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* ''Manga/SangatsuNoLion'': Rei starts developing this toward Hina, especially as the latter becomes more prominent in the story. Despite his meek exterior, he consistently acts to protect and console Hina, including getting in the way of boys who try to flirt with her, and seeking her out on her on a school trip (going so far as to take a train to the city she is in after his own affairs are finished) to console her when she's having a hard time.
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** One of Ichigo's biggest irritations is an older brother harming his younger sister. He gave us the page quote. In the Hell verse movie, when Yuzu dies, Ichigo flips completely until Renji stops him. In the Hueco Mundo arc, Ichigo comes across [[PluckyGirl Nel]], and his constant protection of her eventually leads to her trying to protect him back. When an ArcVillain messes with his little sisters, Ichigo eventually contemplates murder to save them.

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** One of Ichigo's biggest irritations is an older brother harming his younger sister. He gave us the page quote. In the ''[[Anime/BleachHellVerse Hell verse Verse]]'' movie, when Yuzu dies, Ichigo flips completely until Renji stops him. In the Hueco Mundo arc, Ichigo comes across [[PluckyGirl Nel]], and his constant protection of her eventually leads to her trying to protect him back. When an ArcVillain messes with his little sisters, Ichigo eventually contemplates murder to save them.
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** Eren also seems to develop this for [[spoiler: Historia]] later on.
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* Natsuki from ''Anime/Tsuritama'' over his little sister Sakura, to the degree that she's one of the very few things that can crack through his grumpy demeanor and get him to smile. Haru saying to Sakura that Natsuki'll be teaching him and Yuki how to fish is the only reason Natsuki agrees to do it, just to keep her from feeling let down.
* ''Music/Vocaloid''-- although technically all the canon Vocaloids are supposed to be siblings -- has Len Kagamine, who in vids is protective or over-protective of his sister, Rin, although Rin is supposed to be the older one.

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* Natsuki from ''Anime/Tsuritama'' ''Anime/{{Tsuritama}}'' over his little sister Sakura, to the degree that she's one of the very few things that can crack through his grumpy demeanor and get him to smile. Haru saying to Sakura that Natsuki'll be teaching him and Yuki how to fish is the only reason Natsuki agrees to do it, just to keep her from feeling let down.
* ''Music/Vocaloid''-- ''Music/{{Vocaloid}}''-- although technically all the canon Vocaloids are supposed to be siblings -- has Len Kagamine, who in vids is protective or over-protective of his sister, Rin, although Rin is supposed to be the older one.
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** During the filming of their [[SoBadItsGood amateur, plotless movie]], Haruhi gets Mikuru to drink alcohol, trying to get a certain effect out of her. He almost punches Haruhi in the face.

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** During the filming of their [[SoBadItsGood amateur, plotless movie]], Haruhi gets and Tsuruya get Mikuru to drink alcohol, trying to get a certain effect out of her. He get so angry at Haruhi when she refuses to aknowledge her share of responsability that almost punches Haruhi her in the face.face, and is kinda [[MyGodWhatHaveIDone surprised at himself]] when Itsuki manages to calm him down.
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* ''Manga/FullmetalAlchemist'': The main plot revolves around Ed scouring the earth for a way to restore his younger brother Al's body to normal. On the other hand, considering Al is inhabiting an animated suit of armor much larger than Ed, there's a quite unusual dynamic going on there. Especially considering how Ed reacts to [[BerserkButton anyone calling him short]].
** Ed sacrificed his arm to keep his brother's soul in existence. [[spoiler:And later, his use of alchemy altogether.]] If that's not Big Brother Instinct, what is?

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* ''Manga/FullmetalAlchemist'': The main plot revolves of the manga and the two anime series revolve around Ed scouring the earth for a way to restore his younger brother Al's body to normal. On the other hand, considering Al is inhabiting an animated suit of armor much larger than Ed, there's a quite unusual dynamic going on there. Especially considering how Ed reacts to [[BerserkButton anyone calling him short]].
** In the manga and ''Brotherhood'', Ed sacrificed his arm to keep his brother's soul in existence. [[spoiler:And later, his use of alchemy altogether.]] If that's not Big Brother Instinct, what is?



** Scar's older brother. [[spoiler: When Kimblee attacked, he jumped in front of Scar even though the effort was... well, fruitless. Afterwards, as Scar lay dying with one arm gone, his brother sacrifices his own arm and bleeds to death in his place.]]

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** Scar's older brother. [[spoiler: When Kimblee attacked, he jumped in front of Scar even though the effort was... well, fruitless. fruitless [[CowardlyLion and he clearly knew it]]. Afterwards, as Scar lay dying with one arm gone, his brother sacrifices his own arm and bleeds to death in his place.place, [[SpannerInTheWorks ultimately giving Scar the chance to fight back against the Ancient Conspiracy]].]]
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** Similarly Pikachu often plays this to all of the team's newer Pokemon, especially the younger or un-evolved ones. Secondary mascots of the team such as Togepi, Piplup, Axew and Dedenne especially are the target of Pikachu's softer protective side.
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* In ''Anime/YuriOnIce'', Michele Crispino has this towards his younger twin sister Sara, stemming from when boys used to bully her when they were younger. However, it's deconstructed since over time, his protective instincts have become very dependent and possessive; the two of them go everywhere together, he's [[MySisterIsOffLimits hostile towards any man who tries to approach Sara]], and he always needs her to be near the rink when he performs. Sara, for her part, knows their relationship is very codependent and they need distance, which she tells him [[CruelToBeKind in no uncertain terms]] in Episode 9. [[spoiler:In the end, Michele realizes that if he truly loves Sara, he needs to let her live her own life. He uses these feelings to fuel his routine and is able to put on a fantastic performance without needing her near the rink.]]
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* ''Anime/DarkerThanBlack'': There is a ''reason'' Hei goes [[BerserkButton completely nuts]] when his [[strike:Dead]] missing sister is brought up. [[spoiler:Namely, the reason he came to be a BadAss martial artist in the first place was to protect his Contractor sister. That's right, the normal sibling wanted to protect the one with superpowers. [[BadassNormal And did a pretty good job]] up until [[RealityIsOutToLunch Heaven's Gate]] somehow fused them.]] In the second season, [[spoiler:he starts treating Suou as a substitute little sister.]]

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* ''Anime/DarkerThanBlack'': There is a ''reason'' Hei goes [[BerserkButton completely nuts]] when his [[strike:Dead]] missing sister is brought up. [[spoiler:Namely, the reason he came to be a BadAss badass martial artist in the first place was to protect his Contractor sister. That's right, the normal sibling wanted to protect the one with superpowers. [[BadassNormal And did a pretty good job]] up until [[RealityIsOutToLunch Heaven's Gate]] somehow fused them.]] In the second season, [[spoiler:he starts treating Suou as a substitute little sister.]]
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** Chrono is something of a retroactive example. He went out of his way to defend Fate after her arrest at the end of the first season (dialogue in later seasons suggests that people are normally expected to defend themselves) and she was adopted by his mother at the end of ''A's''.
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** [[{{Trickster}} Romania]] feels this way toward his younger brother [[AdorablyPrecociousChild Moldova]], to the point that he gets depressed and feels like a failure when it seems like Moldova is considering going to live with [[PsychopathicManchild Russia]].

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*** [[BoisterousBruiser Denmark]] acts this way as well, loudly referring to himself as the older brother of all the Nordics. His being especially attentive toward Iceland annoys Norway.

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*** All of the older Nordics act this way toward Iceland to some extent, though Norway is the most adamant about it. [[BoisterousBruiser Denmark]] acts this way as well, loudly referring refers to himself as the older brother of all ''all'' the Nordics. His being especially attentive toward Iceland annoys Norway.


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** [[ChivalrousPervert France]] thinks of himself as the older brother to the European nations[[note]]While acknowledging Spain as his elder brother in turn[[/note]], but it's subverted in that only [[TheDitz North Italy]] treats him as such.
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*** Denmark acts this way as well, loudly referring to himself as the older brother of all the Nordics. His being especially attentive toward Iceland annoys Norway.

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*** Denmark [[BoisterousBruiser Denmark]] acts this way as well, loudly referring to himself as the older brother of all the Nordics. His being especially attentive toward Iceland annoys Norway.



** England also acted as an older brother figure to America, in his own way. The Revolutionary War thus broke his heart, and he still seems to have a soft spot for him ([[{{Tsundere}} not that he'd ever show it]]).

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** England [[MeanBrit England]] also acted as an older brother figure to America, in his own way. The Revolutionary War thus broke his heart, and he still seems to have a soft spot for him ([[{{Tsundere}} not that he'd ever show it]]).
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*** Denmark acts this way as well, loudly referring to himself as the older brother of all the Nordics. His being especially attentive toward Iceland annoys Norway.
---->'''Norway's World☆Stars Character Profile:''' Because Denmark also acts like he's Iceland's older brother, Norway pokes him every time he does that!
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* In ''Franchise/MagicalGirlLyricalNanoha'':

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* In ''Franchise/MagicalGirlLyricalNanoha'':
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* Kenichi from the titular story ''Manga/KenichiTheMightiestDisciple'' has a younger sister named Honoka who is equal parts adorable and annoying. Thrust into the world of martial arts has led to his sister being in danger more than a few times. Endangering her is one of the quickest ways to earn his genuine ire.
** One of his rivals, Natsu, HAD a sister, who succumbed to her illness, leaving him a broken and bitter young man. He quit his gang after one of the high-ranking members kidnapped Kenichi's sister and then threatened the girl with a knife. She has since made him her 2nd Big Brother.
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** Ginga also demonstrated this in a flashback to airport fire. Rather than wait to be found, she went deeper into the burning building looking for Subaru (an act that would have gotten her killed if Fate hadn't rescued her).

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** Ginga also demonstrated this in a flashback to the airport fire. Rather than wait to be found, she went deeper into the burning building looking for Subaru (an act that would have gotten her killed if Fate hadn't rescued her).
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** Kinkaku seems to have this. He and his brother, Ginkaku, are infamous among Kumogakure. They fight as a team, and work well together. One another's name being their most used words. When Ginkaku is backed into a corner, he calls for his brother to help him. But he doesn't make it. In response to his brother's defeat, Kinkaku goes into rage [[spoiler: and enters six-tailed bijuu mode and rampages through the first division of the shinobi alliance.]] His first words [[spoiler: after transforming]] is "How dare you do that to Ginkaku." Darui apologizes to Kinkaku, but the latter just says it's too late, and attacks anyhow. The two brothers, if not half-siblings are fraternal twins. Their ages are the same, but birthdays are one month apart, with Kinkaku's being in March, and Ginkaku in April. it's accepted by fandom that Kinkaku is the older brother. He is bigger, ad also seems to be smarter. And Ginkaku, given his calling on Kinkaku for help, seems to show certain reliance on his brother. And Kinkaku, given his reaction looks out for his brother and can't stand for him to be harmed. Kakuzu even stating he hasn't seen Kinkaku that pissed in a while, and concludes it must mean Ginkaku has been defeated.

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** Kinkaku seems to have this. He and his brother, Ginkaku, are infamous among Kumogakure. They fight as a team, and work well together. One another's name being their most used words. When Ginkaku is backed into a corner, he calls for his brother to help him. But he doesn't make it. In response to his brother's defeat, Kinkaku goes into rage [[spoiler: and enters six-tailed bijuu mode and rampages through the first division of the shinobi alliance.]] His first words [[spoiler: after transforming]] is "How dare you do that to Ginkaku." Darui apologizes to Kinkaku, but the latter just says it's too late, and attacks anyhow. The two brothers, if not half-siblings are fraternal twins. Their ages are the same, but birthdays are one month apart, with Kinkaku's being in March, and Ginkaku in April. it's accepted by fandom that Kinkaku is the older brother. He is bigger, ad and also seems to be smarter. And Ginkaku, given his calling on Kinkaku for help, seems to show certain reliance on his brother. And Kinkaku, given his reaction looks out for his brother and can't stand for him to be harmed. Kakuzu even stating he hasn't seen Kinkaku that pissed in a while, and concludes it must mean Ginkaku has been defeated.
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* ''/Manga/PeacemakerKurogane'': Tatsunosuke is overly protective of his younger brother Tetsunosuke. The other characters tease them both about this.

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* ''/Manga/PeacemakerKurogane'': ''Manga/PeacemakerKurogane'': Tatsunosuke is overly protective of his younger brother Tetsunosuke. The other characters tease them both about this.
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** In ''Anime/TheLastNarutoTheMovie'', a part of Hinata's CharacterDevelopment shows in her developing this towards her younger sister Hanabi. She [[spoiler: offers herself to the BigBad in an attempt to regain [[EyeScream the eyes that he literally ripped out of poor Hanabi's eyesockets]] ]], and towards the end [[spoiler: she personally retrieves them and rips them off said BigBad's reach.]]
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* In ''Dorohedoro'', Asu sacrifices his devilhood in order to save Nidaido, whom he consider a sibling, even though they're not related by blood.
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** A much straighter example would be Tsubasa and Souma in ''KannazukiNoMiko'': the entire conflict between them stems from Tsubasa's desire to protect Souma as effectively as possible, which unfortunately involves pulling him to TheDarkSide and killing his love interest. [[spoiler:Towards the end, however, Tsubasa recognizes that Souma has wishes, too, and helps him to reach ''his'' goals.]] Also, Tsubasa killed their father who beaten up Souma when were very young, which is why they were separated.

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** A much straighter example would be Tsubasa and Souma in ''KannazukiNoMiko'': ''Manga/KannazukiNoMiko'': the entire conflict between them stems from Tsubasa's desire to protect Souma as effectively as possible, which unfortunately involves pulling him to TheDarkSide and killing his love interest. [[spoiler:Towards the end, however, Tsubasa recognizes that Souma has wishes, too, and helps him to reach ''his'' goals.]] Also, Tsubasa killed their father who beaten up Souma when were very young, which is why they were separated.
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** During the filming of their [[SoBadItsGood amateur, plotless movie]], Haruhi gets Mikuru to drink alcohol, trying to get a certain effect out of her. He almost attacks Haruhi. Let us repeat. He almost attacks a reality-warping goddess.

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** During the filming of their [[SoBadItsGood amateur, plotless movie]], Haruhi gets Mikuru to drink alcohol, trying to get a certain effect out of her. He almost attacks Haruhi. Let us repeat. He almost attacks a reality-warping goddess.punches Haruhi in the face.
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** There's also a slight dynamic between Touma and Index.
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* ''Manga/FateKaleidLinerPrismaIllya'': Miyu's brother, [[spoiler:Shirou Emiya]], who kicks off the plot by [[spoiler:winning the Holy Grail War]] to give her a normal life.
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** Ginga also demonstrated this in a flashback to airport fire. Rather than wait to be found, she went deeper into the burning building looking for Subaru (an act would have gotten her killed if Fate hadn't rescued her).

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** Ginga also demonstrated this in a flashback to airport fire. Rather than wait to be found, she went deeper into the burning building looking for Subaru (an act that would have gotten her killed if Fate hadn't rescued her).
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* In ''Anime/PersonaTrinitySoul'', Ryou used to be like this 10 years ago. After their family reunited he turned out to be [[spoiler:AloofBigBrother]]. His younger brother Shin also have this toward their youngest brother Jun. Shin is really worried about Jun, he really worried when Jun came back home 30 minutes late than usual, including [[spoiler:[[DatePeepers peeking]] him on his date]]. But it turns out [[spoiler:that it was not really a date]].

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* In ''Anime/PersonaTrinitySoul'', Ryou used to be like this 10 years ago. After their family reunited he turned out to be [[spoiler:AloofBigBrother]].[[spoiler: AloofBigBrother]]. His younger brother Shin also have this toward their youngest brother Jun. Shin is really worried about Jun, he really worried when Jun came back home 30 minutes late than usual, including [[spoiler:[[DatePeepers peeking]] him on his date]]. But it turns out [[spoiler:that it was not really a date]].


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*** She once teamed up with Gym Leader Liza when Max and Tate (their respective little brothers) got captured on a rocket by Team Rocket. They utterly destroyed them.


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** Hawlucha is fiercely protective of Noibat, who [[HeroWorship utterly adores the older Pokemon]].
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** Since May's introduction, Ash tends to have this with most of his female companions due to taking his place as the novice trainer. Possibly inverted since Ash will never be more than a slightly older ten at best.

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* In ''Franchise/MagicalGirlLyricalNanoha'', Cinque of the Numbers is quite protective of her younger sisters, staying behind to fight Subaru (who is in the middle of a terrifying berserker rage brought on by the Numbers hurting her own sister Ginga) and getting badly injured in the process to allow Nove and Wendi to escape. Even though her crimes are more severe than the other Numbers and she does not expect to ever be completely free, she decides to atone for them and cooperate with the investigation so she can help her younger sisters.

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* In ''Franchise/MagicalGirlLyricalNanoha'', ''Franchise/MagicalGirlLyricalNanoha'':
**
Cinque of the Numbers is quite protective of her younger sisters, staying behind to fight Subaru (who is in the middle of a terrifying berserker rage brought on by the Numbers hurting her own sister Ginga) and getting badly injured in the process to allow Nove and Wendi to escape. Even though her crimes are more severe than the other Numbers and she does not expect to ever be completely free, she decides to atone for them and cooperate with the investigation so she can help her younger sisters.sisters.
** Ginga also demonstrated this in a flashback to airport fire. Rather than wait to be found, she went deeper into the burning building looking for Subaru (an act would have gotten her killed if Fate hadn't rescued her).

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