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Captain Caveman
Voiced by: Mel Blanc
- Bamboo Technology: Well... he did live in The Flintstones world of Bedrock.
- Catchphrase: His two most memorable ones are "CAPTAIN CA-AVE-MA-AN!" and "Unga Bunga!"
- Extreme Omnivore: He'll eat anything that isn't edible.
- Flight: He can use his magical club to fly by saying a chant.
- Hammerspace: His hollowed-out club will carry a wide variety of gadgets for fighting crime.
- Papa Wolf: Never, ever mess with his son, Cavey Junior.
- Reused Character Design: He greatly resembles Rock and Gravel, the Slag brothers from Wacky Races.
Brenda Chance
Voiced by: Marilyn Schreffer
- Butt-Monkey: Brenda is always getting the short end of the stick and captured by the villains. Plus, she's picked on by her friends because of it.
- Cute Clumsy Girl: She's easily caught by villains because of her clumsiness.
- Damsel in Distress: She's a perfect target for villains.
- Dub Name Change: In the Brazilian Portuguese dub, she was renamed as Nelly, to sound closer to Kelly, the member of the Charlie's Angels she was modeled after.
- Hartman Hips: One of the most common Teen Angel features.
- Nervous Wreck: Brenda is timid and nervous, but also very sweet.
Dee Dee Skyes
Voiced by: Vernee Watson
- Black and Nerdy: She is black and the smartest of her group.
- Dub Name Change: In the Brazilian Portuguese dub, she was renamed as Sabina, to sound closer to Sabrina, a member of the Charlie's Angels. Although she's physically different from Sabrina, she fits the same role, being the leader and the brains of the trio. She was even voiced by Sabrina's voice actress, Sumara Louise.
- The Leader: She's the one in charge.
- Token Minority: The only minority on her team.
Taffy Dare
Voiced by: Laurel Page
- Compressed Hair: For disguises, she has managed to fit the pictured hair under smaller wigs and caps with no trouble.
- Dub Name Change: In the Brazilian Portuguese dub, she was renamed as Gilda, to sound closer to Jill, the member of the Charlie's Angels she was modeled after.
- Genius Ditz: For all of her ditzy moments, she's usually the one to come up with clever plans to capture the Villain of the Week.
- Genki Girl: She’s very energetic.
- Femme Fatale: Taffy is always flirting with Cavey to get him into going along with her plans.
- Hartman Hips: She shows it off even by the way she usually stands.
- Master of Disguise: She often dons a disguise of some sort as part of her plans. Can be a a Paper-Thin Disguise, depending on Rule of Funny.