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- Ghost Rider has one that's on fire.
- Judge Dredd:
- Judge Mortis has a cow skull for a head, representing the Horseman Famine.
- Fink Angel has lost his lips and most of his nose, which makes his face look eerily similar to a skull.
- There's a demon in The Grievous Journey of Ichabod Azrael (and the Dead Left in his Wake) who commands Charon, and also has a cow's skull for a head.
- Bludgeon in Transformers tends to have this; in G1 it's just the face of his Pretender shell, but the movie version has this as his main robot head.
- While the original character was just a guy in a mask, some versions of Captain America's Arch-Enemy the Red Skull qualify:
- After having his consciousness transferred into a cloned duplicate of Captain America's body, the original Red Skull accidentally inhaled a dose of his own "Dust of Death" - a chemical similar in effect to Joker Venom. Ordinarily, the Red Skull's dust kills its victim, while also transforming the head into a red skull. In this case, due to his cloned body's Super-Soldier Serum, the Skull didn't die, but merely gained an actual red skull for a face.
- The Red Skull's daughter, Sin, suffered a similar fate, but her face looks like a red skull due to relatively "normal" disfigurement - an explosion and severe burn damage.
- His Ultimate counterpart is Captain America's sociopathic son who skinned his head because of his resemblance to his father.
- Franklin Richards in Marvel's MC 2 gets a dose of cosmic rays, giving him new energy powers that burn the flesh off his head and require him to wear a mask.
- Death's Head, a freelance peacekeeping agent who appeared in Marvel's Transformers and Doctor Who comics.
- Borderline example: the Doom Patrol archvillain the Brain is a Brain in a Jar perched atop a chess piece-like pedestal. The upper portion of the pedestal is designed to look like a skull.
- Batman villain the Black Mask originally just wore an obsidian mask. But Cameron Stewart, artist of Catwoman 14 drew him with a blackened skull which later writers picked up on.
- In the B.P.R.D.-verse, a Nazi supervillain known as The Black Flame had a skull wreathed in black fire. Decades later, one Mr. Pope from Zinco Enterprises takes up the mantle of The Black Flame; he wears a skull-shaped helmet.
- The Blue Knight of Astro City wears a face mask that projects a holographic skull.
- One What If? story showed a world where Captain America came into being during The American Civil War when Native American magic gave skinny Union soldier Steve Rogers a body to match his heart. His racist commander "Bucky" Barnes was likewise affected by the spell, turning his head into a fleshless skull and causing him to become the villain White Skull.
- Skully/Cranicola of Brazilian comic Monica's Bug-a-booo is an extreme case: he's a skull that lost its body and lies atop a rock.
- The WildC.A.T.s villain Helspont has a flaming horned skull for a head due to his possession of Acuran host.
- Atomic Skull (Joe Martin) from Superman.
Films — Animated
- A plot twist in Wreck-It Ralph: the character of Turbo, the protagonist of a racing game, has chalk-white skin, sunken eyes, and yellow, grinning teeth. Guess who's the bad guy...?
- The mechanical Cat Beast from 9 has an actual cat's skull incorporated into its head.
- The Horned King from The Black Cauldron is a horned variation. While he's an undead evil sorcerer, the rest of his body looks quite normal compared to his positively skull-like head.
Films — Live-Action
- Time Bandits. Evil's minions include tall humanoid creatures with giant claws for hands and cow skulls for heads. As seen here◊.
- The Marvel Cinematic Universe version of the Red Skull in Captain America: The First Avenger had his previously normal face transformed into a literal red skull due to infusing himself with an incomplete Super Soldier Serum.
- In Star Wars: A New Hope, Elis Helrot, a member of the Givin species, can be seen in the cantina scene.
- The hybrid alien from Alien: Resurrection has what can only be described as a skull face.
- General Grievous from the Star Wars Expanded Universe — his head/helmet generally resembles a skull.
- The Headless Horseman in The Legend of Sleepy Hollow, albeit briefly.
- Skulduggery Pleasant
- Arguably, Bob the Skull.
- And in Ghost Story, Evil Bob. Specifically, when Harry and the Lecter Ghosts assault the Nevernever entrance to Corpsetaker's lair, Evil Bob takes the form of a Nazi SS officer with a skull for a head.
- The Phantom of the Opera, before Adaptational Attractiveness set in.
- Monty Python's Flying Circus. In a sketch about a hospital for overacting, there's a brief animation of actors portraying Hamlet giving his "To be or not to be" speech. At one point they pull the flesh off their heads, leaving them with only their skulls on their shoulders.
- The Master does this in the Doctor Who finale The End of Time. Due to an accident during his resurrection, he's burning up life-energy faster than he can take it in, which results in his skull showing through his skin. He had a skull-like face earlier, in "The Deadly Assassin," but it applies even more here, because the Tenth Doctor even calls him "Skeletor."
- There is an episode of Boy Meets World, where the gang is in detention and being stalked by a killer who wears a skull mask.
- Kamen Rider:
- Emperor Gruumm from Power Rangers S.P.D.
Mythology and Religion
- Older Than Print: The gods Cihuacoatl and Mictlantecuhtli, in Aztec artwork, each have a form where they have a skull for a head.
- Baron Samedi, perhaps the best known deity of North American voodoo, usually gets portrayed as having a skull face. Countless impersonators have mimicked the look with makeup.
- Dungeons & Dragons:
- The Gambado from the 1st Edition Field Folio.
- In Module I12 Egg of the Phoenix, the cleric MacKurian's dead body had a cow's skull attached to it. It is later changed into a revenant form and occupied by MacKurian's spirit, leading to the final confrontation with Doc.
- One of more freakish monsters in Forgotten Realms is "lichling". A 6'' cockroach with human arms and legs and skull-for-a-head, feeding on the fear, immune to normal weapons and thus hilariously lethal. It can slowly grow to 80' long, but is likely to be destroyed sooner. They're spawned by demiliches. In thousands.
- Black Dragons are sometimes nicknamed "Skull Dragons" because as they age, their acidic breath degrades the flesh and scales around their face, which combined with their already sunken eyes gives them a distinctly skull-like appearance.
- In Warhammer 40,000, Space Marine Chaplains have skull-designed helms, as do Eversor assassins.
- In BattleTech, the archetypal 100 ton assault mech, the Atlas, features a head stylized after a human skull. Making it "as ugly and foreboding as conceivable" was explicit part of the design specs. The numerous successor models and derivatives like the Akuma keep the motif.
- Shadow Tracker from G.I. Joe (released in 2011) looks like a Predator expy, but is this trope once his mask is removed.
- The He-Man knock-off line Combo Warriors has Satana, who has skin on the right-side of his face, but the left-side is a skull.
- Skullossus from League of Super Evil has a floating expressive skull in a jar for a head.
- Dark Souls has the Darkwraith, the former knights of New Londo succumbed to the Dark. They wear skull mask with a hood, and are merged with their face over time.
- Shin Megami Tensei: While not a hard-and-fast rule, most demons of the Fiend race appear as this to signify their status as avatars of Death. The most famous of these demons include the Horsemen of the Apocalypse, the Trumpeter, and Mother Harlot, all figures from the Book of Revelation.
- Modern Warfare features Ghost, who wears an iconic skull mask.
- Ghost was so popular that his mask became the inspiration for the titular unit of Call of Duty: Ghosts, who all wear custom skull masks.
- Blacklight Retribution has the "Bonebreaker" helmet, which places a stylized skull faceplate on one of the default helmets.
- Some incarnations of Scorpion from Mortal Kombat depict him as having a flaming skull for a head.
- Most other times, it's a non-flaming skull. It's never made clear whether this is a supernatural power of his or if that is his actual head now.
- Scorpion's fellow undead Noob Saibot has an alternate costume in Mortal Kombat 4 that gives him one, too. Along with his shadow powers and Sinister Scythe, it makes him look a lot like The Grim Reaper.
- Mephisto of Diablo has this. My goodness! So horrible!
- Duskull from Pokémon.
- One can make a case for Marowak too: in its pre-evolutionary form as Cubone, it wears its mom's skull as a helmet. After it evolves, the skull's become fused to its head.
- In RuneScape, the normal form of the Mahjarrat is this when they haven't been rejuvenated for a while.
- Applies to every character in Raskulls, aside from the Pirats.
- Mumbo from Banjo-Kazooie. According to his backstory, his head became a skull because he was placed under a magic spell by the evil witch Gruntilda, who was once his student.
- Murray from Monkey Island. However, his skull is all that's left of him after Guybrush destroyed his boat.
- The Skullmonkeys and Klogg from The Neverhood.
- Like his namesake suggests, Skull Man from Mega Man 4.
- Doc Robot in Mega Man 3 predates Skull Man—Doc Robot's name is is Dokurobotto in Japanese, and is actually a Punny Name based on the Japanese words 'dokuro' (skull) and 'robotto' (robot).
- Harpies and Medusa in Will Rock.
- Rogath, one of Dage the Evil's Generals from AdventureQuest Worlds, has a horned skull for a head.
- Kirby Mass Attack: Necrodeus also has a horned skull for a head, as well as a clown-like nose on it.
- This example, combined with exaggerated Facial Horror, is the result of what happens if Lance can't escape the deadly Beautifier in Vivi's Funeral Salon in Brain Dead 13.
- Skullmageddon, the Big Bad of Double Dragon Neon (naturally, since he's a walking, talking Expy of Skeletor).
- In Little Kings Story, Cow Bones of the Cemetery, one of the UMA Guardians. Its skull comes off sometimes.
- The Jersey Devil in The Wolf Among Us is depicted as having a horse's skull for a head when he takes on his true form.
- The Atlas battlemech in the MechWarrior series, like its source material, is an assault-class Humongous Mecha with a skull-shaped cockpit, often painted bone-white. Depending on the game, it can have a laser mount in one of the eyes or Glowing Mechanical Eyes
- Concept art for Commander Rimanah in EYE Divine Cybermancy gave him a golden, grinning skull helmet, though his in-game appearance uses a serene face mask.
- In PlanetSide 2, players can purchase skull helmets that invoke this, though they are merely masks that are worn around the basic helmet. The Lumifiber Skulls introduced in the Halloween 2015, however, completely remove the user's head and replace it with a glowing holographic skull in either red, blue, or purple depending on the player's empire.
- Lord English from Homestuck has a green skull for a head, natch.
- Various characters in Coga Suro 2 adopt this look when activating their Immortal-given powers- their skin turns grey, their hair white, and their head into a grey skull that glows from within.
- Edward from Monster Pulse, since his face turned into a monster.
- Skeletor in He-Man and the Masters of the Universe (1983) and its reboot. He was simply a guy whose head looked like a skull; in one episode of The New Adventures of He-Man we even see that he has some hair up top. In the 2002 series, however, Keldor's face was melted off by a vial of acid - his life was saved by Hordak, but at the cost of his head now being a skull floating above his shoulders.
- Justice League examples:
- "Only a Dream": Dr. Destiny uses his powers of illusion to achieve this look. He reverts to a normal appearance when recovering from a punch to the face, and when he is finally defeated.
- Atomic Skull also has a skull wrapped in green fire, which he could fire energy blasts from.
- Slade from Teen Titans had this while acting as Trigon's undead servant, because in life he was burned to death by lava. As he kept it hidden behind his mask, however, it was only glimpsed a couple of times near the climax of that storyline.
- In Jonny Quest The Real Adventures, Ezekiel Rage usually gets the "Phantom of the Opera" motif, what with his face badly burned and him having to wear a white mask. His Questworld avatar, though (which we see in "The Edge of Yesterday"), actually has a skull for a head.
- The Scarecrow from the Batman: The Animated Series revamp (the New Batman Adventures) had a shriveled zombie-like face with the skin seemingly shrunk to the bone - if it was a mask or not is still up for debate.