Tsubasaki Sora (Cure Zephyre) | Voice Actor: Satomi Sato
"The wind that blows throughout the sky and land - Cure Zephyre!
- The Hero
- Expy (Of Nozomi)
- Meaningful Name ("Sora"/"Sky" - "Tsubasaki"/"Wing Bloom"
- Blow You Away
- First-Name Basis
- You Gotta Have Blue Hair
- Razor Wind
- Eleventh Hour Superpower (Northern Windy in last episode and movie)
Hideaki Inara (Cure Dawning) | Voice Actor: Saeko Chiba
"The sunlight that shines in every heart - Cure Dawning!"
"I may be extremely short, but it comes in handy. Sometimes."
- Expy (Of Urara)
- Genki Girl
- Parental Neglect (Her mom never talks to her, is constantly working.)
- Eleventh Hour Superpower (Eastern Shine in last episode and movie)
Mizuki Mina (Cure Tornado) | Voice Actor: Saki Fujita
"The waves that wash the shores of the world - Cure Tornado!"
"Sora, you are so laaaazy. I wish someone would put a permanent buzzer in your head."
- Expy (Of Rin, despite her element being water.)
- Book Dumb
- Twice Shy (With Akane)
- School Girl Lesbians (With Akane)
- Eleventh Hour Superpower (Western Wave in last episode and movie)
Haruto Akane (Cure Saharia) | Voice Actor: Kana Ueda
"The flame of the sun that burns with passion - Cure Saharia!"
"If I want to eat something, I'll eat it. If I want to say something, I'll say it. I'm the student council president. I can do what I want."
- Expy (Of Karen and Ikuko)
- Cool Big Sis
- It Is Pronounced Tro PAY (It isn't Sa-HA-ri-a. It's Sa-ri-a.)
- Playing with Fire
- Brutal Honesty (She's not afraid to say what's on her mind.)
- Even the Girls Want Her (Mina falls in love with her.)
- School Girl Lesbians (With Mina)
- Student Council President
- Eleventh Hour Superpower (Southern Flame in last episode and movie)
Hideyoshi Haruka (Cure Valterre) | Voice Actor: Kana Hanazawa
"The plant of life that grows through the world - Cure Valterre!"
"Being responsible is such a burden."
- Expy (of Komachi and Hanae)
- The Glasses Come Off (As Cure Valterre)
- Big Fancy House (Her family owns one, but she doesn't live in it. Her sisters do though.)
- The Quiet One
- Apologizes a Lot
- Eleventh Hour Superpower (Central Blossom in last episode and movie)
- Smart People Wear Glasses
Venus | Voice Actor: Rei Sakuma
"Sweets are my specialty. If you want something, chances are I'll have it on my shelves. No, I don't know why or how."
- The Mentor (Since there are no mascots, and despite her age, she fills this role.)
- Curious as a Monkey ( Her memory as Vanessa Yorkshire was completely wiped out by Aphrodite, so she knows nothing, but in the end, Vanessa decided to stay Venus.)
- Duality Motif (One eye is red from Aphrodite, one is yellow from the girl she took over.)
Hemera / Goddess Of Sun and DayOne of Aphrodite's closest friends. When Mr. Kuroro takes Aphrodite's crown, Hemera and her sister Nyx take care of Aphrodite while she lives as Venus.
Nyx / Goddess Of Moon and NightOne of Aphrodite's closest friends. When Mr. Kuroro takes Aphrodite's crown, Nyx and her sister Hemera take care of Aphrodite while she lives as Venus.
Rosalie Auburn (Rosetta) | Voice Actor: Eri Saito
"Shut up or you'll have homework. I mean it!"
- What Is This Thing You Call "Love"? (She falls in love with her co-worker, and rethinks her life.)
- Evil Is Sexy (Moreso than human)
- Heel–Face Turn (Then death)
- Eerie Pale-Skinned Brunette (As Auburn-sensei)
- Hot Teacher (She's a teacher too.)
- Redemption Equals Death (She chose her love for Akira, so Mr. Kuroro killed her.)
Marina | Voice Actor: Miki Ito
- Whip It Good (She loves to torture people. With something whip-like usually.)
Rudy | Voice Actor: Ayahi Takagaki
"This is sooooo unfair. You guys think you're all mature, but I'm the only who doesn't overreact over failure. No. I. Do. NOT!!! Stop it!"
B.T. | Voice Actor: Megumi Ogata
- Brainwashed and Crazy (He doesn't really brainwash anyone, but a lot of girls fall for him when he's around, so much that they go into a trance.)
- Sharp-Dressed Man
- Worthy Opponent
M. Quartze | Voice Actor: Daisuke Kishio
"Out of all you pitiful humans, the French have the most beauty. Not you ugly Japanese humans. You are ugly. Ugly."
- Gratuitous French (He's not french, he just like French stuff.)
Mr. Kuroro | Voice Actor: Daisuke Kirii
"Money can buy happiness. I have all the money, and I'm happy."