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Five Bad Band:
Fu Leng and the other subsequent rulers of the Shadowlands in Legend of the Five Rings tend fall into this structure.
With the Oni Overlords:
During the Clan War story arc:
Four Winds story arc:
Bloodspeakers circa Diamond Edition:
Champions, being a superhero roleplaying game with a long history, has produced a few villain teams that more or less fit the pattern.
The original line-up of Eurostar are a fair example:
Big Bad - Fiacho, whose name actually means "very bad".
The Dragon - Bora, though she may be too flighty to do the job perfectly, maybe even being more of a Dark Chick type.
The Brute - Durak, no question.
The Evil Genius - Le Sone, the team scientist.
The Dark Chick - Pantera, the clawed psychopath (who might swap roles with Bora at times).
The scenario book features two five-member villain teams:
The Sands of Time The Iron Five fit the trope fairly well. What they don't know is that Belragor is basically using them as a .
Quirky Miniboss Squad Big Bad - Chevron, though mostly by virtue of his being the team leader.
The Dragon - Shaggy, though more by default than inclination; he's much more of a trickster.
The Brute - Shellshock.
The Evil Genius - Sharkskin, though his genius is limited to being a useful business manager and driver.
The Dark Chick - Shrapnel, in a twisted sort of way, as the team's junior member. Though he'd gut you for suggesting this.
Belragor's followers, on the other hand, avert the trope more than they fit it:
Big Bad - Belragor, definitely.
The Dragon - The Obedient One and the Unswerving Champion both want this position, and are locked in rivalry.
The Brute - The Functionary's powers put him in this slot, though he doesn't look the part, and the Obedient One has more of the mindset.
The Evil Genius - Belragor really won't let anyone else take this role, though the Vengeance Swarm might also be in contention sometimes.
The Dark Chick - Simply not a role recognised in this group. The Vengeance Swarm is the low-strength oddball character, but it wants to be The Starscream.
The World Slayers from Rifts Chaos Earth Creatures of Chaos.
The five vampiric species from Vampire: The Requiem.
The Big Bad: The Ventrue. Blue-blooded, controlling, and always in charge.
The Dragon: The Nosferatau. Disfigured, brutally fast and strong, capable of casting fear, and completely loyal to anyone who accepts them.
The Brute: The Gangrel. Animalistic, savage, frequently (though not always) stupid, with a tendency to operate as mercenaries or Psychos For Hire.
The Evil Genius: The Mekhet. Shadowy, clever, dislike direct contact, and can find out anything for a price.
The Dark Chick: The Daeva's. Decadent seducers obsessed with the finer things in life. Can become The Dragon (or more frequently, The Starscream) to the Ventrue if truly motivated.
Similarly, the five Slasher Undertakings (both Ripper and Scourge) from
Hunter: The Vigil The Big Bad: Geniuses/Maniacs or Charmers/Psychos. Really varies depending on the Slashers in question.
The Dragon: Freaks/Mutants. As in the Nosferatau example above, these guys are disfigured, strong, and extremely loyal to anyone who accepts them. May be just misunderstood, or genuinely evil, or somewhere in between.
The Brute: Brutes/ Masks. Neither is particularly smart, neither is emotional in anyway, shape or form, neither shows mercy, and both have Implacable Man as their hat. May actually be more physically dangerous than The Dragon, but much less competent.
The Evil Genius: Geniuses/Maniacs or Charmers/Psychos. As above, this will vary from Slasher to Slasher.
The Dark Chick: Avengers/Legends. The only ones with something approaching justification for their behaviour; often bound up by the rules of their own story. Generally have Jerkass Woobie as their hat.
Warhammer 40,000 armies. Granted, the setting is swimming in Black and Gray Morality. However, the classic "evil" factions fill out all the archetypes:
And the same, but for the Warhammer Fantasy setting. Though if one accepts the theory that the Horned Rat is a lesser Chaos God and removes the Orcs and Vampire Counts it can be made a lot neater, since those two have no real connection to Chaos.
Let's not forget the principal Five-Bad Band of the franchise, the Chaos Gods. Well, four. Depending on who you ask.
The Horus Heresy's principal characters:
The five Praetors of New Phyrexia (and their boss) from Magic: The Gathering: