!The Angels

!!Sabrina Duncan
-> Played by Kate Jackson

!!Jill Munroe
-> Played by Farrah Fawcett

!!Kelly Garrett
-> Played by Jaclyn Smith

!!Kris Munroe
-> Played by Cheryl Ladd

!!Tiffany Welles
-> Played by Shelley Hack

!!Julie Rogers
-> Played by Tanya Roberts

!!Natalie Cook
-> Played by CameronDiaz

* ActionGirl
* Adorkable
* BadassAdorable
* CuteClumsyGirl
* TheCutie
* DrivesLikeCrazy
* EveryoneLovesBlondes
* FriendToAllLivingThings: Is seen helping a cow give birth, and knows quite a bit about bird cries.
* GeekyTurnOn: We see her wake up wearing Spider-Man underoos.
* GeniusDitz
* GenkiGirl
* HairOfGoldHeartOfGold
* ThePollyanna
* RunningGag: Her dancing skills.

!!Dylan Sanders / [[spoiler: Helen Zass]]
-> Played by Creator/DrewBarrymore

* ActionGirl
* AllGirlsWantBadBoys: The other girls get GenreSavvy about this in the sequels, and lampshades it.
* DeadpanSnarker: Shares the duty with Alex.
* FieryRedhead
* TheLadette
* RedHeadedHero
* SignificantGreenEyedRedhead
* {{Tomboy}}
* TomboyishName
* UnfortunateNames: [[spoiler:Her birth name is Helen Zass.]]

!!Alex Munday
-> Played by Creator/LucyLiu

* TheAce
* ActionGirl
* AloofDarkHairedGirl
* DeadpanSnarker: Along with Dylan.
* DragonLady: Some of her disguises.
* LadyOfWar
* LethalChef
* TomboyishName

!Villains

!!Madison Lee

* AGodAmI
* AloofDarkHairedGirl
* BigBad: Of the second film.
* DarkActionGirl
* DeadpanSnarker
* FaceHeelTurn
* FallenHero
* GangstaStyle: With a [[BlingBlingBang gold-plated]] [[RareGuns Desert Eagle]] [[HandCannon .50 Action Express]].
* GoingFurASwim: Wore a bikini and full length sable coat.
* GunsAkimbo: With ''two'' [[BlingBlingBang gold-plated]] [[RareGuns Desert Eagle]] [[HandCannon .50 Action Express]].
* LawOfInverseRecoil: With any number of [[BlingBlingBang gold-plated]] [[RareGuns Desert Eagle]] [[HandCannon .50]] [[OverlyLongGag Action Express]].
* MsFanservice
* {{Satan}}: Her backstory is clearly an allegory of the story of Satan. Fallen angel? Get it? Hence why she's often depicted against fiery backgrounds and [[spoiler: dies falling into [[KillItWithFire fiery pit]].]] "[[IncrediblyLamePun She is so fired!]]"
---> "Why be an Angel when I can play God?"
* [[HeWhoMustNotBeSeen She Who Must Not Be Seen]]: Starts off this way.
* TwoFirstNames
* WomanInBlack

!!The Thin Man

* AntiHero: In the second movie.
* TheDandy
* TheDragon: To [[spoiler:Knox]].
* BadassInANiceSuit
* EeriePaleSkinnedBrunette
* {{Fetish}}: The Thin Man has one for hair.
* HeelFaceTurn
* LeanAndMean
* NoNameGiven: The Thin Man is only ever referred to as this (either that, or "Creepy Thin Man") for the first movie - the second movie, however, reveals that his real name is [[spoiler: Anthony (his surname is not given, however)]].
* RedemptionEqualsDeath
* SharpDressedMan
* TheSpeechless
* WouldHitAGirl

!!Seamus O'Grady

* TheDragon: To [[spoiler:Madison.]]
* PsychoExBoyfriend
* TattooedCrook
* WouldHitAGirl

!Others

!!Charlie

* BigGood
* CharacterTitle
* AFatherToHisMen
* HeWhoMustNotBeSeen
* MagneticHero
* MysteriousEmployer
* OnlyOneName
* RetiredBadass: Former special forces.
* TheVoice

!!Bosley
->The first Bosley played by Bill Murray, and the second by Bernie Mac in the sequel.

* CampStraight
* MyFriendsAndZoidberg: How Bosley is treated.
* NonActionGuy
* NumberTwo: To Charlie.
* PluckyComicRelief
* SuspiciouslySimilarSubstitute: [[SubvertedTrope Except]] not really. The Bosley in the sequel is his adoptive brother.

!!Eric Knox
->Played by Sam Rockwell

* {{Adorkable}}: Eric Knox is a "warm, fuzzy" kind of guy. [[spoiler: It's all an act.]]
* BigBad: Of the first film.
* BitchInSheepsClothing
* BlondGuysAreEvil
* TheChessmaster: [[spoiler:His kidnapping is a set-up.]]
* FauxAffablyEvil
* YouKilledMyFather: [[spoiler:His motive to kill Charlie, but he's wrong.]]
* WouldHitAGirl