"Yuuki o Uketsugu Kodomotachi e" is another memorial theme, this time for the end of Frontier, and featuring darn near everyone who ever recorded a theme song or battle theme for Digimon up to that point.
"With the Will". Then there's "The Last Element", which played in Frontier as the Hyper / Unified Spirit Evolution theme (in other words, for Emperorgreymon and Magnagarurumon), and during the birth of Susanoomon. The track which replaced it in the dub is just as good.
On a more solemn note, Theme of Darkness ~Kouichi's Theme - while the other "Theme of ____" BGM tracks are instrumental arranges of their respective characters' image songs, Kouichi's is a slow arrange of Kouji's "Theme of Light".
The most hilarious song ever in Digimon, Get the Biggest Fire, where the two main characters of Digimon Frontier try to sing a new theme, starting with the earlier themes. They sing very badly.
Frontier's opening sequence "Fire" is so fun and uplifting as well as touching one's heart. The English opening is really catchy and powerful too, to say the least, ending on a surprisingly meaningful note: "If we're all for one world, there's a world for us all." The instrumental version is just as awesome.
"Lucemon's Theme has a mixture of elegance, suspense and power fit for the fallen angel digimon. It starts slow and somber before the crescendo comes in and the melody takes on a tone not unlike a parade, then shifts into calm again before the main notes return with a vengeance at the end. Truly a chilling reminder of Lucemon's Egotism and ruthlessness.