Acquired Situational Narcissism: Charles starts out as a pleasant, unassuming English instructor, but as soon as he gets famous he starts timing his arrivals at the university so as to coincide with the students coming out. Eventually it wears off, as he starts to regret his involvement in the fix.
Eternally Pearly-White Teeth: Inverted. One of Herb's teeth is actually brown, and at one point he asks his wife if she thinks he should get them capped. Definitely a factor in why the sponsors decide they've had enough of him.