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Five Bad Band: Web Original
The Children of the Night, supervillain team of the Whateley Universe
The Big Bad - The Necromancer, dark mage and A-minus level supervillain
The Dragon - his pal Lycanthros, who has super-werewolf powers
The Evil Genius - while the Necromancer is the planner and brains, Nightgaunt is the smartest fighter
The Brute - the Arch-Fiend, who turns into an eight-foot tall demon
The Dark Chick - literally, since Lady Darke has the name and the dark-based powers
The Sixth Ranger Traitor - Vamp, who has been blackmailed into joining the team and isn't happy about it
Naturally, Sailor Nothing had a crack at this
Beath of Flams :
With the That Guy With The Glasses crew being Villain Protagonists in Kickassia , their roster goes somewhat like this:
With the Atop the Fourth Wall, Lord Vyce Arc:
Darwin's Soldiers has a Five-Bad Band only for the Dragonstorm scientists.
The Big Bad - Zenarchis: Founder/Leader of the Dragonstorm
The Dragon - O'Neill: A high-ranking officer within the Dragonstorm ranks, possibly second only to Zenarchis.
The Evil Genius - Hicks: He comes up with the plans and other errata but he is also a capable combatant .
The Brute - Kozlov: A hulking and violent but brilliant Russian scientist.
Dark Chick - Montgomery (despite being male): He has very little in the way of combat prowess but he has served vital roles.
Super Stories has the now-dispanded League of Shadows, once counterpart to the original Ultimate Justice Squad
Big Bad : Lord Oberon, whose leadership skills held the normally indepentend villain team together.
The Dragon : Mechan.
Evil Genius : Dr River. Mechan also has aspects of this.
The Brute : Muria, described as the "tank" of the team.
Dark Chick : Wisp.
The third season of The Guild had the Axis of Anarchy
Death Battle has a battle where Dr. Robotnik and Dr. Wily fight. The two doctors and their robots make two bands:
Dr. Robotnik's Team:
Dr. Wily's Team:
tGA has a few notable villainous groups during the Godslayer era.