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Launcher Of A Thousand Ships:
has 9 5, because he's VERY touchy-feely with the other characters, and 7, because she's the only girl.
Maleficent seems to be this for the Disney Villains, having been paired with Chernabog, Hades, Jafar, and Captain Hook in works such as House of Mouse or Disney Theme Parks shows or related media. There's even a ship between her and the Horned King
Just take a look around YouTube or Deviant ART for Jim Hawkins; the poor kid's been paired with nearly every heroine in theatrical animation (and some of the guys); among them, Ariel, Audrey and Kayley, the three most popular crossover girlfriends for him and Dimitri seeming to be the most popular boyfriend. Which is not even getting into the OCs.
Poor Alice is the Fan Vid community's Lolita.
Merida from launches a Brave Crossover Ship practically every minute. She's got her own Portmanteau Couple Name with Hiccup (Mericcup), and has been paired with Hawkeye, Flynn Rider and Rapunzel, Katniss, the aforementioned Jim Hawkins, and all three of the suitors from her own film.
Jack Frost seems all but ready to usurp Katara for the Launcher of a Thousand Ships title. He's been shipped with his Guardian teammates, their sidekicks (especially Babytooth), the villain, the children who believe in him, characters who only appeared in the books, the aforementioned Merida along with the rest of their Rise of the Brave Tangled Dragons cohorts, the supporting characters from those movies, several Crossover Ships besides including characters from a certain movie starring another cryokinetic, and many many many Mary Sue OCs.
Fix It Felix Jr from has launched a whole ton of ships in the fandom.
Wreck-It Ralph What is it with ice-themed characters? Elsa of has been shipped with all the main characters of her own movie, most prominently Frozen Anna, Kristoff and Hans, as well as an uncountable number of crossover ships, including the aforementioned Jack Frost and Pitch Black, the Ice King, Frozone, practically any other ice-themed character the fans could think of, Rapunzel and Flynn, Merida, Wreck-It Ralph, Loki, Hiccup, Belle and Smaug. That's not even mentioning all the OCs. Elsa now seems to be vying to top Jack for most ships created in a two-month period.
The aforementioned Hiccup from has had a resurgence in How to Train Your Dragon Crossover Shipping with the sequel coming out soon. The fact that his older appearance in the film has been considered by many to be quite attractive has only served to help him in this case.
The Once-ler from the 2012 adaptation, partly because he's attractive and partially because there's practically no one in his canon story for him to be shipped with. Because he undergoes a The Lorax Face-Heel Turn and Evil Costume Switch, the two sides of him are often treated as two entirely separate characters, thus shipping Once-ler and Greed-ler.
Scar from has been paired with The Lion King Zira, Sarafina (Nala's mom), Sarabi, Nala, random background lionesses, tons of OCs, even Simba. However; many of these pairings exist not because fans find them romantic, but to explain the parentage of other characters.