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Heel Face Turn:
Sonia and Dr. Hart in .
lonelygirl15 Fair numbers of this happen in . Mostly, it is the result of a 'player' stopping killing their fellows, usually due to a guilty conscience.
Survival of the Fittest Hawley Faust of the first game, although he was semi-convinced instead of spontaneously deciding to quit.
Julie Mikan in V3. She set out to actively play, but after killing Owen Fontaine realised she didn't have what it takes and became a heroic character instead.
Dominica Sharpiro, also of V3. A less conventional example in that she made the switch purely on the chance the escape plan of the group she joined would succeed.
Sharon Kulikov, similarly to Julie, originally decides to play indiscriminately, but upon realizing that she can't bring herself to do that she resolves to only target other players.
The most recent example is probably Bobby Jacks, although he was pretty shaken up about killing other people.
Laeil Burbank, who started off as a vengeful Psycho Lesbian, until she pissed off an even bigger player who... decided to have some fun with her. After she's rescued, by someone who's best friend she'd killed (though it was a Mercy Kill), punched in the face, and told that if she ever saw him again, she'd kill him no less, she decides that she's through with being an indiscriminate killer (unfortunately, she doesn't survive for very long after that).
Sarah Atwell, who took part in one of the most horrific murders of V4, is now making a bid for redemption through killing other players after a shocking realization.
Of course, she ends up dying crying and begging on the floor to not die.
Happens with several characters from the RPs, most notably with Hans.
Darwin's Soldiers Possibly : in the last episode of the first season, NES digs up a Sega Menacer for Captain S to use against Game Genie (NES's former master). Although, the series ended with NES's fate unknown, so his motivation for doing this is just as unclear.
The New Adventures of Captain S In most of the shorts, Jeebus is the enemy of the protagonist, Hank. However, in Part 8, he is featured as trying to stop the Mooks and new Madness Combat Big Bad.
Ralph from pulls one of these when he realizes that Dead Ends he is hunting down an unarmed teenager and her friend during a
Zombie Apocalypse because his best friend, Ephram, has gone batshit crazy. Surprisingly rare in the .
Global Guardians PBEM Universe Battle betrayed Tarot to save the life of her son, Stone.
Gadgeteer villain Knick-Knack retired from his life of crime and became the custodian of the Hyperion Academy.
The Redeemers are a team made up of former super-villains.
Gross Sword does this at the end of The Sick Kids, but only because his lawful-good siblings nearly kill him.
Bogdan from does that after he develops a liking for a prisoner that his partner tells him to kill. He proceeds to attack his own partner.
Water Human Kelly from is easily We're Alive the most hated character among both the cast and audience during Season 1, but eventually pulls one of these after her attitude indirectly kills Tommy.
Demonking does this in . TOME Then he becomes bad again, but then ascends again and is currently more of a rival to Nylocke than a bad or good guy. This entire process is subverted when it's revealed the hackers aren't really bad guys anyway.
Spiro of pulls one after refusing to kill a Demon Bunny for his master's dinner. He's banished from his homeland for showing mercy, and ends up as the The Questport Chronicles Token Evil Teammate in the Fellowship.
The King of Thieves and Assassins reforms after hearing the Harp of Remorse.
In , a bunch of antagonists eventually switch sides and become more heroic. Some examples include The Gamers Alliance Dalthas, Jemuel, Kagetsu I (he joins the Alliance because they saved his wife, but he still more or less pursues his agenda albeit with different means while being bound by his oath to the Alliance), Omaroch, Titaniel and Viirsa.