The baby crocs in "Mom of a Croc". And the way they're calling for their mother.
Any time Blur appears. The first time, she's chasing Chris (who's an antelope thanks to his Creature Suit) and decides to cuddle him. Then there's also the time where she's with her son.
In "Flight of the Pollinators" a miniturized Chris goes missing after getting stuck to a bee due to being covered in pollen. Throughout the episode, Martin expresses guilt over letting it happen and worry for his brother's safety as he searches for him.
The Wild Kratts sending Donita the faux spider silk to use in her dresses, even after everything she's done to them.
From "Race for the Hippo Disk", Chris being genuinely concerned about Zach after he almost fell into a hippo's mouth (although we wouldn't expect anything less from the Bros).
Chris: Whoa. You okay?
In "Bat in the Brownies", Koki start feeling sorry for the bats when their tree home is destroyed. She immediately helps in the efforts of giving them new homes. And even lets builds a bathouse for Bitesize.