In chapter 26, Shiki throws a rock at Mirea's face. She doesn't even blink as a Jacky comes out of nowhere and catches it.
Chapter 38, Rio going against her father to prove she is worthy of being a hero. It looks like a losing battle but then she performs her special move "Rio De Carnival" and knocks him down. She later wakes up after the fight to remember her Dad got right back up and knocked her out but still respected her enough to let her finally be a hero.
Fatman taking out Mr. Big Horn after being knocked around for most of the fight and just thrown into the sky by countering the throw via body slamming him from above.