In one scene, Napoleon tries to convince a kid that Pedro will protect him as president after he was bullied at his locker. The next scene has the same bully trying to steal the same kid's bike, but is stopped by Pedro's cousins in their Cool Car with "Vote 4 Pedro" plastered on the side, and all they have to do is shake their heads. Doubles as a Crowning Moment of Awesome.
In the Spanish audio track, when one of the cousins shakes his head at the bully, there's an "uh-uh-unh", which is also golden.
The part where an entire school bus full of children pull up to Nepoleon's house right as a farmer shoots a cow in the head. Cue screaming from all the kids.