The Radiant Rain and The Lovey Lacey, acted as a pair of alpha bitches known as The Minnesota Home Wrecking Crew, though in a humorous twist on this trope they acted as baby faces Women's Extreme Wrestling and WSU just because their opposition was worse. They were the bad guys for most of their Ring of Honor, Full Impact Pro and SHIMMER runs. Payton Banks(the name Radiant Rain takes on when working for Bobby Roode) was also this in Victory Pro Wrestling, but was once again a baby face thanks to the object of her scorn being Jillian Hall, whose notoriously bad singing made the crowd agree with Banks.
Of team blondage, created to capitalize on the popularity of Mean Girls, Lollipop and Krissy Vaine best served in this role, Amber O'Neal being more like a Jerk Jock party girl and GeeStar being The Brute. Vaine in particular would be accused of engaging in various immoral activities for positions of power and interrupt shows in her attempts to publicly humiliate other wrestlers. Lollipop rarely appeared with Vaine, usually acting as a Suspiciously Similar Substitute when Vaine wasn't available, but could be distinguished by being more playful and less malicious or ambitious in matters that didn't involve tag team title belts.
Torrie Wilson became this for a time after she came to the Raw roster late in 2005 and expressed her jealousy toward new Diva Ashley Massaro. She and fellow bad girls, Victoria and Candice Michelle, divided their time between picking on the more sympathetic Divas and serving as henchwomen (and, presumably, mistresses) for Vince McMahon. And just to make audiences detest her more, Torrie started carrying around a cloyingly cute Maltese puppy named Chloe. Torrie eventually turned face again after Candice became The Starscream and she and Victoria beat Torrie up.
WWE Divas Michelle McCool and Layla El were vapid, brainless co-champions (the last co-champions were over-caffeinated male cheerleaders for reference). They seemed to exist only to insult every other Diva on the Smackdown roster. They started with trying to say that Mickie James◊ and Beth Phoenix◊ were fat and ugly. Eventually, they wised up and used only non-visual insults, saying that Kelly Kelly had bad body odor ("Smelly Kelly!") and just treating Rosa Mendes like dirt (although they occasionally still called The Bella Twins◊ "The Belly Twins"). Michelle was tall and blonde, fitting the traditional visual aid for this trope; Layla, by contrast, was rather short and Ambiguously Brown (Moroccan father, English mother).
AJ Lee became this after her Face–Heel Turn. She could back it up in the ring & on the mic though. The general dislike of the existing, poorly trained reality stars turned Diva's, compared to AJ who had fought her way up through the industry and who could actually wrestle, the heel turn lead to her cutting promos about the other divas that were supposed to draw heel heat but instead were cheered by the audience.
Another male example is John Morrison, aka Johnny Mundo, aka Johnny Impact. The only thing he lacks is a posse, though given the amount of time he spends telling everyone else how much less attractive, healthy, wealthy, fashionable and enlightened they are than himself, the idea of him keeping a posse would probably stretch the Willing Suspension of Disbelief to its breaking point. He's such an alpha bitch that he once traveled through time to mock his past self, Celebrity Hanger On Johnny Nitro, for not being as awesome as he was. However, on the occasion Mundo is a baby face, he is less vocal about his presumed superiority.
Dos Caras Jr became yet another male example after being unmasked as Alberto Del Rio, a towel wearing Mexican aristocrat who looks down on other Mexicans who identify with their Amerindian roots on the basis that he can trace his blood back to the monarchs of Spain, on Gringos on the basis they have no soul, on anyone not as wealthy as himself or at least not appearing to be on the basis they are peasants who need to know their place, on anyone with darker skin than himself unless they can produce papers to prove they are not illegal immigrants and on Puerto Ricans on the basis they are inferior to Mexicans. The latter was ignored as El Patron Alberto in the World Wrestling League in favor of him having his own posse known as The Gentleman's Club. He curiously tends to clash with Johnny Mundo.
The Dollhouse led by Taryn Terrell increasingly became this. Terrell supposedly started the group for the purpose of getting out of Gail Kim's shadow, but somewhere down the line their purpose became tormenting the other knockouts for the sake of it.
Progress Wrestling has Jinny, who is a fashionista that feuds with people she thinks are ugly.
Maria Kanellis herself would become this after The Kingdom split when she(and Bennett) joined TNA Wrestling in early 2016. Kanellis began to more overtly manipulate and bully other new knockouts like Allie into serving her, with intent to gather enough power to remove more established wrestlers like Gail Kim from the show while keeping someone around to look down on while getting in the ring herself as scarcely as possible.
Candy Cartwright tends to behave in such a manner, and even got her own posse in "The Cutie Pie Club", a group actually named for Kiera Hogan but who Cartwright is the unquestioned leader of through whining and bossiness. That said, Hogan is one of the few people Cartwright is usually nice too.