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Alston Family
Ron Alston
- Played by: Ron Daise
Natalie Alston
- Played by: Natalie Daise
James Alston
- Played by: James Edward Coleman II
- Cool Big Bro: To his younger siblings Shaina and Simeon and his cousin Vanessa.
Vanessa Alston
- Played by: Vanessa Baden (speaking voice), Hillary Hawkins (singing voice)
- Fear of Thunder: She has a fear of thunder and lightning as it was shown in "Lightning is Frightening".
- Tomboy and Girly Girl: The tomboy to Shaina's girly girl.
- Tomboy with a Girly Streak: She was stated to be a girly girl in "Please Don't Eat the Alstons".
- Vocal Evolution: Her speaking voice sounded more older in the fourth season.
Shaina Alston
- Played by: Shaina M. Freeman (Seasons 1-3), Tristin Mays (Season 4)
- Annoying Younger Sibling: She sometimes gets on her cousin Vanessa's nerves.
- Girly Girl with a Tomboy Streak: She likes to play baseball.
- Tomboy and Girly Girl: The girly girl to Vanessa's tomboy.
Simeon Alston
- Played by: Simeon Othello Daise
- I Got Bigger: The first season shows him as a baby, and the fourth season shows him as a toddler (almost a kid) speaking sentences.
Armando's Family
Armando
- Played by: Armando Guerra
- Annoying Younger Sibling: He sometimes annoys his big sister Marisol.
- I Got Bigger: The first season shows him as a kid, and the fourth season shows him as a teenager.
- Vocal Evolution: His voice got deep in the fourth season.
Marisol
- Played by: Ana Christina Randolph
- Cool Big Sis: To his little brother Armando.
- Put on the Bus: After the second season, she does not appear for the rest of the series.
Abuelo
Juana
- Played by: Iris Chacón
Other Characters
Binyah Binyah Polliwog
- Played by: Philip D. Garcia (Seasons 1-3), Justin Campbell (Season 4)
- Catchphrase: "Binyah Binyah!" or "Binyah Binyah Polliwog!", "Binyah Binyah, uh-oh!"
Grandma Pixee
Bryan
- Played by: Bryan Nguyen
- Ascended Extra: Appears in more episodes in the first two seasons of the series.
- I Got Bigger: The first season shows him as a kid, and the fourth season shows him as a teenager.
- Kids Love Dinosaurs: He's a dino lover, according to the Season 2 episode "Whose Friend Are You Anyway?" during the song "Jump In, Jump Out".
- Out of Focus: He only appears in four episodes of the third season and three episodes of the fourth season.
- Vocal Evolution: His voice got deep in the third season.
Jessica
- Played by: Jessica GorskiFirst appearance: Yes I Can!
- Tomboy and Girly Girl: The Girly Girl to Mia's tomboy.
- Out of Focus: She only appears in three episodes of the third season.
- Vocal Evolution: She sounded more older in the fourth season.
Mia
- Played by: Mia Barrington
Greg
- Played by: Greg Davis, Jr.First appearance: Whose Friend Are You Anyway?
- Kids Love Dinosaurs: He loves dinosaurs. He even states that he collects toy dinosaurs.
Sara
Shaina's best friend.
- Played by: Sara Makeba DaiseFirst appearance: Yes I Can!
Corey
One of Shaina's best friends.
- Played by: Corey HayesFirst appearance: Friendship-Just the Perfect Blendship
Ranger Mike
- Played by: Ranger MikeFirst appearance: The Binyah Binyah Polliwog Show
Miss Audra
- Played by: Anita Endsley
Zachory
- Played by: Zachary Chartier
Miguel
James' new friend who only appears in "James' New Buddy".
- Played by: Cristian Sola
Chansome the Pelican
- Played by: James J. KroupaFirst appearance: Away All Boats
- Out of Focus: He only appears in two episodes of the fourth season, as compared to only five absences in the third season.