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Season 5, Episode 16:
The Dark Side of the MoonSam and Dean are shot to death by a pair of angry hunters and find themselves in Heaven. They are contacted by Castiel, who asks them to find Joshua in the hopes that he knows where God is. Sam and Dean must make it to the Garden in the middle of Heaven without letting Zachariah find them and return them to their earthly bodies. They travel through a series of their fondest memories. Dean becomes angry at Sam because several of Sam's happiest moments were times when he got away from his family.After a reunion with Ash and Pamela, Sam and Dean are cornered by Zachariah. They're saved by Joshua, who tells them that God has a message: back off. God knows everything that's going on, but he doesn't think it's his problem. Joshua returns Sam and Dean to Earth. They pass the news on to Cas, who is devastated. He gives the amulet back to Dean, who throws it away as they leave the motel.