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The music from the fight with the giant Baby Bowser at the end of Yoshi's Island.
Big Boss battle. Just feel the tingle shoot up your spine when the rock organ kicks in at 0:29.
Sure, it might not be badass or, for some, even fit for a boss fight, but try the Mini-boss fight music.
The Room Before Boss theme. The build-up is intense.
The Map Theme. Simple, but catchy. As the player defeats more bosses, the song gradually becomes more elaborate and awesome, adding instruments like strings and drums.
This dubstep remix of the map theme counts as well.
Title Screen, which was used again when the now-grown Mario found Yoshis on another island, and given an edge of panic when he had to, in a neat little inverse, go help a bunch of multi-colored baby Yoshis return to THEIR families.
Athletic overworld theme.
And an orchestral rendition here.
Touch Fuzzy, Get Dizzy.
Underground Theme. It has a sadder mood than the other songs, used as an overworld theme for world 6.
This has to be the best remix of it ever!
The Ending Credits music.
Yoshi's Island DS
Yoshi's Island DS has even more awesome music, like this.
And then there's the temple/jungle theme...
This epic remix of the Starman theme.
Also the Credits theme.
The title screen music for the game starts off with typical beach sounds and after a while plays a soothing melody of the game's theme that plays during certain levels while giving a relaxed tropical feel.
Yoshi's New Island