Desann: I was wrong about you, Katarn. Your failure as a Jedi hasn't weakened you; it's made you stronger. Come, join me. You know in your heart that you'll never truly be one of them. Kyle Katarn: Maybe, maybe not, but I know I won't bealone. How 'bout you, Desann? Even now, after all this pain, there's still hope. Come, join us.
Lyle Dylandy offers this to Ali al-Saachez in episode 24 of Season 2 of Gundam 00. It doesn't work... however he's Genre Savvy enough not to lower his gun, allowing him to immediately shoot Ali when the latter attempts to turn around and fire at him.
Used at the end of season one of Magical Girl Lyrical Nanoha. Precia refuses Fate's invokement of the trope, however, and goes down with the tank containing Alicia's lifeless body.
Nina tries to pull this on Johan in Monster by forgiving him for his actions (towards her, at least) in the climax, to stop his plan to make Tenma shoot him. Johan replies, apparently somewhat saddened, that some things cannot be taken back or forgiven. He had already pulled the same plan on her ten years ago, and she shot him.
Also occurs in Sonic X when Yellow Zelkova basically commits suicide rather than choosing to let Knuckles save him.
One of Yu-Gi-Oh!'s most prominent examples is Jounouchi's/Joey's second duel with Mai during the Doma arc. Unfortunately, by the time she decides she doesn't want to kill him, he's already in the throes of a Heroic Sacrifice.
Not really. Mai was still under Mind Rape/brainwashing when she was about to finish him off, but suddenly snapped out of it at that very moment.
In Toriko, IGO President Ichiryuu visits the Gourmet Corp headquarters to confront Midora. He invites Midora to share a meal with him at one of their old hangouts, reminding Midora of the good old days when they considered each other family. He then asks if Midora would be willing to share GOD. Midora smirks and declares that he'll be taking GOD all for himself. Ichiryuu resigns himself to war with his former brother, realizing they can no longer sit at the same dining table.
At the end of Batman: The Killing Joke, Batman confronts The Joker and asks him to let Batman help him back towards sanity. The Joker refuses. Actually, many Batman stories have him asking his more deranged enemies to go peacefully back to Arkham Asylum for treatment... usually followed by a big fight. The Joker, for probably the only time in his villainous career, actually considers Batman's plea to try to get rehabilitated, which he dismisses with surprisingly humane sadness (it's "far too late for me", he says) rather than rejecting it instantly.
Batman never stops trying to rehabilitate his former friend Harvey Dent aka Two-Face. Sadly, Harvey's inner demons are too strong and his Heel Face Turns never last.
In the latest Wavedancers graphic collection, Surge (former chief) is so paranoid about "landers" (humans, but by extension, anyone who doesn't live underwater) that he takes drastic measures to prevent his tribe from becoming friends with the "lander" elves. This includes kidnapping Cutter (chief of the non-Wavedancer elves) and swearing to kill him if he doesn't get his way. During the hostage situation, Cutter just about talks him into being more open-minded, when the actual chief of the Wavedancers challenges Surge (his father). The chance is lost, and Surge reverts to his paranoid control-freak persona. But in the end, he does sacrifice himself to save Cutter, and there is an afterlife for elves, so it's kinda okay.
At the end of the Dashverse story May the Best Friends Win, Rainbow Dash tells Trixie she can either leave town, thus ending their friendship, or stay and try to make amends for her actions, giving them a chance to rebuild. She chooses the latter.
In the My Little Pony: Friendship Is Magic/Mass EffectFusion Fic, Mass Effect The Equestrian Equation, it is instinct to do this to any potential opponent for both the Equestrians and their ancient ancestors, the Equines. However, having evolved from prey animals, they are a lot shorter-tempered with outsiders trying to pick on the small, harmless-looking critters than they are with each other. At one point, Twilight gives a broadcast explaining that while Equestrians have an elaborate conflict solving/defusing social ritual, it only applies to their own kind; other species get given one chance to back down, and then are immediately attacked with everything the Equestrian has to offer.
Occurs in Batman Returns, where Bruce gives Catwoman the offer to live happily ever after with him in his mansion. Her answer, she could never live with herself.
The ending of Falling Down has Det. Martin Prendergast asking William "D-Fens" Foster to surrender so that he can still watch his little girl grow up. Foster refuses, insisting instead on a final shoot-out with Prendergast. It turns out to be Suicide by Cop, since Foster only has a water pistol.
In the 2000 version of Jesus Christ Superstar, after a much more taunting version of the climactic song than usual, Jesus reaches out to Judas, who rejects him one last time. Once Jesus is back in the physical world, the demonic showgirls vanish, and the last we see of Judas is of him suffering in Hell.
In the film version of David Brin's The Postman the title character does this to General Bethlehem after defeating him His reward? A predictable but failed attempt to stab him in the back.
Of course, the final scene in Return of the Jedi is an example of this in incredibly slow-motion, with Darth Vader refusing to save Luke several times before finally saving him, and as always, Redemption Equals Death.
Offering a Last Second Chance to potentially redeemable opponents is the Jedi's counter to the Sith's "Dun Moch".
In Robot Jox, the two leading robot pilots, hero Achilles and villain Alexander, end up fighting it out hand to hand after they destroy each others' mecha. After a Not So Different realization that they are both just soldiers for their corporate masters, Achilles offers Alexander a chance to end the fight in an honorable draw that would let them both survive. Unusually for this trope, Alexander accepts the offer, and the movie ends with the two saluting each other.
In the new Star Trek film, the villain is on the ropes and is especially spiteful in turning down his Last-Second Chance. "I would rather suffer the end of Romulus a thousand times! I would rather die in agony than accept assistance from you!"
In Search for Spock, Kirk tries to save the Klingon commander from falling into a lava field. Of course, Klingons being Klingons, the commander tries to drag Kirk down with him; and gets kicked off.
"I... have had... enough of... you!"
Transformers: Dark of the Moon has Optimus trying to awake some good in his old mentor Sentinel Prime but fails and ultimately forcing him to execute the latter. When Sam Witwicky was fighting Dylan Gloud in the final battle, he tried to reason with him but likewise, said person didn't listen.
Taken 2: Bryan Mills tries to offer the Big Bad Murad a chance to walk away in exchange for leaving his family in peace. Murad blows it.
At the end of Indiana Jones and the Last Crusade Dr. Elsa Schneider had a second chance when Indiana dove for her hands as she almost fell into an abyss. All she had to do was let him lift her up to safety; instead, she pried one of her hands free to reach the grail underneath her. As she stretched, the glove on her other hand came off slowly but surely, resulting in a fatal plunge.
The Grapes of Wrath has an odd example, when Jim Casy tries to talk a strikebreaker into switching sides, because the strikers can't afford any more wage cuts. Said strikebreaker bashes his head in.
Gandalf offer one to Saruman in The Two Towers, and while Saruman actually considers it seriously for awhile, his overwhelming pride and jealousy of Gandalf make him ultimately refuse. And then he gets offered another one toward the end of The Return of The King.
Galadriel: Saruman, we have other errands and other cares that seem to us more urgent than hunting for you. Say rather that you are overtaken by good fortune, for now you have a last chance.
Saruman: If it be truly the last, I am glad, for I shall be spared the trouble of refusing it again.
In The Silmarillion, Maedhros and Maglor receive one from Eönwë, after they demand the remaining Silmarils from him. Eönwë tells them that they no longer have any right to the Silmarils, and gives them a chance to return to Valinor and be judged by the Valar for their crimes. Maglor wants to go and tries to persuade Maedhros, but Maedhros refuses, and in the end persuades Maglor to go along with his plan to steal the Silmarils from Eönwë. Needless to say, it doesn't end well...
The Scarlet Letter: Hester Prynne, title character, gets one against a passive-aggressive villain, just after he's had his epiphany.
Chillingworth: Thou hadst great elements. Peradventure, hast though met earlier with a better love than mine, this evil had not been. I pity thee, for the good that has been wasted in thy nature! Hester: And I thee, for the hatred that has transformed a wise and just man into a fiend! Wilt thou yet purge it out of thee, and be once more human?
In A Song of Ice and Fire, Theon Greyjoy is offered the opportunity to be conscripted into the Night's Watch as an alternative to being executed after his botched invasion of Winterfell. He considers the offer, but his acceptance of it is interrupted by the invading Bolton army, who drag him away to a much worse fate.
In the Dale Brown novel Shadows of Steel, Madcap Magician attempt to persuade Admiral Tufayli to surrender so that he and his men can be treated and released. The other guy doesn't bite.
In the Star Wars Expanded Universe book Dark Rendezvous, Yoda travels to meet with Count Dooku, his former pupil, to negotiate an end to the Clone Wars. Dooku tells Yoda that what started out as an idealistic crusade has gone horribly wrong and that he's in over his head, and Yoda offers to let Dooku return home to the Jedi Order. Darth Sidious however gets wind of what's going on, and playing off Dooku's dislike and jealousy of Anakin Skywalker, sends none other than Anakin and Obi-Wan to go "help" Yoda. When battle breaks out between Dooku's guards and the two younger Jedi, Dooku assumes that Yoda brought them along as reinforcements and feeling rather betrayed, he flees the scene.
In Darth Bane, one of Bane's former comrades from his days in the Sith Army reaches out to him and tries to get him to turn away from the path of the Sith. It almost seems like it will work, and for a brief moment Bane is Dessel again. His own apprentice Zannah kills his comrade to stop it, and the moment passes.
Lanfear also gets one of these. It actually looks like she seriously considers taking it for a moment, but of course she doesn't. Cue Neck Snap. There's more than a bit of Alas, Poor Villain about this one.
In Doctor Who, the Tenth Doctor makes a point of offering most of his enemies a peaceful resolution if possible. Woe betide them if they refuse... "No second chances. I'm that sort of a man." In his tenure as the Doctor, exactly one villain ever took him up on this. Still, he's often inconsistent and generally never stops trying to get the enemy to come over to the light.
In The Sarah Jane Adventures, Sarah Jane also tends to do this. Three guesses where she learned it from, and the first two don't count.
In Stargate Atlantis, Sheppard's team repeatedly tried to convince Lt. Ford to return to Atlantis to get cured to no avail. Note that he was not an actual villain, but just crazy because of the wraith enzyme that he was addicted to and prone to endangering the lives of expedition members without realizing it.
Averted in an early episode of Andromeda where Trance offers a second chance to the man who killed her in the pilot, and after a few threats and a chase scene he accepts. As Trance explained to Harper at the end of the episode. "Everyone deserves a second chance.... or as many as they need."
Turned up to 11 in Xena episode "Tsunami": Villain tries to kill Gabrielle, Xena says "If you do that again, I will kill you." Villain tries to kill the Captain, Xena says etc. etc. Villain tries to kill the pregnant woman, Xena says etc. etc. Villain tries to kill everybody, Xena says etc. etc. Repeat for 40 minutes.
Occurred once in Farscape, when Crichton tries to convince Pathfinder Neeyala to help save Moya instead of her research vessel, offering to return her to her home planet. Neeyala coldy refuses, explaining that returning home without her ship and its precious data would be punished with her execution, the execution of her family, and the families of her crew.
Michael Westen offers one of these in the Burn Notice episode "Friends and Family", as outlined in a page quote.
Faith: Give me that speech again. [...] It's not too late, we can still save you.
Willow: It's way too late.
Used in The Vampire Diaries on Damon, who is seemingly permanently on this trope, usually with Bonnie, on occasions with Elena & Stefan. Due to Contractual Immortality it's unlikely he'll ever get his full comeuppance.
Hardly surprising. Can you imagine how boring the show would be without him?
Averted for Sonny Steelgrave in the first season of Wiseguy: although Vinnie admits to Sonny that he would have given him a Last-Second Chance to elude prosecution, Sonny murders a man in cold blood while Vinnie's hidden video camera is recording him, making it impossible for Vinnie to invoke this trope for him.
In the Christian radio drama Adventures in Odyssey, Mr. Alan gives Dr. Blackguard a chance to redeem himself after his plot to collect a mineral that could be used to produce a super virus he was planning on selling. The Dr. says he's beyond saving, and decides to trigger a bomb to take him, Mr. Alan, and much of Whit's End out. Ironically in a scene, and part of an arc that the show's creators would have criticized for being too violent if it had been in a visual form rather than audio only.
Depending on the ending you're going for in Devil Survivor 2, you can do this to all your former party members after defeating them.But notable examples are Yamato and Ronaldo, who will either become available to recruit, try a last-ditch attack against one of your party members (disregarding the fact that he's a Physical God), or, in Yamato's case, perform a Heroic Sacrifice by pushing you out of the way of a falling tower.
In the Tales series, the heroes almost always try and reason with the Big Bad at the end, which never works.
Hell, the Player Character can get one if you choose to go down the path of the Dark Side if Revan is female and began a romance with Carth. True to the trope (patches notwithstanding), your character spits in the face of opportunity and you get the choice of killing Carth yourself or having Bastila do it for you... the ending in which it would have been possible to accept the offer and die together saving the Republic was cut from the game. Oh well.
Those are actually only the major characters, the game gives you the option to offer the Last Second Chance to pretty much every single Dark Jedi that doesn't attack you on sight. Only a handful of them will accept it.
Including one who's long past his last seconds; you can redeem his ghost.
The second in command of the Korriban Academy, Yuthura Ban, will actually accept it if your diplomacy's good enough and you've talked to her about her motive beforehand.
Kyle Katarn to Desann in Jedi Outcast, as seen in the page quote. No luck, but at least it manages to make him angry. Kyle's student Jaden Korr has even less success trying this on Alora in the next game; she just laughs.
One of the major villains in Chrono Trigger, Magus, gets one of these. In the final battle against him, when he realizes that he has lost, he admits defeat and invites you to kill him. However, you can take the merciful route, and not only let him live, but convince him to join your party to fight against the realBig Bad.
However, Bryce, the last of the Four Riders, plays this trope straight to the hilt, as his loyalty is to the Daein crown, no matter how insane its sovereign may be. This happens after Ashnard admits to killing everyone ahead of him in line for the throne, including his own father, the previous king to Bryce's face. Further, fighting him with Tauroneo, a former Rider of Daein and Bryce's old comrade, causes a bit of bonus dialogue where he admits that he realizes Tauroneo's decision to defect is more just, but that there are some people who can't change their ways.
Also notable is General Shiharam, father to party member Jill. Already a defectee from Begnion rather than serving the corruption in the senate, he sees his service to Daein as the only way to be sure that his troops have a home to come back to, following the orders of General Petrine who openly despises him as a foreigner in the process, and ends up dying to accomplish nothing. In an ironic turnabout, fighting him with Jill is a double Last-Second Chance both ways: if Jill does not have a support built up with one of the other characters, she'll switch sides and fight alongside him.
Path of Radiance's sequel, Radiant Dawn, plays this straight more often. Jarod is given this choice when outnumbered and outmaneuvered at the end of the first act, and the final act features this choice given to Hetzel, Levail, Dheginsea, Nasir and Gareth if you choose to attack them, and finally Sephiran.
Radiant Dawn also subverts this a few times as well, with Ludveck, who pre-emptively accepts the Last Second Chance and surrenders before Elincia takes his head off and Oliver who volunteers to defect to the good side without any effort on the player's part if he spots Rafiel, much to everyone else's discomfort. Furthermore, with a little hoop jumping, Sephiran will actually accept rather than refuse his Last-Second Chance on the second play through the game.
Seifer gets one of these just prior to the last fight with him in Final Fantasy VIII. Naturally he refuses it, claiming that he's gone too far to stop now. The ending sequence implies that, because he was fortunate enough to survive, he actually does renounce his evil ways, though it's a little ambiguous.
At the end of Final Fantasy IX, right after the final boss is defeated, Kuja, the villain and Zidane's brother, is dying inside the roots of the Iifa Tree when he realizes the mistakes that he's made in his life, resolving to at least try to make up for them by teleporting Zidane and his friends with the last of his power safely away from the now convulsing roots of the dying tree. Zidane, being the good guy that he is, heads straight back into the roots, where he finds Kuja and tries to convince him that he doesn't have to die just yet, and that he can make up for what he's done. Kuja thanks Zidane for the offer, but knows that he's finished. Just then a root heads straight for them, with the scene fading to black right as it's about to hit. It's heavily implied that Kuja died saving his brother from the root, making this a Redemption Equals Death situation.
In Gabriel Knight: Sins of the Fathers, the player has a choice to either try to kill or save Malia at the end. Choosing the latter has her refusing to be saved as she sacrifices herself to destroy Tetelo.
You can offer this to a lot of characters in Baldur's Gate, most notably perhaps Yoshimo. He doesn't, or rather, can't, take it.
In the game Mercenaries: Playground of Destruction, you play as a mercenary blowing stuff up for money, eventually making many people angry at you. However, those same people know that if they pay you well, you will end up destroying your own clients, so these people come up with a deal. You give them a cut of the paycheck you received from your previous client (say, $100,000-$500,000), and they give you a brand new job. This, of course, leads to a cycle of you betraying every single faction of the game, and THEY STILL WILL HIRE YOU! Lampshaded when the leader of the South Korean faction, a CIA Spook, said, "This is your last second chance."
In Planescape: Torment, you can also offer try this trope at a few characters, most poignantly to Trias the Betrayer by reminding him that the Upper Planes are also a place of forgiveness. Bring Vhailor with you and it's a moot point, however, as he'll strike Trias down whether you succeed or no.
Mass Effect 1 has one of these just before the final confrontation with Saren. If you succeed, he commits suicide. Sovereign still reanimates his corpse for the final battle, however.
In Mass Effect 2's Arrival DLC, a Paragon Shepard gives this to the DLC's main villain, Dr. Amanda Kenson. Sadly, by this point, she's too heavily indoctrinated to be helped, and triggers a bomb to try and take Shepard with her.
In Mass Effect 3, Shepard gave this by showing mercy to Kai Leng after their final confrontation, leaving him beaten-but-alive on the floor. Cue Leng realising far too late that he really should have stayed down.
In the Citadel DLC, Paragon Shepard gives this to both the DLC's Big Bad and their Dragon. The Big Bad refuses, playing the trope straight, but the Dragon will actually take the chance (if Shepard is being really Paragon), and quietly goes to jail rather than continue to fight.
In Dissidia: Final FantasyCecil offers a place among the Warriors of Cosmos to his designated nemesis, Golbez. He does this because, at this point, he knows that Golbez is his brother, and not entirely responsible for the evil he committed in their homeworld. Golbez refuses the first time, telling Cecil that he has done too much to be forgiven at this point. After their final final battle in Shade Impulse, Cecil offers him the same thing, and this time, while he still turns away, Golbez acknowledges that there may be hope for him someday.
"But... maybe someday. If the light should smile upon me..."
In Halo 2, the Arbiter attempts to talk Tartarus out of activating the Halos. After presenting evidence (in the form of an "Oracle", Guilty Spark, even) of the true purpose of the rings, Tartarus seems to consider stopping... but instead knocks Johnson away with Spark, forces Miranda Keyes to insert the Activation Index, and haughtily claims that his race will rise above the Elites.
Notable in that the Elites and Brutes are at each others' throats at the best of times, yet the Arbiter gives him a chance to step away without a fight even when he's about to destroy all life in the galaxy and orchestrated the death of hundreds of Elite elders. It shows the Arbiter's nobility, even compared to other Elites.
Boy, Gordon Frohman of Concerned gets his chances. Too bad he never makes proper use of any of them. He even manages to undo his Deus ex Machina.
In strip #913 of The Order of the Stick, Tarquin makes one last attempt to reconcile with Nale, even after Nale rebelled against him and killed his best friend Malack. Nale stubbornly refuses and declares that he wants nothing from Tarquin. Tarquin promptly stabs Nale to avenge Malack.
Zuko getting a last second chance was the major point of hype for the season 2 finale, a chance he blew when his sister played the "honor and father's love" cards. His Heel-Face Turn only came around when he finally got sick of playing along with her in the third season, by which point none of the viewers were surprised.
Of course, Aang gives one to Ozai, who just laughs it off.
Katrina from the second My Little Pony special is offered this — and she accepts.
Late in season 3, Celestia does this once again to Discord, enlisting Fluttershy to reform him. Surprisingly, it (mostly) works.
Bob from ReBoot actively tries not to delete Megabyte because he believes all viruses can be redeemed and believes that if Megabyte can it would serve as the ultimate example. He has some backing for this: as he points out, if he had deleted Hexadecimal earlier in the series instead of trying to redeem her, the entire Internet would have been destroyed in the first movie.
The second season of the animated Teen Titans series ended with one of these, with Terra sacrificing herself to stop a volcanic eruption. Note that in the comics she was much less sympathetic, so naturally she didn't get this treatment.
Nox, the Big Bad from Wakfu is offered this after his plan to travel back in time to save his family fails. In a bit of a twist on the norm, he accepts and retreats. The finality of his last line hints that he does not intend to return.
In Transformers Prime, Dreadwing is disillusioned with the Decepticon cause after discovering just how little honor really matters to Megatron. He then aids the Autobots by giving them the Forge of Solus Prime. Optimus once again asks Dreadwing to join the Autobots. Dreadwing refuses, since betraying the Decepticons doesn't mean he is ready to join the Autobots. Dreadwing then returns to the Nemesis and takes actions that he almost certainly knows will lead to his death and indeed they do.