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I'm not sure if this is a movie or an episode. I saw it in the early 2000s, say up to 2007.
While channel browsing I stumble upon a movie where a guy is at a stoplight, followed by a blonde behind him. She comes out of the car and unravels her coat to flash him her breasts. He sees it in the rear view mirror and chuckles. Then he goes to have lunch with a brunette, turns out he's a cop and she's his partner. He tells her about the blonde, they laugh at the situation. The partner, named Diane or Diana, seemed to know her, she must've been an ex.
This looked to be in a small town, it was mostly empty & they had the wide long style American cars. They do get back together for a while, I think she even slips in his shower saying "I promise to be good". But she turns out crazy and in the end, the brunette arrives just in time to shoot the blonde.
So it's like Fatal Attraction basically. The two looked like the characters of Silk Stalkings, but the guy with darker hair. There is an episode of it that seemed to match, Dark Heart but no. Also NYPD Blue with "the kookie bookie" had a woman stalker. I tried "sexy coat flashing" and "psycho ex gf" on this site and it's not there.
Edited by kaletan