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Season 1
- First Day of School: Arnold Armstrong, formerly the superhero Captain Fantastic, faces an unexpected career change after losing his superpowers in a final epic showdown with Dr. Superior; he’s now tasked with guiding a special group of six kids through superhero training and the challenges of kindergarten.
- Art of the Steal: A field trip to the Greenville Museum of Art is interrupted by a critical mission, and the Super K's must work as a team to save the museum's most precious painting from two clever art thieves.
- Hammy: Hammy, the new class pet and mascot, teaches the kids about taking care of a pet — and the kind of trouble a hungry super-powered hamster can cause!
- Super K's VS The Fearsome Foursome: The Super K's meet their arch-nemeses, the Fearsome Foursome, and learn about the importance of perseverance.
- Call Me Hugzilla: A superhero lesson on creative thinking leads Billy to question what it means to be a monster.
- One Dark Night: Dueling sleepovers and pranks lead to a lesson on overcoming your fears — real or imagined.
- The Experiment: Billy and Jackson get into a tricky situation when Nigel Danforth hatches a plan to get his evil superpowers back.
- Sleeping Duty: When Mr. Arnold falls asleep in class, the kids take on an important mission without him that they're not quite ready for.
- Castaways: The Super K’s accidentally take off in a hot air balloon without Mr. Arnold and crash onto a deserted island.
- How the Super K's Save Christmas, Part 1: The Super K's must stop Nigel Danforth and his Fearsome Foursome from canceling Christmas forever.
- How the Super K's Save Christmas, Part 2: Countinuation of Part One.
- Lost In A Space Odyssey Trek: A trip to the Greenville Science Museum leads to an out of this world adventure.
- Super K's Gone Bad: The Super K's are doing horrible, no good, super bad things all over Greenville, but… is it really them?
- The Substitute: When Mr. Arnold misses class to attend a Retired Superhero meeting, the new substitute teaches the Super K's a lesson on trusting their instincts.
- Hall of Fame: When Captain Fantastic is inducted into the Super Hero Hall of Fame, Nigel Danforth decides to do everything he can to disrupt the main event.
- Bessie, We Hardly Knew Ye: Vik's quest to find Bessie the lake monster teaches everyone that just because you can't see something doesn't mean it isn't real.
- The Magic Ring: A trip to meet Mr. Arnold's friends Penn and Teller leads to a magical mystery that only the Super K's can solve: what happened to Houdini's Ring?
- Time Trippers: The Super K's accidental trip through time teaches everyone that history is best left in the past.
- Checkmate: Mr. Arnold's special guest, Arnold Schwarzenegger, has an epic chess match against Natasha Badinski.
- Weirdo World: Mr. Arnold and the Super K's are teleported to an alternate world where everything is opposite!
- A Royal Visit: A Super K royal visit with Princess Zamunda turns chaotic when her priceless tiara goes missing.
- The Paris Affair: A geography lesson and a story about Mr. Arnold's long lost love leads to an adventure in Paris to save the city from the dastardly Joan of Dark.
- Earthlings Got Talent: When Patty, Billy, and Vik are abducted by aliens, Mr. Arnold and the rest of the Super K's must race to save them from the most dangerous talent show in the universe.
- Captain Fantastic Begins: The mysterious origin of Captain Fantastic and his rivalry with Dr. Superior is finally revealed.
- Austrian Adventure: The Super K's take a trip to Austria with Mr. Arnold to solve the mystery of a missing mini horse.
- Emerson: A new exchange student from England teaches the Super K's that appreciating each other's differences can save the day.
