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And, a few minutes before that when turning down the advances of a man attending the ball:
Charlotte: Travis. When a woman says "later", she really means "Not ever". Now run along. There are plenty of young fillies dying for you to waltz them into a stupor.
The superfast way Charlotte reapplies her makeup upon seeing "Naveen" and hurries down the stairs is pretty funny as well.
To viewers from Louisiana, the scene where Naveen says he is from a land far away (which Ray interprets as meaning Shreveport) is beyond hilarious.
Even after seeing it over and over in the ads, it's still hilarious:
Naveen: I am Prince Naveen... [Naveen is squished by a book] Naveen:...of Maldonia.
He introduces himself the same way to Charlotte near the end of the movie, with almost the exact same results.
Naveen: I am the real Prince Naveen... [Naveen is squished by a book] Naveen:...of Maldonia. Charlotte: Did you say "prince"?
When Dr. Facilier's talisman is broken, his "Friends" soon show up to claim their due. He tries to charm his way out one more time, greeting them with a cheerful "FRIEEEEEEENDS!" and a big wide ''scared out of his mind'' grin.
Including this line, after his "Friends" sing, "Are you ready?"
"No! I'm not ready at all! In fact, I've got lots more plans!"
"Well, yes, yes, you know WHAT? The egg is on YOUR face! Because I do not HAVE any riches! I am COMPLETELY BROKE! Ahaha-! Oh no."
Naveen: [seductively, as a frog] Come, we pucker! [his throat suddenly inflates and he lets out a loud croak]... [still seductive] That's new.
"PUT. THE MONKEY. DOWN."
Tiana's little hissy-fit as she works up the nerve to kiss Frog!Naveen.
The rare scenes in which Reluctant Monster Louis overcomes his timidity and acts upon his predatory "alligator" instinct; the first time clearing a crowd by scaring everyone during Mardi Gras and second time to persuade the realtors to sell Tiana the building.
Naveen's moth bow-tie. No cuter frog has ever existed.
Naveen: Well, waitress, it looks like we are going to be here for a while. We might as well get... comfortable. Tiana: [slap] Keep your slimy self away from me! Naveen: I told you, it is not slime! It is MUCUS!
When we first meet Mama Odie, after seeing her "eccentricity".
[Mama Odie falls asleep and Louis stares at her] Louis: Are you sure this is the right blind Voodoo lady who lives in a boat in a tree in the bayou? Ray: Pretty sure. Louis: [concerned Aside Glance]
The end of "Dig A Little Deeper".
Mama Odie: Do ya un'astand what ya need no', child? Tiana: Yes, I do, Mama Odie! I need to dig a little deeper and work even harder to get my restaurant. [everyone groans and Face Palms] Ray: Okay, everybody now. One more time! [singing] Don't matter what ya look like, don't matter what — ain't nobody gonna sing wit' Raaay, okay.
Anytime Louis gets a thorn from the pricker bushes.
Louis: PRICKER BUSHES GOT ME! GATOR DOWN, GATOR DOWN!! THE WALLS ARE CLOSIN' IN ON ME! IT'S SO COLD!
Ray's "-_-" Aside Glance and Ray going to pull a thorn out of Louis, causing him to scream in pain... "I ain't touched it yet."
Before Disguised!Lawrence and Charlotte's wedding, an aggravated Facilier throwing one of his cards at Lawrence.
Big Daddy's reaction to having a beignet he was about to eat snatched out of his hand by Charlotte.
A few seconds after this, when Charlotte gives Tiana enough money for the beignets to pay for the building, the look on Tiana's boss's face is absolutely priceless.
Big Daddy stuffing another beignet into Charlotte's mouth, so that he could finally put in a single word into her endless stream of chatter. This is made even better by the fact that right before this, it looks like Charlotte is going to let him talk... Then she interrupts him again, which is what causes Big Daddy to shove the beignet in her mouth.
Naveen's proposal. Even though that should count as heartwarming, it's just too hilarious to see him overdo it and just fall short of screwing up. Take a look.
Charlotte sweetly telling the fake Naveen to hurry up and finish getting ready for their wedding. . .then in a split second turning to her father and screeching at him to "START THE CAR!"
Charlotte yelling "Cheese and crackers!" when disguised Lawrence runs away with Naveen the frog after Naveen stops the wedding kiss from happening.
"Prince Naveen! Your shy and retiring bride-to-be is getting antsy!" (kicks in the door to the church)
The old firefly granny with the walker and a Clapper function on her bulb.
"What a coincidence Lawrence, I have been avoiding you everywhere!"