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troperville

Most of the the music here comes from the mecha genre Muv-Luv Alternative, widely regarded as one of the best visual novels, and as such contains some truly awesome music designed to get your blood pumping or make you cry.

Muv Luv is a good opening theme for the first game and a fitting way to end Alternative.
Asu e no Houkou from Alternative is one of the most hot blooded openings to a visual novel ever fitting perfectly with the humungous mecha and is made by Jam Project.
Theory for a Speedy Welcome and Farewell.
Rain Cloud (a carryover from Kimi Ga Nozomu Eien).
Confession.
Creeping Anxiety is used for some of the more shocking moments in both Extra and Alternative.
Gravestone.
Bonds, a reprise of "Wings".
An Eishi's Style, a reprise of "Carry On".
War Preparation.
Footsteps of Military Shoes.
A Battlefield's Desire for Blood.
Clash.
Assault Landing (also a fantastic Suspiciously Similar Song and homage to Starship Troopers' "Klendathu Drop").
Howling Spirit (another homage, this time to the famous Gunbuster March).
Decision.
Resistance to the Bitter End.
Over my Dead Body.
Original Hive perfectly captures that alien feeling.
Valkyries.
Storm Vanguard for whenever Takeru does something Badass.
Flame of Life, which plays as Michiru dies.
Farewell, which plays as Mitsuki dies.
Meiya, which becomes an absolute tearjerker when playing during her death scene. The Standard Edition uses an extended version.
Reminiscence: You'll be remembering this song seeing as how it plays during the most shocking scene aka the HEADCHOMP scene.
Something Stolen: The official theme music of the PTSD Arc.
The End of Regret (still another homage, to Is Paris Burning?)
Destiny and its rearrangement For You Who Departs.
Sunshine as far as peaceful/calming songs go, and takes some cues from Giant Robo's Main Title.
From The Day After: Roar of Counterattack, the Theme Music Power-Up of Hibiki and the Wardog Squadron.
Total Eclipse is not to be outdone:
- "No Place Like A Stage", which plays whenever Yuuya is being badass.
- "Apocalypse of Destiny", the insert song for Episode 5. Yui versus Argos Flight.
- "Doubt The World", the 2nd OP, which sets the stage for the final arc of the anime.