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"Kid, I wouldn't last five minutes leading an outfit like that if I wasn't as rotten as hell."
The legendary leader of a ruthless gang of outlaws. After his most recent robbery, Wade is captured by chance and must be escorted to the town of Contention so he can be placed on the 3:10 train to Yuma to be hanged.
- Affably Evil: Wade might be ruthless to the very core, but he's also a very charming and polite man. From time to time, he's even sincere.
- Badass: He's legendary for being one of the most dangerous men in the entire country.
"Well, would you look at all this? You all spared no expense this time, Byron. I gotta say, though, it's probably cheaper just to let me rob the damn thing."
- Death Glare: The look in his eyes when he's about to shoot someone is so potent that his victims recognize it and (futilely) try to counter the coming attack.
- Holy Hitman: Ben Wade seems to either not believe in God or dislike Him, but he can exchange Bible quotes with the best of them.
- Kick the Son of a Bitch: The only members of the posse he kills are Tucker and McElroy, a bully and a killer respectively.
- Parental Abandonment: When he was a child, his mother gave him a Bible to read at the train station and promptly left to never return.
- Wicked Cultured: He has a strong interest in art and nature.
- You Have Failed Me: He kills Tommy Darden for getting taken as a hostage.
"Well, Tommy, it seems that there was a Pinkerton inside that coach that wasn't quite dead yet. Now, I know Charlie told you, because we done got but a few rules in this outfit. And this is what happens when you put us all at risk."
"Name's Charlie Prince. I expect you heard of me."
Ben Wade's vicious right-hand man. Deeply loyal to Wade, he leads the remaining gang in pursuit of him after Wade is captured in Bisbee.
- Ambiguously Gay: His loyalty to Wade borders on obsessive love, and he appears jealous of the young barmaid Wade sleeps with.
- Ax-Crazy: He's a trigger-happy psychotic.
Played By: Rio Alexander
A Mexican sharpshooter and member of Wade's gang.
- Cold Sniper: His job within the group, which he is very good at.
Played By: Johnny Whitworth
A young, incompetent outlaw in Wade's gang.
- Shoot the Hostage: He's taken hostage by a surviving pinkerton, and Wade promptly kills them both.
"I've been standin' on one leg for three damn years waitin' for God to do me a favor...and he ain't listenin'."
A one-legged Civil War veteran barely managing to support his family on a ranch. Disrespected by his son and in dire financial trouble, he volunteers to help escort Ben Wade to Contention.
- The Atoner: For his cowardice during the Civil War.
- Dirty Coward: During the war, he was this and he still feels guilt over it.
- Rancher: His current occupation, although he's failing badly at it.
"I ain't ever walking in your shoes."
The eldest son of Dan Evans.
"The Southern Pacific will have Ben Wade convicted in a federal court. Hanged in public. An example made. And we will pay to make it happen."
An agent of the Southern Pacific Railroad, it's at his behest that Ben Wade is to be escorted to Contention.
- Screw This, I'm Outta Here!: When Wade's gang surround him, Butterfield decides to leave. However, it's easy to be sympathetic toward him; the U.S. Marshals even gave up and recommended the same to him. Butterfield just didn't want to die pointlessly for the sake of his bank.
Played By: Peter Fonda
A ruthless pinkerton agent frequently on the hunt for Wade. After his capture, McElroy joins the posse to escort Wade to Contention.
- Badass Grandpa: His hair might have 'gone all grey', but it's a bad idea to mess with him. He's tough, ruthless and has Nerves of Steel.
- Flat Character: Is accused of being one by Wade, who considers him boring.
Byron's like a song with only one note in it. You ever read a book in your life besides The Bible
Byron: No need.
- Nerves of Steel: Even with a gun trained on him, he doesn't lose his ability to snark at his would-be killer.
- Worthy Opponent: For Ben Wade, or so it appears at first. It's subverted later when the depth of their hatred for each other is revealed.
"It's nice to have a conversation with a patient for a change."
A veterinarian from the town of Bisbee, the nervous but good-hearted Potter is dragged along with Wade's escort to provide medical service to a wounded McElroy.
- Frontier Doctor: A veterinarian, but the closest the posse have to a medic.
- The Heart: Doc is the kindest member of the posse, and is only part of it because of his duty to his patient. Dan wants respect and money, Tucker is ordered to by Hollander, Butterfield wants to protect his bank's interests, McElroy wants to see Wade swing and William wants to prove himself a badass. The Doc has the most moral reason of all of them to help.
- The Medic: For the posse. He's brought along to tend to McElroy's wounds.
- Not That Kind of Doctor: It's a matter of some concern for McElroy when he sees that the Doc mostly tends to horses, not humans.
"You have a week, Evans. Then we burn the house."
- The Bully: Tucker is a sadistic jerk who enjoys taunting others and causing misery. Notably he only bullies Dan, who is under his boss's thumb, and Wade when he's tied up and supposedly helpless.
- Bullying a Dragon: He tries his bullying tactics with Wade. It doesn't end well for him at all.
- The Dragon: To Glen Hollander.
- Psycho for Hire: Even if he wasn't working for Hollander, he'd probably be off exercising his violent impulses elsewhere considering the sick pleasure he seems to take in hurting people.
"If it's alright by you Mr Wade, I'd rather we not talk."
The determined, steadfast wife of Dan Evans.
Played By: Benjamin Petry
The youngest son of Dan Evans.
"Railroad's coming, Dan. Your land's worth more with you off it."
- Greed: He's willing to toss a family off their land to swell his own pocket.
Played By: Vinessa Shaw
Played By: Forrest Frye
Played By: Luke Wilson