!!Tiara
->Voiced by: Creator/SayuriYamauchi (Japanese), Tara Sands (English)

* CainAndAbel: With Lena, in the best friends type.
* FieryRedhead: Tiara never backs down from a challenge. Why should she? She's stronger than ''everyone''.
* HairWings: The Geil Eldo Zamath transformation gives Tiara a pair of blood-red wings that double as her hair.
** PowerGivesYouWings
** PowerMakesYourHairGrow
** PowerDyesYourHair: Her hair goes from fiery red to blood red.
* HeyItsThatVoice: Creator/SayuriYamauchi aka [[GundamWing "Lady Une"]]
* IdiotHair: Has one, although it doesn't seem to fit her personality. This may be related to the ToneShift the series went through in development. ''Shamanic Princess'' was initially planned as a standard MagicalGirl with a NaiveEverygirl heroine.
* {{Joshikousei}}: Wears a blue sailor outfit when at school,.
* MagicalGirlWarrior
* MegaTwintails: Vast, poofy not-quite-ringlet examples. It's part of what makes ''Shamanic Princess'' a great cosplay challenge series.
* MsFanservice: She exhibits a laundry list of RuleOfSexy tropes:
** Her usual outfit features CleavageWindow, MagicSkirt and ZettaiRyouiki.
** AbsoluteCleavage in her SuperMode form, which leaves little to the imagination in the first place.
** Gainaxing, though mild.
** ClothingDamage -- tasteful, but fun.
* TheScapegoat: She gracefully accepts punishment for a mistake Graham made on a mission.
* SupernaturalGoldEyes: Her SuperMode form has golden eyes with a black ring in the middle.
* {{Tsundere}}:Tiara knows who the strongest person in the room is. It's her. She doesn't ''have'' to play nice with anyone, and [[TauntButton she's not above letting them know it.]] But underneath, she just wants everyone to be happy.

!!Lena
->Voiced by: Creator/MitsukiYayoi (Japanese), Suzy Prue (English)

* BerserkButton: Give her the impression that you're betraying/abandoning your loved ones, and she'll thirst for your blood.
* BlondesAreEvil: In her SuperMode form. [[spoiler: To be fair, she was a PeoplePuppet at the time.]]
* CantCatchUp: Lena knows she will never be as powerful as Tiara, but [[AlwaysSecondBest that doesn't make it any easier to accept]].
* DefectorFromDecadence: Lena abandons her mission and sides with Kagetsu when she decides his motives are more noble than the faceless Guardian World elders.
* FashionableAsymmetry: Her SuperMode outfit.
* HeyItsThatVoice: Mitsuki [[BlueSeed "Kaede Kunikida"]] Yayoi
* LadyOfWar: She looks elegant no matter what she does. It helps that she is a strictly {{long range|Fighter}} SquishyWizard.
* LoveConfessor: Expresses her UnrequitedLove for Kagetsu in a monologue.
* MagicMusic: Lena controls her powers by playing her flute.
** MusicalAssassin
* ProperLady: Her civilian dress is modest and she's friendlier than Tiara.
* {{Stripperiffic}}: Her SuperMode outfit [[BodyPaint looks like it was painted on.]]
* RapunzelHair: [[YouGottaHaveBlueHair Bluish-green hair]] down to her knees.

!!Sara
->Voiced by: TomoSakurai (Japanese), Mary Anne Towne (English)

* ApocalypseMaiden: In the sense that Kagetsu is risking the integrity of the Guardian World on her behalf.
* [[spoiler:AscendToAHigherPlaneOfExistence: She ascended during the TimeSkip (between eps.6 and eps.1) by merging with the Throne of Yord. It makes her...[[BlueAndOrangeMorality difficult to deal with]].]]
* IllGirl: The nightgown-like dress she's always shown wearing suggests this, and episode 5 confirms that she is indeed sickly.
* IncorruptiblePurePureness: The first impression she gives is "sweet, innocent DistressedDamsel" [[spoiler:but the series {{subvert|ed}}s this as it reveals more about the Throne of Yord. If the Throne has darkness in it, then so does Sara.]]
* [[MalevolentMaskedMen Malevolent Masked Maiden]]: [[spoiler:The Throne of Yord (or Sara, or some combination of the two) switches forms at one point from a [[EldritchAbomination pile of tentacles]] to]] Sara in a black and red third eye mask.
* MysticalWaif
* SpellMyNameWithAnS: The subtitles in the CPM release render her name as both Sarah and Sara. Considering that her name is written with [[UsefulNotes/JapaneseWritingSystem kanji]], Sara would be more appropriate.

!!Kagetsu
->Voiced by: Creator/KoichiYamadera (Japanese), Creator/CrispinFreeman (English)

* AntiMagic: He is a Neutralizer - his powers nullify magic. A Neutralizer's function is keeping the Throne of Yord pacified. Dialogue implies that Neutralizers are a lower tier in the Guardian World FantasticCasteSystem than magic users like Tiara and Lena.
* AntiVillain: Or so we initially assume.
* HeyItsThatVoice: Both Koichi and Crispin also voiced Tosuga in ''GhostInTheShell''.
** They both also voiced Albedo in VideoGame/{{Xenosaga}}.
* InternalizedCategorism: He regards himself as less capable because he is a Neutralizer, but he achieves a great deal through sheer force of will.
* KnightTemplarBigBrother: Stole the Throne to save his beloved sister Sara.
* MyGreatestFailure: He blames himself for Sara's imprisonment.
* OldFlame: He and Tiara dated before he stole the Throne of Yord.
* PeekABangs
* TallDarkAndHandsome: Swarthy, dark hair, dark eyes and in a LoveTriangle.

!!Japolo
->Voiced by: RicaMatsumoto (Japanese), P.M. Lewis (English)

* BattleButler
* BigEater: He's frequently shown eating - at one point he devours an apple that's as big as he is.
* CartoonyTail: It poofs up when finds the scent of the Throne of Yord.
* ExpositionFairy: Japolo helps to explain the setting for the benefit of the audience. There is a potentially justifying implication that Japolo and Tiara [[NewMeat haven't been partners for very long]], and that's why he wants to make sure they're both on the same page.
* KillerRabbit
* TheNoseKnows: He helps Tiara locate the Throne of Yord by sense of smell.
* TalkingAnimal: ''And'' a DeadpanSnarker.
* WeaselMascot

!!Leon
->Voiced by: Creator/HiroYuki (Japanese), Alvaro J. Gonzalez (English)

* {{Bishonen}}
* BodyguardCrush: On Lena
* DarkSkinnedBlonde: In his SuperMode form.
* FacialMarkings: A mole on his forehead

!!Graham
->Voiced by: RicaMatsumoto (Japanese), Tristan Goddard (English)

* BodyguardCrush: He exists to protect Tiara, and has some...''issues'' with her boyfriend Kagetsu.
* CoolMask: A pretty unique one that covers the left half of his face vertically.
* CuteMonsterGirl: A SpearCounterpart - Graham is a cute Gothic horror monster.
* NotGoodWithRejection: Graham is not the same after his painful failure to confess his feelings to Tiara. It's not clear if he's simply being reckless or if he as a death wish, [[spoiler:but he seems relieved when Kagetsu nullifies him.]]
* RubberMan: Graham attacks by splitting his arms into tentacles.
* {{Yandere}}: Clearly loves and wants to protect Tiara, and will kill anyone he sees as a threat.

!!The Throne of Yord
->Voiced by: RokuroNaya (Japanese), Tristan Goddard (English)

* [[spoiler: EldritchAbomination]]
* [[spoiler: GeniusLoci]]
* MacGuffin
* PortalPicture
* [[spoiler: ShapeshifterGuiltTrip]]
* SpookyPainting

!!Apolline Faria, Mimi Joyman and Susanna White
->Voiced by: Tomoko Maruo, Creator/YukaImai, Akiko Nakagawa (Japanese), Wendy Walker (Apolline), Creator/RachaelLillis (Mimi and Susanna) (English)

* HairDecorations: Susanna uses a headband.
* {{Meganekko}}: Apolline
* {{Muggle}}
* OrdinaryHighSchoolStudent
* [[ThoseTwoGuys Those Three Girls]]
* {{Tomboy}}: To a degree, Apolline. She has a deeper voice, short hair, seems to be somewhat more down to Earth than Susanna and Mimi...