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Nightmare Fuel: Shatterheart
Kurogane's reaction when Syaoran impulsively kisses him the first time. He gets so angry that he flats out attacks Syaoran and would have done worse if Syaoran hadn't run to his room in time. Just the image of Kurogane banging down the door so hard that he nearly breaks it while Syaoran hides in a corner and prays for him to not get in, establishes that Syaoran is not even safe from his own friends.
When Fai realizes that Syaoran has disappeared during their outing to bookstore after Fai tries to make amends. He frantically searches for him to no avail and how he finds Syaoran's blood in a back alley.
When Syaoran get kidnapped while on outing with Fai. Turns out those gang members that attacked him earlier in the story? Their leaders are Serial Killers, who picked Syaoran as their next victim.
Syaraon's time in the gang's Torture Cellar. He tortured for sixteen hours barely hanging on the hope that Kurogane will rescue him.