Here's the list of Chapters' names with a short summary:
Volumes
1. Origin Story: Sam Shepherd gets caught up in a battle between the heroes and an Alpha Terror.
2. Save the Girl, Save the World: Sam gets a mysterious system that gave him his first quest.
3. Gods and Monsters and Those Who Train Them:
4. The Will of Self Sacrifice
5. Starting Line
6. Powers And Bonds
7. Solo Mission
8. Goodwill Hunting
9. Facing Despair
10. Lesson Number Eleven
11. Into the Fire
12. The First Meeting of the Brave and the Bold
13. Mr. Moonday
14. Suiting Up
15. A Starry Night Infiltration
16. Midnight Madness
17. Going Delta
18. The Bow of Heracles
19. A Visit to the Healing Gardens
20. Broken Prophesies
21. Boars and Walls
22. Blunt Force Trauma
23. Lesson Number Ten
24. Liar, Liar, Pants on Fire
25. Lost Girls and Bad Dreams
26. The Rooftop Running Man
27. No Rest for the Wicked or the Heroic
28. The First Labor
29. Love and Thunder
30. Hero
31. Rebirth
1. Brave New World
2. A Meeting of the World's Finest
3. Meet the Crew
4. The Chime of Liberty
5. Predator
