a Worthy Opponent. In the second game, he pulled a Big Damn Heroes against the uber-powerful Big Bad and held his own long enough to pull two kids to safety. In the third game, he fought Azrael and Azrael longed for the chance to spar with him again; as a point of reference, Azrael soundly defeated Jin and called him boring.
In Blazblue's daddy, Guilty Gear, Axl Low. While he looks naive and goofy, he can hold his own against I-no and Sol Badguy himself. He's stated to be one of the few humans who were capable of using magic prior to its discovery, and has Super Reflexes which renders firearms ineffective against him. And he's just a perfectly nice, funny, easy-going British guy who's only tangled up in the plot at all because of involuntary time travel which keeps placing him in the GG-verse. Revelator tops it off by revealing that he's actually a full-blown Reality Warper with Time Master powers.
JohnnyCage since Mortal Kombat 9. The guy looks and sounds like a parody of a self-absorbed action movie star and spends a good portion of his chapter in 9 making an ass of himself and being an insufferable flirt towards Sonya Blade. And yet he manages to survive the plot which sees a massive death toll among the heroes, and his ending reveals that he has the potential to be staggeringly powerful due to his lineage tracing back to Mediterranean warriors bred for the gods. His role in the sequel? Unlocking said power for a beatdown on Shinnok, the resident Satanic Archetype of MK, and becoming the new Champion of Earthrealm. And becoming a very effective Cool Teacher for the next generation of heroes who end up saving the day from the same villain, now in his One-Winged Angel mode.
In World of Warcraft, prior to the release of the Wrath of The Lich King expansion, a Hunter using the Survival talent tree was an example of this trope. Survival was the least played class/spec combination in the game, at somewhere between 3-7% of the overall playerbase, and was generally ridiculed. During an Expose Weakness, or ten second Deterrence proc, however, things changed. The spec went from a typical DPS output of 400 outside an instance, (barely enough to kill non-elite mobs during questing) during "crouching moron," mode, to 1200 when appropriately raid buffed and proccing EW. The dodge/parry chance during a ten second Deterrence activation also doubled, sometimes reaching a potential maximum of 110%; which meant that Surv could theoretically (and often did, practically) finish tanking 75%+ dead raid bosses after the main Warrior or Paladin tank died.
In the first game, Laharl issues a challenge that whoever wins a fight against him and his allies will be the next Overlord. Things look bad when the mid double-digits party faces off against an insanely over-leveled opponent. then the comic relief characters that hang around Laharl's castle jump in and defeat him in a few seconds flat. It's generally then that you realize that the levels they have actually mean something.
In Disgaea 2, Rozalin shows off a particularly fearsome variant of this. Having spent her entire, pampered life in a palace, surrounded by servants waiting on her every whim, she's a complete novice when it comes to fighting (thus giving the hero, Adell, an excellent opportunity to explain the combat-system to her...) It's up to the player how much he wants to level her, but she'll probably still only be around level 50 when you first encounter, and are soundly defeated by, a level 1200 Overlord. At which point a seal is broken, and she suddenly jumps to level 1700, learns a world-destroying special move, and kicks seven different shades of ass. Afterwards, when she snaps out of it, she's got no idea what happened.
The King of Fighters has a game play example in Hotaru Futuba. Sure she looks harmless and is usually so personality wise, but in the hands of a competent player, she's an utter monster.
Arado Balanga of Super Robot Wars Original Generation is exactly like this. He's normally a reckless idiot who gets shot down more than not, but if his partner Seolla (who he was trained to work as a perfect partner to) is threatened with death, he'll be there to take it and go down in flames and utterly kick ass.
Though it is worth mentioning that Arado isn't necessarily a bad pilot by normal means. His tendency to get shot down most of the time is because early on he was stuck using long ranged machines when he had been trained exclusively in close ranged combat. Once he gets his eventual upgrade to a mech that better suits his skills, the other characters note that his piloting performance goes way up, even without Seolla around.
Arado still makes stupid mistakes on a frequent enough basis, though, such as overdoing his flashier attacks and running out of fuel or energy. Luckily, it seems to happen mostly when the enemy's already been blasted out of the sky.
Demyx from Kingdom Hearts II is the villainous embodiment of this trope. His clumsy, cowardly, scatterbrained personality was stressed so much that even Jiminy's Journal called him "a poor fighter". He isn't.358/2 Days shows that he's not exactly a coward, he's just REALLY lazy (or rather Dismotivated). He prefers to bribe other people to do his missions for him, and his reaction to nearly half the Organization dying at Castle Oblivion is "remind me to underachieve twice as hard from now on".
And turned right back around for comedic effect in multiplayer, where Johnny's lack of nanomachines robs him of SOP-linking and the benefits it provides; if you try to link while standing still, he does an anime pose, and if you try while running, he does a Rainbow Six-esque hand signal. He also can't do CQC and will flail hilariously if you try. His diarrhea, however, turns him into a walking gas grenade as it will incapacitate anyone he runs by.
What's more is that the attack (like her personality) seems pretty innocent. How you say? It's a beautiful field of flowers that appears on screen, that's it.
In Undertale, Papyrus is portrayed as a foolish, though ultimately kind-heartedCloud Cuckoolander. His boss fight, however, is a Wake-Up Call Boss that can be surprisingly challenging even though he barely pays attention to you. Undyne even admits that he's a perfectly capable fighter, but he's too sweet and innocent to join the Royal Guard.
There's also Sans, Papyrus' brother who at first appears as a lazy bum that loves to slack off and crack jokes. However, should the player take the Genocide route, Sans shows up as the Final Boss and he is by far the hardest boss in the game. Even his Check description uses Exact Words to deceive you into believing that he is weak, saying that he only has a defense of 1 and can only deal 1 damage. This is true, but left unsaid is the fact that he can avoid any attack and that his attacks deal 1 damage per frame, bypassing Mercy Invincibility. And apply a lingering damage over time effect.
Both Toriel and Asgore can be argued to be this as well. Toriel's badassery is established early on when she effortlessly blows away the Hopeless Boss Fight in one hit, but it's easy to forget about it as she dotes on the character, literally holding them by the hand through puzzles. Asgore is a big fluffy pushover of a king who would like nothing more than to offer you tea, but for the sake of his subjects, he has to kill you - and even though he can barely find in himself the will to attack you, his attacks are still hellish to avoid.
In Pokémon Mystery Dungeon: Explorers of Time/Darkness, Guild Master Wigglytuff seems to be nothing more than a simple, Perfect Apple-loving, uber-happy goof of a Pokémon. But if he gets upset, you'll find out exactly why Chatot seems to fear his temper.
The additional side stories for Wigglytuff (as a child Igglybuff) and for Team Charm from Explorers of Sky further explains this. Wigglytuff has a tremendous talent for solving puzzles and getting through traps, almost accidentally, hidden beneath the overtly cheerful demeanor. No wonder he's a Guildmaster despite seeming totally clueless.
King Trode from Dragon Quest VIII would be a great example. He spends most of the game just sitting in the wagon and generally complaining about various things like his curse or how you haven't found Dhoulmagus yet. But in the ending? He can be seen beating up several Argonian guards. His weapon of choice? A twig. You heard me. He beats up men twice his size, who are reportedly tough enough to kill Argon lizards, and he does it with a 2-inch piece of tree wood.
In Pokémon, at first Whitney seems like a generic teenage girl, with some Genki Girl mixed in. However she's renowned by the fanbase as being one of the hardest gym leaders in the games due to her Miltank.
A very popular fan-theory and urban legend for Pokémon Black and White was that Dumb Blonde Bianca would turn out to be the true Pokemon Champion of Unova. While that turned out to be a misunderstanding of the game data for battling her post-storyline, there's still the possibility that, depending on your choice of starter, Bianca can end up with a more robust and better-balanced team of Pokemon than Cheren.
Grit from Advance Wars is a top-notch distance weapons specialist (And considered an overpowered CO in earlier games by the players), but he hardly ever shows it due to his incredibly laid-back, agreeable demeanor.
Touhou is positively brimming with examples of this trope. Shall we start with YukariYakumo herself, wielder of powers far beyond godly who nonetheless prefers to spend her time goofing around, bothering Reimu, and generally acting like a little trickster imp? Or YuyukoSaigyouji, who is genuinely amiable and nice and enjoys a good meal and sake under the cherry blossoms far more than anything else in the world, but who has been heavily implied by the author to know a lot more than she lets on, being able to keep up with aforementioned Yukari? (Not to mention her power is to cause the death in anything that can die.) Maybe Komachi Onozuka, who is a God of Death and the Ferryman of the Dead — and also a complete slacker who runs low on her quota of souls ferried because she prefers to lay down near the Styx and catch a shuteye or twenty? Or Suika Ibuki, a little girl who looks like a perpetually-tanked seven year old with horns and an unquenchable thirst for parties — and can also bench-press a mountain? All in all, when you're in Gensokyo it certainly pays to not underestimate whatever little girls you may find.
Conversely, Rumia, the youkai of Darkness. She consistently walks into trees (the powers of Darkness rendering her blind), is nearly harmless, and is sought out by people hoping to evade the sun on hot summer days.
Also, Flandre Scarlet, an eternal (literally) Cheerful Child who loves to play with the humans who visit her home, and has absolutely no control over her ridonkulous levels of magical power. Even Marisa, who has faced all of those mentioned above and then some, makes it a point to avoid ever meeting Flandre whenever she goes to the Scarlet Mansion to steal books, not-so-subtly implying that she scares the crap out of her.
Also deserving of her own bullet-point is Cirno after starring in her own Gaiden Game, Great Fairy Wars. For all that she's rightfully regarded as the seriesdumbass, she shows the near-unique ability to destroy enemy projectiles in flight without using a spellcardnote Only above-mentioned Youmu has shown a similar skill, in a much more restricted way. Also, unlike every other PC, who only get knocked around when they lose a life until they take enough minor injuries/Clothing Damage to have lost a fight, Cirno out and out dies every time she gets hit, letting her fairy-issue Resurrective Immortality take over before flying back onto the field, unfazed.
The Black Baron of MadWorld. An Uncle Tomfoolery who is constantly killed by his own deathtraps and girlfriend, it's hard to believe he poses any real threat, even when he turns out to be the final boss. Most players saw an easy fight...and then he goes Super Saiyan, kicks at you with lightning and punches you with a black hole. Sadly, when he meets his final end, he's reverted back to his moron stage. This is much more evident in Anarchy Reigns, where he's a playable character and a boxer armed with flaming Power Fists.
In one instance of The Lord of the Rings Online, Radagast the Brown walks through a wight-infested swamp talking to little animals while the players have to fight all around him. In the end, he incapacitates who seems to be the endboss with a single hit, saving the players.
In this case, Emil seems to take a leaflet out of Neville's book here; over time, Emil loses the coward part of himself, even pulling a few moments of role reversal on Marta when the latter isn't up to her best (the pair lampshade this in an aptly named skit named "Role Reversal"). In fact, in the very last chapter of the game, he out and out seals away the Ratatosk side of his personality, and you get to play as Emil himself in battles from that point onward.
Princess Peach when she decides to fight. In "Super Mario Adventures" where, after being kidnapped by Bowser, she easily breaks herself out, finds out Mario has been captured trying to rescue her and proceeds to break back in and rescue Mario. Likewise, in Super Princess Peach, Mario and Luigi are captured and the whole kingdom is thrown into chaos because of out of control emotions, but Peach saves the day.
Wario seems to be nothing but a fat, greedy slob with clumsy tricks that almost never work out. Then when his money is stolen (or he sees the opportunity to get more), he goes piledriving dinosaurs and beating the Artifact of Doom so hard, it cries before exploding.
Toads seem to be nothing more than weak, clumsy, cowards, but there are many heroic Toads that step up to the plate to save the day along with the Mario Bros.
UDON played with this in the Street Fighter Legends, where Dan briefly managed to tap into the Dark Hadou, only to trip and fall on his face before he could attack.
There's also Rufus, a morbidly obese and rather unintelligent loudmouth who is one of the most agile characters in the game despite his size and is more than capable holding his own with the other fighters. Many who fight him comment on just how deceptively powerful he is and fathom how strong he could be if he just lost weight.
Travis Touchdown, the main character of the No More Heroes series, is a very skilled swordsman, Made of Iron, can move at superhuman speeds and transform into a tiger, owns a Humongous Mecha the size of a large building and could probably cut an average human to pieces in the blink of an eye...if he's not too busy pleasuring himself to Moe Anime, playing video games, or clumsily hitting on his female opponents..
The Vortigaunts in the Half-Life series are an entire species of this trope. In Half-Life and its expansions they're a relatively weak mid-level enemy slaughtered by the dozens and used as manual labourers by the more powerful members of the Nihilanth's army. By Half-Life 2 they are freed from their enforced servitude and join Earth'sLa Résistance against the Combine, providing Gordon with cryptic statements and the occasional charge for his HEV suit. At the beginning of Episode One however they render the nigh-unstoppable GMan completely powerless, saving Gordon and Alyx in the process, and when three of them are faced with an army of Antlions in Episode Two they proceed to slaughter every last one, then use what is essentially Antlion feces to raise Alyx from the dead. Given that they were at the time also hunting and presumably killing the horrifically powerful Combine Advisors, hopefully they will return for the expected battle/s with them in Episode Three.
Maeda Keiji from Sengoku Basara is usually a laid-back, jovial guy who enjoys drinking, partying, chasing girls and generally goofing around. He can also carry around a BFS that's over six foot long with one hand and happens to be one of the most powerful characters in the series. To name a few instances, he's capable of sending Hideyoshiflying with a punch, can defeat Ieyasu & Mitsunari in the third game AND tame both Yukimura and Masamune in The Movie even when both pairs tag teamed him (note - it takes Yoshihiro, Kanbe and Muneshige together to do the same thing against the former duo), and most impressively, is the only character who has been shown to be capable of disarming Yoshiteru, the undefeated shogun of Japan. He'd be much more of a threat if he wasn't such a Martial Pacifist.
Dick Gumshoe barely passes as a detective, and despite his woobiesh qualities, he deserves most of the punishment he gets for his screw ups. But when someone he cares about is in danger, like Edgeworth, Maggey or Maya, he gains a drastic burst in competence. In 3-3, he's a surprisingly accurate source of information for Phoenix, gives the more important pieces of evidence to him and stands up to Tigre without even blinking, saving Wright and Maya from a possibly gruesome conclusion. All for his crush, Maggey. He has fought of members of both a Yakuza crime boss and a group of Mafia thugs, showing up the next day completely uninjured. In the third case Investigations he repeatedly breaks away from Lang's men in order to give Edgeworth an important piece of information and in the fifth he actually pulls out a Big Damn Heroes moment (though everyone was doing it by that point). In the second game he was part of an investigation where armed SWAT teams tracked an assassin, led them to his hideout and stole vital evidence from there while there was a firefight going on, then drove top speed to the courtroom through the busy LA streets, only stopping when he crashed, and even then, he was conscious and determined to keep going for a few seconds. He later turns up with little more than a bandaged head.
While you don't see it onscreen, the wimpy and easily-ignored Ron DeLite is also the Gentleman Thief Mask DeMasque.
Phoenix Wright himself. He does double duty as the world's Straight Man and Butt-Monkey; is often behest to the whims of his immature sidekicks; and in the first two years of his career defeated three of the best prosecutors out there—including one who had not lost a single case in forty years of practicing law. And the head of the State Police force, and a man who can blackmail Presidents. He's also bounced back from a host of bizarre accidents with minimal injuries (falling from a burning bridge into a fast river and getting a cold, or getting hit by a car and flung thirty feet headfirst into a pole, then walking away with only a sprained ankle). Also, one time when his assistant is in danger, he breaks down a steel-reinforced door.
This is taken to insane extremes in Marvel vs. Capcom 3. As a fighter, Wright starts out with a pretty limited moveset with bad movility, but once he gains enough evidence, he enters Courtroom mode, and then can activate Turnabout Mode where he temporarily becomes insanely overpowered, plus having the most damaging Level 3 Hyper Combo in the game.
Missile in Ghost Trick. It's just an adorable Pomeranian who doesn't understand certain human concepts and barks excitedly at everything. At the end, it is revealed that Ray, the desk lamp who guided Sissel at the start of the game was actually the time-travelling Missile. It failed its first try at saving Lynne and Kamila on its own, and thus chose to go back 10 years and wait the long span of time (especially long in dog years) for Sissel to appear so it can convince, or rather mislead Sissel into saving the two girls.
The Khajiit, a race of Cat Folk native to the deserts of Elsweyr in southern Tamriel, have a reputation for being rather simple and often morally ambiguous. Their language has no word for "rules" and they take a rather loose view of what constitutes "personal property," frequently getting them in trouble in the lands of other races where what they do is considered "theft." As a race, they are also highly susceptible to Moon Sugar addiction, as well its stronger derivative Skooma. Given all of this, it is not surprising that they are frequent victims of Fantastic Racism. Despite it all, however, they are not a race to be underestimated. They are capable warriors with a number of Fantastic Martial Arts and have no qualms with using underhanded tactics to win. In a border dispute with the Bosmer (Wood Elves) known as the "Five Year War," the Khajiit defeated the Bosmer and extended their territory with the use of tactics including the "vertical ambush." When the Khajiit broke the war-ending truce and continued their attacks, the Bosmer were forced to use the Dangerous Forbidden Technique known as The Wild Hunt, in which they irreversibly turn into terrible monsters in order to finally stop the Khajiit. Even the AldmeriDominion in the 4th Era got the Khajiit to join as vassals rather than via conquest, looking to avoid open conflict with the Khajiit.
The Argonians, a race of Lizard Folk native to the Black Marsh in southeastern Tamriel, are viewed with extremeFantastic Racism by the other races and are thought to have a thoroughly uncivilized culture. They were a flat out Slave Race to the Dunmer for thousands of years and were not treated much better by the rest of Tamriel. Their lack of typical human facial features leads many of the other races to view them as The Stoic, incapable of feeling or showing emotion (which is decidedly untrue). This all began to change around the end of the 3rd Era when the Hist (ancient, sentient, and possibly omniscient trees native to the Black Marsh who the Argonians worship) had a vision of the upcoming Oblivion Crisis and the trials that would follow. They recalled most of the Argonians in Tamriel to the Black Marsh where the Hist, through their sap which the Argonians drink to communicate with the Hist and grow, began to transform the Argonians into greater weapons of war. During the Oblivion Crisis, the followers of Mehrunes Dagon had to stop setting up Oblivion Gates in the Black Marsh because the Argonians were driving The Legions of Hell back and invading Oblivion itself. One of their favored tactics within their homeland is to drag their enemies underwater and hold them there until they drown. Later, when the RedYear decimated Morrowind, the Argonians invaded the homeland of their long time oppressors and conquered most of the still-habitable areas of Morrowind. By the 4th Era, the Argonians are considered only one of two races who could fend off a full scale attack by the Aldmeri Dominion. (The other being the Redguards of Hammerfell.)
The Tang Mo, an Akaviri race of "monkey-folk", are described as kind and brave but also simple and mad. Despite this, they are capable of raising armies when they must and have successfully defended themselves from attack by all of their hostile neighbors (which include the Kamal "snow demons" and the Tsaesci "snake vampires").
From Skyrim, Cicero the jester. He's a crazy loon dressed up like a complete idiot. He's also the Keeper of the Night Mother (meaning he was chosen by the Void to be the Night Mother's protector) and a deadly knife fighter. When he snaps after Astrid dismisses the Night Mother one time too many, he nearly kills the entire Dark Brotherhood in his fury. The guy who pursues him — a werewolf — nearly gets gutted for his troubles, while Cicero is apparently unharmed though he plays possum.
Sonic the Hedgehog: Big the Cat. Yes, that Big the Cat. He was originally voiced by Jon St. John, is now voiced by Kamina. He Took a Level in Badass in Sonic Chronicles: The Dark Brotherhood, where he started acting like a smart-ass. On top of this, he can lift cars over his head and uses his fishing rod as weapon with which to demolish giant robots and flying battleships and is capable of turning it into a mace with a giant spiked ball, usually taking out any enemy on screen. On top of this, he can catch bullets in mid-air, something that not even Sonic can do. Oh and as mellow as he is, don't threaten one of his friends, especially Froggy or Cream.
Sonic himself can be this sometimes. Extremely laid back, constantly cracking jokes and running headlong into danger without a thought, he will regularly destroy entire armies of robots by simply jumping and spinning. Also, God help any bad guy if he gets together the seven Chaos Emeralds or, even worse, the Super Emeralds.
Katze Kotolnos from Endless Frontier is a Camp Gay cat person who is constantly making passes at protagonist Haken Browning. Then there comes a point where you have to fight him and he proceeds to kick your ass with his hands in his pockets. When you first fight him, he fights alongside Ezel, who you've been chasing for a while, and who wears an intimidating skull helmet and looks like a total badass. Katze is the more dangerous of the two.
Hewie of the H-Game Castle Fantasia 2 Renewal is this to degree. He acts a carefree moron who always sent one of his team member angry over and over again, but turns out he's a very great war strategist.
Piu-Piu of the Chaos Rings series for IOS devices. He's a short, weird looking humanoid who runs his mouth about random stuff, owns a shop to sell weapons, armor and other items is a greedy bastard, a cheapskate, and such a God-damn perve that when they tried to create the first Agent Prototype off of his given up perversion, it created a giant, red demon named Libido. He's the least likely person but then you realize in the second playthrough of the game that he actually is the leading scientist behind the Ark Project and that it was him who actually built the Ark spaceship and discovered Time Travelling. Then you make the mistake of challenging him, which makes you enter a bonus boss battle so hard that it would give every other boss in the game a run for their money.
The Aforementioned Boss: "I love you guys!" *shoots a giant Qualia jack-n-the-box at you*
Captain Quark of the Ratchet & Clank series. Despite being both a coward and an idiot, Qwark has managed to surprise Ratchet, Clank, and their enemies with bravery and cunning that lives up to his big-hero bragging. He helped Ratchet and Clank destroy Doctor Nefarious' Biobliterator in Up Your Arsenal, worked as a mole against Emperor Tachyon to steal vital information in Tools of Destruction, aided in defending the Fongoids from invasion and helped them escape a warship after they (and he) are captured, went undercover to steal plans from Doctor Nefarious to help Ratchet find Clank in A Crack in Time, and is one of the playable heroes in All 4 One and Full Frontal Assault.
Cielo in Digital Devil Saga. Usually a calm and cheery ALBINO BRAZILIAN WITH JAMAICAN ACCENT, until a guy from the security eats his comrades in order to get power. Cielo proceeds to make a badass speech. There's also the time that in order to protect Sera and Serph, he destroys two fighter jets by chewing on their pilots and cutting their wings, dying in the explosion.
Karl Blaine in Just Cause 2. Even before Rico meets him, he's established as the unreliable, comedy relief contact on the island nation who you have to rescue from a government sting. Later, Blaine's captured and successfully interrogated as years as a drunk in a tropical paradise have left him soft and out of practice as a spy. Much later, during Rico's assault on the evil president's hideout, Blaine sneaks out of his cell BY HIMSELF, and gets past the ninja guard to suicide bomb the President without any assistance from Rico.This doesn't stop Rico from taunting him for giving into the torture, however.
Roger Wilco will even admit he's far from the sharpest knife in the drawer. Hell, he's a marginally competent janitor who is prone to taking on-shift naps in the closet. When "it" hits fan, though? Tricks a nasty creature twice his size into blowing itself up. Kills an entire ship worth of Sariens to prevent them from nuking his home planet. Stops an evil genius from invading his home planet with a clone army (granted, it was an army of insurance salesmen...), rescues two programmers from slavery and beats their Bad Boss with a Humongous Mecha, destroyed the evil genius in a rematch after the evil genius took over his homeworld, took down the Confederation's shiny flagship with a garbage scow, and stopped another mad scientist from committing Grand Theft Me on a close friend. Do not piss off the Almighty Janitor!
Laguna is this in Final Fantasy VIII and Dissidia: Final Fantasy Duodecim. In the original game he's a goofy, laidback soldier with a terrible sense of direction who becomes the head of a rebellion to overthrow a sorceress and then the leader of the world's largest and most advanced nation. In Dissidia, he's as goofy and directionless as ever, is the only character to have no magic but still stands up to world destroying demi-gods like Sephiroth, Kefka and Exdeath. His boss is Cloud of Darkness, who is literally the personification of darkness itself.
If not even Vaan takes your directions seriously, then you go ahead and snipe Chaos you're probably this.
The Manga adaptation of Ocarina of Time seems to interpret Link this way, in contrast to his very serious and stoic appearance in the game. He's very sweetly boyish and mischievous, at times outright silly and clumsy, up through a large part of the manga - at least until the Bad Future elements of the adult section start to sink in.
The shopkeeper from the Fantasy Quest turns out rather more adept that his demeanor suggests.
Wheatley from Portal 2. The "moron" is intentional as he's "the product of the greatest minds of a generation working together with the express purpose of building the dumbest moron who ever lived." This, however, precludes the fact that he was the person who woke Chell in the first place, willingly performed a series of personal efforts that he had been told would kill him, came up with the plan to sabotage GLaDOS's turrets and neurotoxin production, managed to outsmart both Chell and GLaDOS by laying a trap that relied on them assuming he's too stupid to do it properly, and demonstrated an incredible amount of foresight when it came time for the final battle. In the last case, Cutscene Power to the Max is the only reason Chell survives; without that, Wheatley would have succeed where GLaDOS failed. Of course, he fulfills his programming in that even if he managed to win... he still would have blown himself up because he couldn't be bothered to figure out how to keep the reactor core powering the facility from overheating.
In Team Fortress 2, we have the Pyro, though he is more of a Crouching Badass Hidden Moron. A monstrous creature that instills fear in everyone, even to the people on the same team. It destroys everything in its path and leaves no survivors. It seems unstoppable, sadistic, and completely merciless, spreading chaos wherever it goes...but in its mind, it's in a beautiful wonderland, with fairies and giant lollipops and presents scattered across the land. It just wants to spread happiness and joy, blowing bubbles everywhere, while a constant loop of Do You Believe in Magic by The Lovin' Spoonful plays. The Pyro is a badass and isn't even aware of it.
Heavy: "I fear no man...but that...thing...it scares me"
Nanashi in Duel Savior Destiny is a complete ditz and has a tendency to accidentally lose her limbs, but it turns out that even without an Aether Relic she's so strong that she can match up to even Taiga and Lily, the strongest members of the playable cast. Another example is with Dahlia, though we know from the beginning that she's exceedingly competent.
Super Robot Wars UX: Richard takes up a foreigner act and uses a dialect, which consists of a mixture of easy words from languages, to pretend he's not a serious mercenary when he's on cover missions with Saya. Agnes is completely fooled by this and thinks they are comedians (comic story tellers).
PJ Berri in Parappa The Rapper is very shallow and lazy and pays minimal attention to his surroundings, especially compared to the more exuberant Parappa. However, he's a talented DJ who was performing on stage long before Parappa ever got to.
Lammy from Um Jammer Lammy is neurotic, so socially awkward that she can barely hold a conversation and basically useless unless her guitar is involved, at which point she becomes an unstoppable, optimistic rock goddess able to do whatever ridiculous, dangerous things she has to.
Gumpy from Jagged Alliance. He's one of the squad's explosives experts. He's also unfortunately an overweight, unattractive dork who cracks outdated pop-culture references with a speech impediment and nasty allergies, and as you'd expect, he can't fight for shit. However, if you and your badass mercenaries can keep him alive for long enough, his high Wisdom score and aptitude for learning ensure he will eventually become just as badass and competent as the rest of the mercs.
Star Control has the entire Spathi race. They are ridiculous, they are hilarious, they are easy to push around. They are also dangerously intelligent, cunning, and militarily competent if pushed into a corner. It would be very unwise to underestimate their abilities when their backs are against the wall.
Starbase Commander: The Spathi are like a cowardly, mobile clam... armed with a Howitzer.
Okuni in Samurai Warriors. In her levels, she calmly walks into a raging battle talking about her need to raise money for her shrine and whether this would be a good place to dance, and calmly walks out the other side of it after having beaten everyone in both armies senseless with her Parasol of Pain. Later games seem to have changed her personality a bit, making it seem like her ditzy appearance is done deliberately on her part and that there's a much colder and more cunning mind lurking below the bubbly surface.
Teddie from Persona 4: At the start of the game this hollow bear appears to be an animate suit with no guts, literally or figuratively. He has no combat capabilities until he tried to defend his friends from a powerful shadow. After his own shadow is defeated it becomes the persona Kintoki-Douji, granting Teddie combat capabilities including powerful ice moves and incredibly effective healing abilities. His capability of finding a date, however, remains dismal.
Junpei Iori from Persona 3 is established as an idiot early in the game, but when someone he cared for is murdered his Persona Hermes transforms into Trismegistus. Immediately after the transformation he attacked the ones who stole his loved one from him with a massive fire attack in a fit of rage. While he still behaves as a loveable idiot throughout the game he acts more maturely in serious situations.
Fallout: New Vegas: Benny seems like a rich asshole in an expensive suit, and his relationship with his benefactor comes across as a spoiled rich kid trying to overthrow daddy because he's too greedy to know any better. But before Mr. House revitalized the Strip, the area was under the control of a number of raider tribes. Benny became leader of his tribe by killing the previous leader in fair combat, and then agreed to work with House. In the tie-in graphic novel All Roads, one of the Great Khans he is crossing the wasteland with reacts with shock to the revelation that he used to be a tribal. His friend responds that "It's midday and he's setting the pace. You tell me."