* In ''FanFic/KyonBigDamnHero'', Haruhi facepalms after realizing [[spoiler:that Kyon's gotten himself in trouble with the School Council by hanging Yamane Jun out of a window.]]
* ''FanFic/ImAMarvelAndImADC''
** Green Goblin's drugged antics make Spider-Man facepalm himself.
** Green Goblin manages to make ''Batman'' do this. And Green Goblin wasn't even drugged at the time!
** Green Lantern does this while Deadpool was singing to Ryan Reynolds.
* In ''Fanfic/KeepersOfTheElements'', there are quite a few moments that cause these for various characters, from bad guys to the protagonists.
* In ''A Fanfiction Carol'', Petraverd (the first ghost, in the form of a unicorn) face-hoofs whenever Smooge, after showing some sign of progress, acts like TheDitz-of-a-fangirl she still is.
* In ''Fanfic/TheBlueBlurOfTermina'', Tatl does this in response to Sonic's hesitation during his first use of the Deku Flower.
* In ''FanFic/{{Ragnarok}}'' Light does this when [[{{Tsundere}} Sayu]] meets his "new friends" while insulting all of them:
-->''Light sighed again, pressing the heels of his hands to his eyes. That migraine was assured now- damn all little sisters to the blackest pits of hell.''
* In ''Fanfic/TheElementsOfHarmonyAndTheSaviorOfWorlds'', Celestia facehoofs hard enough to cause a minor quake when she realizes [[spoiler: she forgot to tell Megan about Cadence.]]
* In chapter four of [[http://www.fanfiction.net/s/6841812/5 Twinite]], this is Sarah's reaction to her Uncle.
-->''Turning away from the 'I know I'm cool' look, I rest my head in my palms. Well, more like nearly gave myself a concussion with both my hands. Facepalm, apply directly to face.''
* ''[[http://archiveofourown.org/works/237304/chapters/363772 The Big Reveal]]'' has [[{{Series/Merlin}} Merlin and Arthur]] switch lives with their actors, Bradley and Colin.
-->'''Colin:''' Well, maybe when we get to Camelot, you should refrain from kissing Gwen. In public. Or ever.
-->'''Bradley:''' Hell. [[LoveInterest Gwen]]. What am I going to do?
-->'''Colin:''' I know. [[ComicallyMissingThePoint Usually you have to do three takes before you get the kisses right]].
-->''Bradley gave in to the urge to facepalm.''
* Happens a good amount of times in ''Fanfic/CalvinAndHobbesTheSeries'', almost always from one of the many {{Deadpan Snarker}}s of the fic.
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