Improbable Weapon User: Professional Wrestling aka: Pro Wrestling
Virtually everyone in pro wrestling has made use of what is the most iconic improbable weapon in the industry (heck, maybe in all pop culture): the steel folding chair. That it's synonymous with the profession should not detract from how odd it is to use one in the first place.
Practically every signature weapon used by any wrestler. The most iconic example in the business may be the original Sheik, who would carve his opponent's flesh with a sharpened pencil or launch fireballs at them. The second most iconic may be the dreaded fork of Abdullah the Butcher.
Finlay is known for using the ring apron as an impromptu net to trap opponents.
ECW's "The Innovator of Violence" Tommy Dreamer earned his nickname from his ability to make seemingly ANYTHING into a weapon (regularly leading to announcer Joey Styles saying, "The Innovator of Violence strikes again") , ranging from piledriving Raven on a cream pie to applying a cheese grater to Brian Lee's groin (which prompted Joey to say, "I'm not calling that.").
Averted by Triple H and his sledgehammer, which is not really an improbable weapon, except, of course, because of safety concerns, he can only bludgeon other wrestlers with the head, rather than swinging it at them.
William Regal and anyone else who made use of brass knuckles also averts this trope.