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His appearance on MTV's After Hours with Josh Horowitz.
Tom discovered the joys of the American restaurant chain Chili's while shooting , Thor thinking it was the greatest thing since sliced bread (for the record, Chili's is what's called a "casual dining" restaurant, a collection of medium-range restaurants that aren't as bad as fast food, but aren't exactly considered fine dining either, kind of the food equivalent of So Okay, It's Average.) His Avengers co-stars were, well, less than impressed.
Clark Gregg: [Tom's] line was, (in a fake English accent) ‘I went to this marvelous place called Chilli’s here in Albuquerque.’ We’re like listen, Tom...
When asked by an interviewer what his taste in Music was, he mentioned a few bands before saying he was a big fan of hip-hop and knows the lyrics to Will Smith's "Miami". He then proceeded to rap the first verse. Its exactly as awesome as it sounds.
Tom Hiddleston vs. Loki's Twitter account.
That time he was eating chocolate before an interview and apologized profusely ... with his mouth still very full.
Getting interrupted by Scarlett Johanassen and Jeremy Renner.
Tom: I'm trying to explain who I am, can you tell them who I am?
Jeremy Renner: Bad.
Scarlett Johanassen: To the core.
Even funnier how he was interrupted - Jeremy Renner did a quick slap on his rear. When he tried to retaliate, he accidently grabbed Scarlett's back instead.