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WARNING: Major spoilers ahead for anyone who hasn't yet finished the mod itself. You Have Been Warned!

Introduced in DDTO

  • Girlfriend Countdown: Complete Sayori's week.
  • Poems n' Thorns: Complete Natsuki's week.
  • Dual Demise: Complete Yuri's week and return to the Story Mode menu.
  • Epiphany: Complete all the other available songs. / Complete the original weeks in Plus.

Introduced in the Plus update

Songs

  • Side Stories: Beat the entire Story Mode.
  • Titular (MC Mix): Complete the entire Story Mode.
  • Drinks On Me: Complete all four Side Stories, then click on a peculiar object in the Main Menu.
  • Epiphany WITH LYRICS: Beat Epiphany.
  • Libitina: Beat every song in the mod save for "Epiphany" and "Epiphany WITH LYRICS".

Costumes

Boyfriendnote 

  • Uniform: Available by default.
    • Sutazu: While selecting this outfit, hold B and press Enter to switch to this character.
  • Regular: Beat the entire Story Mode.
    • Christmas: While selecting this outfit, press the left/right arrow key and Enter to switch to this outfit.
  • Minus Boyfriend: Beat the entire story mode.note 
  • Benjamin: Have save data for Friday Night Funkin' Soft on your PC or beat "It's Complicated (Sayori Mix)" with the Festival costume in Mirror Mode.note 
  • Mr. Cow: Have a save file for Doki Doki Literature Club! or Doki Doki Literature Club Plus!, or complete "Our Harmony" with all casual costumes enabled.
  • Blue Skies Boyfriend: Get an accuracy of 90% or higher on "Your Demise".
  • Aloe: Find and click on a certain succubi in the Sticker Gallery.note 

Girlfriendnote 

  • Uniform: Available by default.
    • Sayori behind the speakers: While selecting this outfit, press B and Enter to switch to this "outfit".note 
  • Regular: Beat the entire Story Mode.
    • Christmas: While selecting this outfit, press the left/right arrow key and Enter to switch to this outfit.
  • Minus Girlfriend: Beat the entire Story Mode.
  • Soft Pico: Have save data for Friday Night Funkin' Soft on your PC or beat "It's Complicated (Sayori Mix)" with the Festival costume in Mirror Mode.
  • Blue Skies Girlfriend: Play "Love n' Funkin'" on Mirror Mode.
  • Nene: Find and click on a certain succubi in the Sticker Gallery.
  • TBD-Tan: Beat every song in Doki Doki Takeover! at least once.

Monikanote 

  • Uniform: Available by default.
  • Casual: Beat the entire Story Mode.
  • Valentine's Monika: Play an alternate version of Epiphany.
  • Hex Outfit: Get an accuracy of 90% or higher on "Glitcher (Monika Mix)".
  • Senpai Outfit: Beat "Wilted" on Mirror Mode.
  • Blue Skies Monika: Play "Reconciliation" on Mirror Mode.
  • Vigilante Outfit: Pick Monika at the midway point of "You and Me".

Sayorinote 

  • Uniform: Available by default.
  • Casual: Beat the entire Story Mode.
  • Sleep Wear Outfit: Experience a Bad Ending or beat "Joyride" on Mirror Mode.
  • Picnic Outfit: Pick Sayori at the midway point of "You and Me".
  • Grace's Outfit: Get an accuracy of 90% or higher on "It's Complicated (Sayori Mix)".
  • Zipper Hoodie: Get an accuracy of 90% or higher in "Constricted".
  • Blue Skies Sayori: Play "My Confession" on Mirror Mode.

Natsukinote 

  • Uniform: Available by default.
  • Casual: Beat the entire Story Mode.
  • Skater Outfit: Pick Natsuki at the midway point of "You and Me".
  • Kapi's Outfit: Get an accuracy of 90% or higher on "Beathoven (Natsuki Mix)".
  • Sunday's Outfit: Have a save file for Vs. Sunday or play "Baka" on Mirror Mode.
  • Hank's Antipathy Gear: Find and click on a certain vulgar assassin in the Art Gallery.
  • Blue Skies Natsuki: Pick Natsuki as your playable character for "Catfight".
  • Buffsuki: Press B and Enter while highlighting Natsuki's normal outfit to use this costume.

Yurinote 

  • Uniform: Available by default.
  • Casual: Beat the entire Story Mode.
  • Derby: Pick Yuri as your playable character for "Catfight".
  • Picnic Dress: Pick Yuri at the midway point of "You and Me".
  • Taki's Outfit: Get an accuracy of 90% or higher on "Crucify (Yuri Mix)".
  • Tabi's Outfit: Have a save file for Vs. TABI Ex Boyfriend or play "Obsession" on Mirror Mode.
  • Blue Skies Yuri: Play "Shrinking Violet" on Mirror Mode.

MCnote 

  • Uniform: Available by default.
  • Casual: Beat the entire Story Mode.
  • Rude#1's Outfit: Have a save file for Hotline 024 or beat BOTH "Deep Breaths" and "Poems n' Thorns" on Mirror Mode.
  • Blue Skies MC: Fail "You and Me" by picking no Doki.
  • Henry Outfit: Get an accuracy of 90% or higher on "Titular (MC Mix)".

Miscellaneous

  • Free Play: Complete the Prologue week.
  • Mirror Mode and Randomised Notes: Complete the Festival Week.
  • Art and Sticker Galleries: Complete the Side-Stories.

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