And, a few minutes before that when turning down the advances of a man attending the ball:
Charlotte: Travis. When a woman says "later", she really means "Not ever". Now run along. There are plenty of young fillies dying for you to waltz them into a stupor.
The way Charlotte reapplies her makeup super-fast upon seeing "Naveen", throws a handful of glitter into the air, and hurries down the stairs is pretty funny as well.
To viewers from Louisiana, the scene where Naveen says he is from a land far away (which Ray interprets as meaning Shreveport) is beyond hilarious.
Even after seeing it over and over in the ads, it's still hilarious:
Naveen: I am Prince Naveen... [Naveen is squished by a book] Naveen:...of Maldonia.
He introduces himself the same way to Charlotte near the end of the movie, with almost the exact same results.
Naveen: I am the real Prince Naveen... [Naveen is squished by a book] Naveen:...of Maldonia. Charlotte: Did you say "prince"?
When Dr. Facilier's talisman is broken, his "Friends" soon show up to claim their due. He tries to charm his way out one more time, greeting them with a cheerful "FRIEEEEEEENDS!" and a big wide ''scared out of his mind'' grin.
And they respond by shouting "ARE YOU READY?", making it clear that they're most certainly not his friends anymore.
Including this line, after his "Friends" sing, "Are you ready?"
"No! I'm not ready at all! In fact, I've got lots more plans!"
As horrible as Facilier's end was, a pause as he gets pulled into the portal shows his hat flew off and then fell back down.
"Well, yes, yes, you know WHAT? The egg is on YOUR face! Because I do not HAVE any riches! I am COMPLETELY BROKE! Ahaha-! Oh no."
Naveen: [seductively, as a frog] Come, we pucker! [his throat suddenly inflates and he lets out a loud croak]... [still seductive] That's new.
"PUT. THE MONKEY. DOWN."
Tiana's little hissy-fit as she works up the nerve to kiss Frog!Naveen.
The rare scenes in which Reluctant Monster Louis overcomes his timidity and acts upon his predatory "alligator" instinct; the first time clearing a crowd by scaring everyone during Mardi Gras and second time to persuade the realtors to sell Tiana the building.
Naveen's moth bow-tie. No cuter frog has ever existed.
Naveen: Well, waitress, it looks like we are going to be here for a while. We might as well get... comfortable. Tiana: [slap] Keep your slimy self away from me! Naveen: I told you, it is not slime! It is MUCUS!
When we first meet Mama Odie, after seeing her "eccentricity".
[Mama Odie falls asleep and Louis stares at her] Louis: Are you sure this is the right blind Voodoo lady who lives in a boat in a tree in the bayou? Ray: Pretty sure. Louis: [concerned Aside Glance]
The way Louis asked Ray implies that there are other blind old voodoo ladies that happen to live in boat in trees in the bayou.
The end of "Dig A Little Deeper".
Mama Odie: Do ya un'astand what ya need no', child? Tiana: Yes, I do, Mama Odie! I need to dig a little deeper and work even harder to get my restaurant. [everyone groans and Face Palms] Ray: Okay, everybody now. One more time! [singing] Don't matter what ya look like, don't matter what — ain't nobody gonna sing wit' Raaay, okay.
Anytime Louis gets a thorn from the pricker bushes.
Louis: PRICKER BUSHES GOT ME! GATOR DOWN, GATOR DOWN!! THE WALLS ARE CLOSIN' IN ON ME! IT'S SO COLD!
Ray's "-_-" Aside Glance and Ray going to pull a thorn out of Louis, causing him to scream in pain... "I ain't touched it yet."
Before Disguised!Lawrence and Charlotte's wedding, an aggravated Facilier throwing one of his cards at Lawrence.
Big Daddy's reaction to having a beignet he was about to eat snatched out of his hand by Charlotte.
A few seconds after this, when Charlotte gives Tiana enough money for the beignets to pay for the building, the look on Tiana's boss's face is absolutely priceless.
Big Daddy stuffing another beignet into Charlotte's mouth, so that he could finally put in a single word into her endless stream of chatter. This is made even better by the fact that right before this, it looks like Charlotte is going to let him talk... Then she interrupts him again, which is what causes Big Daddy to shove the beignet in her mouth.
Naveen's proposal. Even though that should count as heartwarming, it's just too hilarious to see him overdo it and just fall short of screwing up. Take a look.
Charlotte sweetly telling the fake Naveen to hurry up and finish getting ready for their wedding. . .then in a split second turning to her father and screeching at him to "START THE CAR!"
Charlotte yelling "Cheese and crackers!" when disguised Lawrence runs away with Naveen the frog after Naveen stops the wedding kiss from happening.
"Prince Naveen! Your shy and retiring bride-to-be is getting antsy!" (kicks in the door to the church)
The old firefly granny with the walker and a Clapper function on her bulb.
"What a coincidence Lawrence, I have been avoiding you everywhere!"
When Louis performs a variation of mouth to mouth on Ray, using a reed. It works, but Ray comments "Your breath done near killed me to death."
Louis having a fanboy spazz on the paddleboat at the chance to finally "play with the big boys."
"Gumbo, gumbo, in the pot, we need a princess. Whatcha got?" "Hush up and look at the gumbo."
The way Naveen puckers up for Charlotte's kiss, compared to the beginning.
Meta example. Jim Cummings is a voice actor who voices Ray and is well known for his Cajun impression. However, more and more Voice Acting is going to "Named" actors. During the audition process he joked that it would come down to him and Harry Connick Jr. When he got final callbacks, his agent told him it was between him and one other person. Harry Connick Jr.
When Tiana shows her mother the inside of the sugar mill, which is quite dilapidated.
Tiana: (cheerfully) Doesn't it make you want to cry?
Eudora:(not so cheerful) Yeeesss...
"Friends on the Other Side" is mostly Nightmare Fuel, but it also has this part:
Mama Odie: Now which one of you naughty children has been messing with the Shadow Man?
Everyone points at Naveen, who smiles nervously
Another brief moment in "Friends on the Other Side".
Facilier:[singing, about Lawrence] You've been pushed round by your mother and your sister and your brother. [Lawrence looks progressively more annoyed] And if you was married... [Lawrence looks very happy about that idea] ...You'd be pushed round by your wife! [Lawrence glares at him while Naveen laughs]
While Facilier is convincing Lawrence to continue impersonating Naveen, we get this line.
Facilier: And you and I can split the LaBouff fortune straight down the middle. Sixty-forty, like I said.
Also while he says the last line, he's looking away from Lawrence while rubbing a hand over his mouth like he's trying to lessen the chance Lawrence notices what he's saying.
Before this, Lawrence's Naveen disguise starts to wear off while he's with Charlotte. Cue him slowly switching back while trying to hide from Charlotte.
Mama Odie's epic Troll moment when she offers Tiana and Naveen candy and they turn down the offer.
Mama Odie: Now, that's too bad. This is a special candy. Woulda' turned y'all human. (pops the candy into her mouth as the two frogs frantically beg) I'm just messin' with y'all!
When Charlotte's kiss fails to turn Naveen and Tiana back into humans, she frantically keeps kissing Naveen. While the plot point itself is serious, the shot of Naveen with a Covered in Kissesdead-serious face shrugging as if to say 'Sorry, still ain't working', is hilarious.