Patrick Jane gets this in the first few minutes. In a scene the creators made to clearly show off how badass he is, (and it worked) he goes into the house of a family discussing the arrest of the (alleged) killer of their daughter, he makes a sandwich and a pot of tea, offers the wife a cup when she walks in, talks with her, tells her all he's picked up about her, tells her he thinks that her husband killed her daughter, explains how a wife knows when her husband is lying to them, and then the husband comes in. He has a bit of small talk and blatantly asks the man if he did it. The man has an outrage, which causes the wife to leave, a minute or so later, the wife comes back and shoots him, knowing that he was lying and had actually killed their daughter. Yes...
He does it again in the beginning of the 3rd episode where he was able to get the location of the keys to the van from one of the other investigators "mentally", without hints. When asked how he pulled it off, he responded...
Patrick: If I tell you, the Magic Circle will send assassins to kill us all, it's the law.
Everything he does in "Black Gold and Red Blood"... most of it from prison. He provokes a suspect, over the phone, into getting himself arrested so Jane can talk to him in person. He escapes from jail using a mouse he caught with nothing but a Bible and a cranberry muffin. He pushes the killer into confessing when she hears the police arriving... only to calmly admit that the police are actually there to arrest him for the aforementioned jailbreak.
Lisbon: You Terrence Andrews? Andrews: Who's askin'? Lisbon: People call you Terry or Terrence? Andrews: They call me Mr Andrews. Lisbon: Why don't you come downtown with us, answer a few questions. Andrews: No, I don't think so. Rigsby: (pulls him away) Come on. Andrews: (aggressive) You wanna make something here? Lisbon: (disinterested) No, thank you. (Tazers him.) You OK? Mr Andrews.
Way more awesome than it sounds.
This little gem from the third season's first episode:
Lisbon gets a truly incredible moment in the episode Redacted 3x20. For background: Jane has spent the entire case trying to get a robber out of prison so that he can't tell the police that Jane hired him (don't ask), and failing repeatedly, even at hypnotising the guard. He tells Lisbon about the problem roughly two minutes before the end of the episode: she nods coolly, goes to the prison, and punches the guy hard in the face. The case is thrown out of court and the guy is immediately released.
But the end of the first episode in Season Four reveals it wasn't really Red John. He was a horrible person, though.
How Jane prevails over the serial killer in "Blinking Red Light". He basically tricks the killer into badmouthing Red John on TV, causing the offended Red John to kill that killer. It's the darkest, coldest, and most brilliant Batman Gambit by Jane so far. And as if it's not enough, it also pays tribute on the past sin of Jane and reopens the Myth Arc.
Wainwright stands up to Jane's shit in "Red Rover, Red Rover." For the first time, we see a boss that has some spine.
In the eighth episode of the sixth season, Patrick Jane, after years and years of pursuing him, finally gets his vengeance on Red John, aka Sheriff Thomas McAllister. Trapped in a chapel by Red John with a gun trained on him and his own gun taken away, Jane says he has a trick to show Red John. He reaches into his pocket and pulls out some bread crumbs. Then reveals he snuck a pigeon into his coat and throws it at Red John, momentarily surprising the killer as he has a fear of birds. This gives Jane the opportunity to drop to the floor, pull out a gun he previously taped to the underside of a pew, and shoots McAllister in the stomach. Then Jane kills Red Johnís Corrupt Cop accomplice, knocks out another of Red Johnís followers who tried to kill him with a knife, chases after Red John and corners him. Wrapping his hand around his throat, Jane asks if Red John is sorry for killing Janeís wife and child, and tells him to blink once for no and twice for yes. Red John blinks yes. Jane then asks if heís afraid to die. He blinks yes again. Jane says, "Good," and finally strangles him to death.