In the first episode, while Fury is offering Spider-Man the chance to train with S.H.I.E.L.D., the Trapster somehow frees himself just as Spidey asks Fury how ultimate an "Ultimate Spider-Man" they're talking about is. Fury responds by casually looking over his shoulder at the fleeing Trapster, removing his plasma revolver from its holster, and firing seemingly blindly into the air. The plasma-bolt comes down and sheers through a flagpole a couple stories up, causing the pole to fall and hit Trapster on the head, knocking him out cold.
In "Great Responsibility", Spider-Man manages to rally the team behind him to fight the Frightful Four, after just declining to work with them minutes ago. White Tiger also gets one for finally giving Spidey some credit.
Spider-Man: If you wanna save someone, look down there. (gestures to the civilians below) Superhero 101, we can defend ourselves, they can't. Trust me, I've got these meatheads. Go, protect and serve. White Tiger: You heard the man! Spider-Man: She called me "the man"!
Directly following that, the team not only keeps the civilians safe, but also beats down the Frightful Four. Iron Fist especially gets one for taking down Klaw in one blow.
Klaw: You're next. Iron Fist: Now, the scream of chaos shall meet the soul of iron. KI-YAAAAAAHHHHHH! (cue Iron Fist one-shotting Klaw in a single, chi-enhanced punch so powerful, it creates a shockwave that knocks him off the roof and resonates like a sonic boom)
A villainous one for Dr. Doom. When the teen heroes decide to get some respect by attacking Latveria in order to capture him, he sent them a Doombot and let it be captured instead as a part of a Xanatos Gambit. As a result, the helicarrier is nearly destroyed, and even though Spider-Man and the others save the day, Dr. Doom was able to scan their skills, strengths, and weaknesses so he could use them against them in the future.
Made even more awesome by the fact that the heroes attacked of their own accord. Dr. Doom put his plan into motion with no warning whatsoever.
Iron Fist gets one in "Venom." Not only does he manage to evade the symbiote longer than anyone else on the team (save Spidey), but he even manages to expel it on his own. Even the way he expelled it was awesome. He punched the ground in a fit of rebellion, creating a radial shockwave that literally ripped Venom from his body! He wasn't even phased by the merging/separation process like Flash, Nova, and Luke. He just got back to his feet and rejoined the fray like it was nothing.
Spider-Man and White Tiger using their heads and beating Taskmaster by turning out the lights, and switching up their weapons so Tasky didn't know how to defend himself.
Not a huge one, but Peter intentionally failing an obstacle course set up by a new gym teacher (actually Taskmaster) just to go the extra mile in keeping his secret identity a secret. His teammates made fun of him, but Peter wasn't even in Taskmaster's top three choices to be Spider-Man.
ExclusiveBack in Black
Spider-Man vs. Venom, both in "Venom" and "Back In Black".
Venom in general: unlike other villains (except Doctor Octopus, Taskmaster, Loki, and Dr. Doom) who are treated as comical, Venom is taken more seriously and in every time he appears in an episode and very few scenes with Venom are played for humor, with Imagine Spots becoming less frequent as a result. Also every time he is defeated, it seems that symbiote is gone, but it always survives. Also his design is rather impressive.
Plus there's the rather brilliant twist that, in this series, Harry is Venom as opposed to Eddie Brock.
How does Spidey win the day in "Field Trip?" He tricks Loki, the god of mischief by hitting him the right in the ego. Loki is flat-out incredulous that he was beaten by a mortal, only for Thor himself to correct him that Spider-Man is "no mere mortal."
Iron Fist with a magical short sword. He dices a giant's club, and then throws the bggest piece back at the giant's head.
Doctor Octopus manages to fight Spidey on nearly equal terms despite never being outside of his lab. And he wins.
Spidey saving Doc Ock from drowning.
When Nightmare tries using Uncle Ben's death to bring down Spider-Man, he waves it off, and gives him one hell of a "reason you suck" speech.
Uncle Ben:(regarding Nightmare) Who's the glummy Gus? Spider-Man/Peter Parker: Mr. Pasty? He's just pathetic. Nightmare, you don't know my Uncle Ben, and you sure as heck don't know me. You think this is some buried secret? Even though I couldn't save him, I live with what happened to Uncle Ben every day, but not in the way you think. I took responsibility for this tragedy, and turned it into something special, helping people every day, as Spider-Man. Guess who taught me that magic trick? :: Cue Curb-Stomp Battle.
AwesomeFor Your Eye Only
Spidey, decked out in a full cadre of badass S.H.I.E.L.D gear, laying waste to the Zodiac forces on the Heli-carrier.
Episodes featuring The Beetle usually have more than one. To begin with, Beetle himself is a walking Moment of Awesome, which is saying something since in almost every other adaption he is a joke. But not in this series. In his very first appearance he takes down all of Team Spidey (except for Spidey himself) without them even getting a chance to fight back in less than a minute; successfully holds his own a straight-up fight with all of the team at once; and he would have succeeded in his objective if Jameson hadn't pulled the wool over everybody else's eyes. In his second appearance he would have won against Coulson and Spidey if Aunt May hadn't snuck into that jet's cockpit while he wasn't looking. In his third appearance he out-smarts Hawkeye.
Team Spidey vs. Trapster; as Nick Fury noted, the five are finally starting to work as a team.
To stop Sandman, Spider-Man orders Nova to turn him into glass. And it works. Bonus points for the team really starting to work well and smarter in this episode.
Big time bonus points for Peter reminding us all that he's a lot smarter than people give him credit for, with the plan to incapacitate Sand-Man.
Ava demonstrates her volleyball skills and beans Sam in the head with the ball.
Sam: What happened to no powers!?
Ava: I said no powers. I didn't say no skills.
Damage Control rolling in to help bring down The Wrecking Crew in "Damage".
Thor: (Discussing the fact that The Hunt is currently in the high school) I thought you could handle it.
Coulson: I'm a S.H.I.E.L.D. agent and a principal of a New York public high school. Of course I can handle it. (grabs and cocks a S.H.I.E.L.D. gun)
The above example is followed by Coulson dual-wielding rifles almost as big as he is, taking on The Hunt alone.
This trooper thought it was awesome that they were able to squeeze so many pig jokes out of that episode (Porky Pig, the Three Little Pigs, "when pigs fly", "toss around the ol' pigskin", etc.)
I Am Spider-ManThe Iron Octopus
Norman Osborn pulling a BFG out from behind his desk and open firing on the Iron-man. And then he goes on to calmly electrocute it.
Iron Doc Ock VS Iron Spider-Man.
Not a Toy
Captain America handing the entire team their rear ends. And lecturing them while he does it.
Nova can fly, is super strong, and can blast you with cosmic energy. So first, Cap tackles him out of the air. Then, when he gets charged, he deftly turns Nova's helmet backwards then steps aside letting him fly into a wall.
Iron Fist managed to get in a good fight. But he can't pin down Captain America's fighting style. When he asks which of the styles he's using, Cap replies;
Captain America: All of the above.
Captain America swiping Spider-man's gloves and web-shooters off of him mid-battle.
Captain America: And that's something I picked up in Brooklyn.
He then proceeds to use them more efficiently than Spider-man, despite never having used them before. Wolverine could barely use the thing's basic functions, if that, but Captain America masters them instantly.
Special points for Spider-man for actually lasting the longest of any of them against Cap. With and without his web shooters.
The episode starts with Spider-Man sparring with the rest of his team in a training exercise on Liberty Island. It's four-against-one, and not one of the other heroes manages to lay a finger on Spidey.
The Sinister Six. The last 5 episodes were in fact buildups to bringing in all those villains for their first rendition of the 6, and together, they push Spider-Man to his limits, and eventually require him to bring in The Team to rescue him.
Doctor Octopus gets some props for managing to keep his team mostly focused whenever they start to fray.
The whole episode was an MOA! What with The Lizard having not one but two The Dog Bites Back moments, as well as Spidey rallying his team to switch opponents. And on top of that, Peter's devotion to Curt Conners and the way he tried to save him. And last but certainly not least the Snark-to-Snark Combat between Peter and JJ, during his Epic Hail to the team. This episode is a goldmine all right!
Peter rejecting The Symbiote which turned him into Carnage, which leads to Harry becoming Venom again, and he tries to kill The Green Goblin. The fight between Harry and Norman is a MOA in itself.
It's arguably more awesome when Harry does it, because while Peter had the advantage of Harry convincing the symbiote into taking him back, Harry forced it off his body by sheer force of will.
Apparently, SHIELD has a replica of the entire Parker house on standby.Just in case.
The FrankenStark armor.
Itsy Bitsy Spider-Man
Fury vs. The Destroyer. "Get off my ship!"
Journey of the Iron Fist
Danny gaining the second Iron Fist in "Journey of the Iron Fist"
Spidey figuring out that the crown was just an illusion and saving Scorpion even though he was a huge arrogant jerk towards him and Danny counts too.
Spidey managing to beat Deadpool, Cloud Cuckoo Lander extraordinaire, in a fourth wall breaking fantasy battle.
Deadpool beating Taskmaster in a one-on-one fight, negating the latter's photographic reflexes in a manner similar to how he beat him in the comics: being random and break-dancing.
Venom Bomb has several moments, but the most amazing is Spider-man in the Iron Spider Armor facing off with Venom IN SPACE!
Not only that, but putting all the power in the forward thrusters and basically destroying most of the Symbiote, while still worrying about the Tri-Carrier self destruct and the fact that his suit is cracking!
Guardians of the Galaxy
This is a whole episode of awesome. An entire episode of Spidey and Nova fighting against an earth destroying dictator with the Guardians.
The Parent Trap
Spider-Man one on one fight with Scorpio.
Luke one on one fight with supers soldierScorpio.
Spider-Man using his intelligence to save Luke from a pit of lava.
How Spider-Man wiped the floors with Scorpio's mooks.He really showed how much he Took a Level in Badass from season one.