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Susana Cabeza de Vaca from Mount Dragon. Replace baka with pendejo and hijo de puta, make her dark-skinned, and you have a Mexican tsundere! Insanely proud of her royal heritage and her genius, she almost immediately shows dislike for the main character, who dislikes her right back, and most of the sideplot are the two slowly growing closer and closer, grudgingly respecting each other and, of course, slowly growing attracted.
The rose from The Little Prince by Antoine de Saint-Exupery. The book turns a tsundere flower into a commentary on the pain that love can cause so hauntingly beautiful that it will drive you insane.
About half the women in the Wheel of Time series are tsunderes, and to varying degrees. To whit: Nynaeve starts out a major type A but marriage softens her to a B; Min isn't; Elayne isn't, although Rand probably thinks she is due to mixed signals in a couple of letters; Moiraine isn't; Egwene is usually a Plucky Girl but turns into a raging type A in the second half of volume 12, especially when confronted with her Love Interest; Siuane is a type A, but that's to be expected from a SpanishIron Lady; Faile, despite her rep, is just a Clingy Jealous Girl trying to keep her husband away from Berelain. Oddly, the most pure example (up to and including the classic "this doesn't mean I like you" line) is the often overlooked Tuon.
Aravis Tharkeena from C. S. Lewis's The Horse and His Boy. Her Tsundere-ness is lampshaded at the end of the book, when it's mentioned that she and Shasta/Prince Cor got married because they were so used to their Slap-Slap-Kiss that they wanted to be comfier while fighting and then making out.
In Sandy Mitchell's Warhammer 40,000 novel Scourge the Heretic, Keira's normally not personable manner is considerably worse toward Mordecai Horst, being blind to it herself. It doesn't help that she was raised in a Sex Is Evil cult. But when she accuses Danuld of wanting to sin with her, and he says it's obvious that he has no chance because of Mordecai, she reacts badly but later returns to question him about what he meant, and then, with obvious difficulty, attempts to temper her behavior toward Horst. (And she resolves to consult another woman in the Inquisitor's retinue about whether sex really is so evil.)
Adora Belle Dearheart from Terry Pratchett's Going Postal, though she's more dere-dere towards the golems with which she works at the golem trust.
The Demigod Files basically make it canon. Annabeth's questions include 'What is Percy Jackson's most annoying quality?' Her response could have been taken right out of any Japanese anime, including the hilarious-to-a-troper line...
In The Demigod Files, when Beckendorf tells Percy that Annabeth likes him, his response is: "Yeah, she likes me... for target practice."
She acts mostly tsun in the first book (The Lightning Thief) and has clear traits of both sides in The Battle of the Labyrinth (book four).
Clarrise takes the "fight through life" portion of this to heart, (since she's the daughter of Ares) and we only see her kind side after she saves Chris Rodriguez from the Labyrinth and attempts to nurse him back to sanity.
In Twilight Dragon, Keaira Aleshire fits this trope to a T, and she doesn't just act this way towards her crush.
Karrin Murphy in The Dresden Files keeps calling Harry names, even beats him to a pulp on a few occasions, but mellows at the moment's notice whenever he hurts himself badly or saves her life (again). Pointing that out to her, however, is likely to earn you another beating. This only holds true for the first two books or so. Afterwards, they still bicker, but they're a lot sweeter to each other.
Diana from the Gone series, whenever she's around Caine.
Elinor Wylie's poem "Nancy," referenced on the quotes page, seems to be addressed to a Type A.
Tenar from the Earthsea Trilogy, at least in The Tombs of Atuan. By the time we see her again two books later, in Tehanu, she seems to have grown out of it.
Bridget Jones from Bridget Jones's Dairy is type A thanks to the way she expresses herself in her diary (being annoyed.) She, however, is lovestruck with Daniel Cleaver even though she's being sarcastic to him at times.
Marcia Overstrand in Septimus Heap. While normally being easily irritable and bossy, she can become very caring at times of trouble.
Cecilia Tallis from Atonement towards Robbie. She isn't quite sure of her feelings towards him and convinces herself that she'll be happy when he leaves for medical school. Robbie himself is actually a Type B towards her, mostly playing the part of the nice guy. But then he writes her a very rude letter in a fit of passion that she accidentally reads. Ironically that helps them confirm their feelings for each other. Cecilia's younger sister Briony is a Yandere towards Robbie.
In Warrior Cats, specifically in Bluestar's Prophecy, Bluestar was seen as a clear Type A tsundere example towards her mate Oakheart. She would lose all her patience with him and was quite snappy, especially when she was in denial about her feelings for him since she couldn't be mates with a cat from another Clan. Despite this, Bluestar geniunely loved Oakheart and since their parting, he was the only cat she ever truly loved.
Sandstorm is also a tsundere. She was distainful and looked down on Firestar due to his kittypet blood, but when he saves her life during a border fight, she realizes that she misunderstood Firestar and develops a strong bond and friendship with him. Sandstorm fell in love with Firestar at one point and they had a long-standing relationship. Though Sandstorm is regarded as a sharp-tonged, short-tempered, and independent she-cat and Firestar is not spared because of her feelings towards him, he still has healthy respect for her.
Sandstorm's daughter, Squirrelflight, became a second generation tsundere, since her mother passed her personality to her. Squirrelflight is the most fitting to this trope since in some ways, is even worse than Sandstorm. Squirrelflight is a proud, independant, incredibly impulsive, very rude and a spitfire of a warrior, making her a Type A, though she agruably had mellowed out with age. Squirrelflight's relationship with her mate Brambleclaw was that of any Main Character/Tsundere couple. She was greatly annoyed with his bossy attitude and hated him. Over the course of the The New Prophecy Series, Squirrelflight fell deeply in love with Brambleclaw and they got together.
Yellowfang, the prickly medicine cat of both Shadow Clan and Thunder Clan. She is often characterized as grumpy and obstinate, with a tongue described as "sharp as thorns." However, she holds a surprising amount of inner compassion in her heart despite her rough exterior; her softer side was usually brought out through her relationships with Cinderpelt (her apprentice), Raggedstar (former mate), Brokenstar (son) and Firestar (who she claimed was like a son to her while on the verge of death).
A male example of tsundere is Crowfeather. He is usually constantly angry and foul-mouthed but had a hidden side of friendliness with his first love Feathertail and later Leafpool. Crowfeather also showed this with Tawnypelt, Brambleclaw, Squirrelflight, and Stormfur to a lesser degree, who he grew friendship bonds with eventually. However, seeing Crowfeather's nice side is very rare.
Fittingly, one of Crowfeather's sons took after his father as a male Tsundere. Jayfeather was very sarcastic, insensitive, and short-tempered, particularly as an apprentice, but mellowed out somewhat when older. He's not the most friendliest cat, but values loyalty and has compassion for others more than even his father. Jayfeather's softer side is more seen with his siblings and Half Moon, the cat he fell in love with.
Shades of Grey: Jane. She is so Tsun, the Dere throws you off rails, but suddenly there it is.
Light And Dark The Awakening Of The Mageknight: Instead of the 'ulra-violent mood swinging' of the modern tsundere, Sabrina is more like the classic tsundere. Her 'civilian mask' is friendly and sweet but she's actually aloof and focused on knight training. When she develops feelings for Danny she stubbornly refuses to acknowledge them yet still shows tantalizing displays of affection.
Song at Dawn: Oddly enough, Estela is not this to either Arnauld or Dragonetz but to Nici, her pet. She calls him 'useless', the name she gave him means 'big idiot' and yet she is the only one to pet him, and she feeds him under the table. In the end, he's described as 'a dog that thinks he belongs with her'. In other words, Type A.
Shakuntala of Belisarius Series is a wilful, charismatic princess, that is nice enough, but clearly not one whom you wish to make angry.
Vin from Mist Born. Being abused by Reen for most of her life in order to help her survive did...not help her emotional stability. Neither did having a Hemalurgic spike that let Ruin talk to her. But she's a solid Type A around the crew, and especially Elend, once she starts to warm up. Toward the end of the trilogy, she's moving toward Type B.
Eugénie Danglars from The Count of Monte Cristo is a pretty extreme example, being cold, aloof, and unfriendly to her family, her friends, her acquaintances, and her fiancé(s) and even telling her father that she loves no one and nothing except her studies of music and art. Yet the second she's alone with her vocal coach/friend/lover Louise d'Armilly, she's warm, playful, and affectionate, even calling Louise things like "my sweet" and gently teasing her for being unable to close an over-packed suitcase.
Midori, the teenage main character of Higuchi Ichiyō's Takekurabe, is very much this towards Shinnyo (a timid and taciturn future monk). She calls him names and rants about how she doesn't want to have anything to do with him, but can't quite bring herself to admit that she has feelings for him (and she never does explicitly even at the end). It doesn't help that Shinnyo's attempts to be "nice" to her early in the story all end up being awkward and rather offensive.
Skeeter Traps from Chronicles Of Magic is a Type A who tends to be brash, violent, and rude most of the time; only to show her softer, more compassionate side when everyone least expects it. She also follows the tsundere way of totally denying her feelings for the boy she loves (even to herself), believing him to be an idiot. However, she is a ten year old girl trained by spies and outlaws, so maybe she should be cut some slack.
Duff Obama in the Web Serial Novel parody How To Survive A Zombie Apocalypse has traces of this. While her tsun mode is not as harsh to qualify for once, she finds it surprisingly difficult to show more tender emotions, thus masking them as anger or irritation.
Collin: You may be strange and all... but you're a good person.
The title character of Anne of Green Gables is an extremely sweet, warm, and expressive girl always searching for kindred spirits, but say something insulting about her red hair and she will reveal a temper to match. This is her Berserk Button. She reveals her tsuntsun side to people other than her love interest Gilbert Blythe, but her rage towards him (for making fun of her red hair) is significant, and indicative of Belligerent Sexual Tension.
In the Night World book Daughters of Darkness, Mary-Lynnette is dere dere, but when Ash is around her automatic reaction at first is to kick him in the shins. Doesn't help that he's sexist and speciesist.
Hermione Granger from Harry Potter. She's a good friend who is sensible and restrained a lot of the time, but DO NOT tick her off. She will show no mercy. Just ask Rita Skeeter, Draco Malfoy, Dolores Umbridge, Marietta Edgecombe or Ronald Weasley.
Teenager Lily Evans seems to be interpreted this way by the fans, especially in James Potter's presence.
Luke Skywalker becomes a Type B Tsundere in the Star Wars novels.
Mel from Crown Duel is a type B to such an extent that Shevraeth has to resort to wooing her through anonymous letters.
Leafpool from the Warrior Cats series became a Type B tsundere over time. She was originally, while an apprentice, a very meek and soft-spoken individual with a calm and controlled profile, much different from both her mother Sandstorm and sister Squirrelflight. As she got older, Leafpool became more bossy and ill-tempered, becoming a full-blown Type B Tsundere in The Power of Three. Leafpool still is usually very gentle and kind despite a slight temper. She is both a romantic and non-romantic example. Leafpool was annoyed by her former mate Crowfeather's prickly attitude, but realized that she actually loved him when he confessed his love after saving her. The non-romantic example of this is her relationship with Jayfeather. Leafpool loves her son dearly and is protective over him, though they often got into arguments since her son had inherited Crowfeather's personality. This was especially seen when Jayfeather was her apprentice, her patience always being a short fuse with him particularly.
Aglaya from Dostoyevsky's The Idiot. Not only does the girl spend half the novel telling her love interest how stupid he is, the whole thing actually ends with a big girl fight-out over the guy. This is proto-anime writing at its best!
Demons's Marya Ignatyevna is also an example of tsundere. She spends most of the chapter A Woman Traveller verbally abusing Ivan Shatov but by the end becomes extremely clingy.
Also, in The Brothers Karamazov Lise acts rather tsundere to Alyosha, teasing him in order to get his attention and then blushing. Father Zosima calls her out on it.
Princess Irene is this to Dor early in the series.
Dor's mother, Chameleon, actually has this as a plot point; her magic talent is that she slowly switches between a very sweet (but dumb as a brick) beautiful woman, and a very sharp tempered (but brilliant) ugly woman over the course of a month. Her husband, Bink, prefers her somewhere in the middle.
Tandy is very Type B, but her magic talent is "throwing tantrums" which have the impact of a grenade going off, so when she gets mad you know it. But her husband, Smash, is an ogre and finds this adorable.