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UK
Jamie Winton
- Portrayed by: Mathew Baynton
- Doorstop Baby: He was left in a car park in Slough.
- The Everyman
- Oblivious Adoption: He does not know he was adopted, or that he has a twin brother, until he is arrested for cyber crimes the day the news of the comet breaks.
- Separated at Birth
- Weirdness Magnet
Dave Bosley
- Portrayed by: Joel Fry
- May–December Romance: With Paula.
- Professional Slacker
- Only Sane Man: Has shades of this, particularly whenever Jamie is freaking out.
Paula Winton
- Portrayed by: Pauline Quirke
- Mama Bear: Do not mess with her Jamie, or you'll regret it.
- May–December Romance: With Dave.
Hawkwind "Layla" Winton
- Portrayed by: Karla Crome
- Defecting for Love: Originally Ariel's wife Hawkwind, she posed as Layla as part of Ariel's plan to mess with Jamie's life. She ended up falling in love with him for real.
- Mama Bear: She found out she was pregnant on their honeymoon, but left Jamie and went into hiding to protect both him and the baby from Ariel.
Frankie Winton
- Portrayed by: Grace Taylor
- Waif Prophet: After briefly dying in a car crash and coming back to life, she claims to hear a voice in her head that tells her things she would have no other way of knowing, i.e. that Celine is pregnant with Jude's baby.
Ariel Conroy
- Portrayed by: Mathew Baynton
- Betrayal Insurance: One of Ariel's favourite tactics.
- CriminalDoppelgänger
- Determinator: Ariel literally will not stop until he gets what he wants...
- Even Evil Has Standards: He's a psychopathic murderer, but he's also obsessed with manners and not putting people's feet in food processors...
- Evil Twin: To Jamie.
- Hollywood Hacking
- Separated at Birth
- Stalker with a Crush: To Layla/Hawkwind
- Terrified of Germs
- Twin Switch
- Yandere: For Layla/Hawkwind
Mary Conroy
- Portrayed by: Anastasia Hille
Lady Sutton
- Portrayed by: Diana Rigg
- Faking the Dead
- May–December Romance: With her doctor. The jury's still out on whether it's entirely mutual though...
- Missing Mom: She has abandoned her children, Jude, Rhonda and Scotty.
Vatican
Father Jude Sutton
- Portrayed by: Rob Lowe
- Badass Preacher:
- Bunny-Ears Lawyer: Father Jude has his own approach to things, he smokes like a chimney, swears like a sailor and has a generally casual attitude but he is a devout priest with real faith in his God and a caring man.
- Disappeared Dad: He had a fling with Mary in Slough when he was 18, before joining the priesthood.
- He Knows Too Much: Is killed by the Vatican after protesting against their plan to announce a new fake Messiah, the second coming of Jesus.
Sister Celine Leonti
- Portrayed by: Gaia Scodellaro
- Crisis of Faith: After Jude dies.
- Raised by Natives: Celine was taken in by the convent after being found homeless and penniless, and she joined the order later on.
USA
Rhonda McNeil
- Portrayed by: Jenna Fischer
- Fish out of Water: When in prison.
- Mama Bear: Her main desire is to be with him again before the apocalypse.
- Taking the Heat: She is covering up for Spike's crimes.
Leanne Parkins
- Portrayed by: Megan Mullally
Spike McNeil
Rhonda's son, custody of whom was given to his biological father, Tim.Scotty McNeil
- Portrayed by: Kyle Soller
- Straight Gay
- Badass Pacifist: Couldn't hurt a fly, but that doesn't stop him from taking down a terrorist and stepping in front of a bullet.
General Arnold Gaines
- Portrayed by: Paterson Joseph
- Good Is Not Soft
- Necessarily Evil: One word - Shanghai.
US President Farrell
- Portrayed by: Lloyd Owen
- All There in the Manual: His name is only mentioned in publicity materials, never on screen.
- Killed Off for Real: Gaines shoots him before he enters Mount Genesis, as he feels the new world order would be better without him.
- President Corrupt
Rajesh
Rhonda's husband, hospitalized for cancer.- Portrayed by: Prasanna Puwanarajah
- Heroic Sacrifice: Rajesh stays outside the bunker in order to close the door. By ramming it with a van.
- Parental Substitute: Spike regards him as his father.
- Your Days Are Numbered: He has been diagnosed with a fatal cancer, and only has weeks to live.
Max
- Portrayed by: Edward Judge