Battlestar Galactica: it's a natural state for them (or as natural as Artificial Humans ever get), but each of the Significant Seven models has an army's worth of clones.
In Castelo Rá-Tim-Bum, Nino invents a calculator that can make living clones of people.
In the episode "Which Prue is it Anyway?", Prue decides she needs a power boost, and casts a spell to triple her power. Unfortunately, she doesn't realize that what it actually does is create three of her. It turns out to be useful, after all, because the two clones end up dying instead of the original Prue.
When Piper finds out that the Angel of Death is after her husband Leo in the episode "Vaya con Leos", she decides to cast a spell to hide him. While the spell does confuse the Angel of Death, it had an unintended effect: every man in San Francisco got turned into a clone of Leo.
Variation: thanks to The Nth Doctor, there's currently fourteennote counting the War Doctor different incarnations of the Doctor running around space/time... it's extremely rare for them to meet (Timey-Wimey Ball, actors dying and all that), but when they do the result tends to be similar to this trope. The 10 Doctors is an artist's rendition, shall we say, of how the first ten Doctorsnote pre-the War Doctor being retconned in would act if forced to cooperate.
"The Deadly Assassin": While in the Matrix, the assassin takes on various generic historical personas (a samurai, a clown, a WW1 biplane pilot, etc.) to attack/frighten the Doctor (and the audience). At one point several of him seem to man several positions on a train (or trains) simultaneously to run over the Doctor's leg.
In another Fourth Doctor story, "The Leisure Hive", the villain Pangol used a form of Applied Phlebotinum to recreate himself thousands of times over as a conquering army. Thanks to the Doctor's interference he ended up with an army of Doctors, which disintegrated within minutes of their generation.
A straight example in "The End of Time": The Master hijacks the Immortality Gate to transform the entire human race except for Wilf note (locked in a radiation-shielded booth) and Donna note (thanks to the events of "Journey's End" making her half-Time Lord) into "The Master Race", a planet-wide population of (insane, madly laughing) Master copies.note Luke Smith is an Artificial Human, so he may have also remained unchanged; he appears in the denouement but doesn't address his own fate.
An episode of Eureka features Dr. Stark accidentally cloning himself. The clones try to take over the world. Long story.
In the "Fastest Man Alive" episode of the 2014 The Flash series, Barry has to fight another meta-human who eventually gets named Multiplex. Multiplex's body, after the S.T.A.R. Labs particle accelerator explosion, appears to be made out of stem cells, which he can split off into copies of himself as he chooses (even clothes, apparently). All the copies are under his direct mental control. His main goal is to get revenge on Simon Stagg, who stole his organ cloning research and fired him before Multiplex could use it to save his dying wife. As the good guys figure out, Multiplex can be spotted among his doubles by the amount of stress he experiences from controlling the Hive Mind. Thanks to his hyper-accelerated perception, Barry is able to spot beads of sweat on one of the figures among the hundred or so copies.
In the episode "Aruba", Eobard Thawne brings an entire army of himself from various points across history (and some time remnants to boot) to confront the Legends.
In Game of Thrones, the warlock Pyatt Pree appears to create a double of himself, although many of those watching think the warlocks are charlatans and this is just a trick. It's revealed in the next episode that he really can do this, and create more than a single copy too.
Eli, Samuel Sullivan's right-hand man (men?) in Heroes.
In the Honey, I Shrunk the Kids episode "Honey, I Got Duped", Wayne accidentally clones himself, and the clones are given names such as Slappy and Scabby.
In Kamen Rider Ex-Aid, Kuroto can send phantom copies of Genm to other places to fight in his stead once he achieves Level X.
Kamen Rider OOO has this power as the Set Bonus for his GatakiribaCombo. It doesn't get used very often because (In-Universe) it's physically taxing and because (in Real Life) it's reportedly a very expensive effect. The Movie contains a special usage, where OOO splits into eight copies and then each one transforms into one of his primary Combos to fight the Big Bad.
In the later series Muppets Tonight, Gonzo somehow creates multiple copies of himself to perform a musical number. Fittingly, that number is Dancing With Myself.
The Monster of the Week of an episode of Power Rangers Dino Thunder had the power to create copies of anything in front of him. At one point, he made three copies of Cassidy on the spot, and the four of them proceeded to drive Devin crazy by stacking him with chores.
In the ReBoot: The Guardian Code episode "Game Day", Megabyte uses a code replicator to make copies of himself.
Round the Twist has a character make only one clone to win a running competition. However, a rabbit starts cloning an army of itself with the machine. All the objects used in the machine, cloned or original, begin to dissolve eventually, due to a fault in the machine. At least one rabbit survives, though, because in the final scene we learn what happened when Bronson put her with a male rabbit.
In one episode of Smallville, Monster of the Week Ian Randall has the power to create a clone of himself so that they can study in two places at the same time.
An arc in the later seasons of Stargate SG-1 had Baal make dozens of clones of himself, and in a few episodes set on Earth at least five of them hung out together. One episode even has a Gotta Catch Them All where the heroes travel the galaxy, trying to scoop up all the Baal clones. A freeze frame near the end of the episode shows fifteen clones in one room. It turns out it was a Batman Gambit. Baal knew the heroes would give him the info he wanted to buy time when he had hostages, as long as they knew he couldn't escape with that info. And the clones? Each one has a transponder, too weak to be detected, but if they all stand in one place...
Star Trek: Picard: The five Emergency Holograms on La Sirena all look like and are based on Cristóbal Rios (the owner and pilot of the ship), and all of them can be called upon at once if needed.
In Uchu Sentai Kyuranger, the rangers can make copies of themselves with the Gemini Kyutama.
Ultraman Gaia: Ultraman Gaia manage to slice Satanbizo into 8 pieces in their battle, only for each piece to regenerate into a tiny clone of Satanbizo, each capable of acting independently on its own.
During the Final Battle of Ultraman Geed, Geed's Heroic Willpower calls down a miracle from Ultraman King, allowing him to manifest all of his forms at once to battle Belial Atrocious.
In Ultraman X, the titular Ultra can use his Xlugger ability to split into four different colored clones.
In the You Can't Do That on Television episode "Science", Alasdair develops a cloning machine and tests it out on "motormouth" Lisa, much to the chagrin of the others.
