In Manchester Lost, this ends up having an interesting twist. Crowley has a shoulder angel and demon represented as Inner Aziraphale and Inner Hastur. Aziraphale has an Inner Crowley and Inner Raphael. Both sets are hilarious.
Played with in a Misfitverse (longrunning X-Men: Evolution / G.I. Joe crossover) story. Forge's experimental Shrink Ray accidentally de-bigulates several of the adults - including Beast and Angel, who end up climbing onto Kitty's shoulders and arguing about what to watch on TV.
Here we see K-On's Tsumugi get advice from her angel (Yui) and devil (Ritsu) in an awkward situation.
In Kyon: Big Damn Hero, Achakura and Kuyou transform into these tempoarily, but neither of them quite get Black and White Morality.
Calvin and Susie have an argument in In Love and War. In responce, Spacemann Spiff and the Dictator-for-Life appear. Shortly afterwords, a Hobbes and pirate Hobbes appear as well. As it turns out, the entire shoulder angel secquence was All Just a Dream.
During the Hot Springs Episode of Tengen Toppa Gurren Solvernia, they try to talk to Kamina. The Bad Angel argues that Kamina should see the girls' side, but the Good Angel tells him to not do it, because Nia is among. Then the Bad Angel reminds that Nia shouldn't be there anymore, and thus the Good Angel tells Kamina to continue with his plan.
Played in a literal sense in Ah Archfall, in that Jago actually has an angel AND a devil.
In a Ranma 1/2 doujinshi (Mantou 12) Ranma's good rightious side is represented by Amelia Wil Tesla Seyruun, while his bad lustful side is represented by Lina Inverse
On chapter 3 of "Days of Futures Past What Does That Mean It Kinda Sounds Sexy" a Naruto Young Justice crossover Naruto gets excited that two of his shadow clones argue on ether doing the right thing or turning his back on the young heroes. He demands that both shadow clones transform in order to make their points first transforming into Naruko in a sexy devil costume and a white robe wearing harp player but choices to flow the good clone due to the fact the bad one snapped at him for being indecisive.