Episode 3 of season 2, when Muneakira tries to revive Kanetsugu after she's tossed into a river by a dark samurai. Despite all the trouble she's caused up to this point, when she regains consciousness and sees how hard he's trying to revive her, as well as crying for her, she begins to understand the bond and trust that the other girls have with him, thus allowing her to become a master samurai as well when he "kisses" her while performing CPR.
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