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Madame XanaduAn immortal sorceress and fortune teller who served as Merlin's apprentice thousands of years ago (see Demon Knights for more of that). She assembles the team to handle the threats that the regular Justice League can't.
- Junkie Prophet: An interesting subversion. She can indeed see the future, but it's what she sees that causes her to take drugs (whether they're of an illicit or medical nature is unsure).
- Nice Job Breaking It, Hero!: She's the one who drove Enchantress insane to begin with.
- The Leader: Arguable. She assembles the team, but seems to trade off the role with John and Zatanna.
- Prophecy Twist: In the Books of Magic Arc, she predicted that the group would leave Tim Hunter behind on a parallel world. They do, but only because Tim chooses to stay and learn how to use his magic in a place better equipped to handle his powers. His father also stays with him.
DeadmanIn life, Boston Brand was an acrobat, and a massive jerk... until he was shot during his act one night. As the ghost Deadman, he seeks to do good in the world as penance for his behavior in life.
- All Men Are Perverts: Tries to get Dove to engage in a lesbian kiss with June Moone while he's in control of the latter's body. It's implied that this wasn't Boston's fault, but a result of the Enchantress's madness affecting his personality. Although he did try to have sex with Dawn in the body of a random civilian, which was entirely his own idea.
- The Atoner: Why he is a Jerk with a Heart of Gold rather than just a jerk.
- Deadpan Snarker
- Jerk with a Heart of Gold: He is much more firmly entrenched in this trope than Constantine, mostly because he hates being dead and unable to touch the people he loves.
- Mundane Utility: He possesses a guy, both because he needed to talk to someone, and because he wanted to taste a cheeseburger again.
- The Nicknamer: Calls Zatanna 'darling', and John 'con job'.
- Powers via Possession: Inverted. He hijacks people's bodies in order to use their powers, as the only power he has is being a dead acrobat.
- We Want Our Jerk Back: When John is unable to lie in the Books of Magic arc, Boston complains about John's newfound sincerity.
- Yank the Dog's Chain: Boston is brought back to life when he travels to a parallel universe brimming with unpredictable magic, and promptly killed.
John ConstantineSee John Constantine.
Black OrchidA shapeshifting agent of A.R.G.U.S., the government's superhuman-response agency. She is the only non-magical member of the team. Supposedly.
ShadeShade the Changing Man possesses the magical M-Vest, which allows him to manipulate the world around him.
ZatannaThe daughter of Giovanni Zatara, one of the world's greatest magicians, and a proficient magician herself. Can make anything she wants happen by saying words backwards. Unless something is messing up her spells.
- Beware the Nice Ones: On Epoch, where everyone's natures are reversed, Zatanna appears to be unchanged... until she nearly kills someone, and the only remorse she shows is at Timothy's distress. She also mentions that she doesn't trust people claiming Timothy is their "Chosen One", because that would be the first thing she'd say to manipulate a lonely child. Basically, she and John switch personalities.
- Biker Babe: At least in the first few issues.
- The Heart: Being the most well-adjusted member of the group, Zatanna tends to act as a buffer between John and the rest, and the others trust her most. She trades off the Leader role with Constantine and Xanadu.
- Kill the Cutie: According to a prophecy from Xanadu, John will (might?) kill her.
- Last-Name Basis: She calls John by his last name until their relationship improves.
- Nice Girl: She gets along with everyone because of this. Except John, who has a history with her. Although she even starts to patch things up with him. Tied with:
- Plucky Girl: She's had a horrible life and tends to be the first one whose powers stop working, but remains the most compassionate member of the group.
- Power Nullifier: For one reason or another, Zatanna's spells almost never work when it's important during the first few arcs.
- Put on a Bus: When the House of Mystery is stolen in the Horror City arc, John does not call Zatanna in.
- Stepford Smiler: In the first issue, Batman tells Zatanna that she is not stable, and most later references imply that she still hasn't gotten over watching her father burn to death because of John's actions.
- Your Cheating Heart: Her relationship with Nick slowly withered as he obsessed over the Books of Magic, and she turned to John for comfort. Nick doesn't particularly care, which makes the situation uncomfortable but not outright bad. When he begs them for help, they go to save him out of guilt. However, it was a ploy for Nick to kill John and Zatanna, which makes them ultimately sympathetic.
Andrew BennettThe main hero of I, Vampire.
Dr. MistA powerful mystic working for A.R.G.U.S.