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I will comment about the FiveManBand placement. Overall, it is agreeable for the big fight that Scarlet Witch took TheBigGuy position for one thing: She's extremely immobile, having to sacrifice her mobility that she used in the beginning of the movie with her high firepower.
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Not sure if Black Panther fits Big Guy. However, Ant Man and Spider Man fits more as TheSixthRanger, since they were completely new recruits brought solely for the fight.