* Al Pacino utterly discombobulating Creator/HankAzaria's character (and Hank Azaria himself, as [[ThrowItIn this was an ad-lib]]) with:
--> '''Vincent''': 'Cause she's got a...GREAT ASS!! And you've got your head ''all the way up it!''
* The famous coffee scene. Not only is it a Crowning Moment for the movie and cinema in a meta sense (as it's the first time Creator/AlPacino and Creator/RobertDeNiro ever shared the screen in the same scene in a movie), but also for the characters in the movie; in a film which isn't without its bombastic and grand moments of awesome, it's strangely fitting that its most compelling moment should be a simple, quiet scene where two protagonists share a coffee, have a pleasant conversation and discovering that, despite the fact that they work on polar opposite sides of the law, they're [[NotSoDifferent two similar guys]] [[WorthyOpponent who actually kind of like each other]].
** In real life, people hunted down the eatery just to sit in that booth until it closed in 2014.
* The [[http://www.youtube.com/watch?v=ICOZ9UnvH5E bank robbery sequence]]. The most believable, most intense cops-and-robbers shootout committed to film. When a ''real'' bank robbery in L.A. [[http://en.wikipedia.org/wiki/North_Hollywood_shootout happened a few years later]], nearby citizenry thought someone was filming a ''Heat'' sequel.
** What really sold the sequence was the audio, which sounds like no other cinematic gunfight. None of the gunshots were added in post. Instead, the sound was captured live during filming with carefully placed microphones.
** The level of training and realism is so impressive that [[http://imgur.com/gallery/n0zDj3t Chris' mid-firefight reload]] is often shown to ''United States Marines'' as an example of a flawless tactical reload.
*** Not surprising, considering that Creator/MichaelMann consistently uses former Special Forces operatives like [[http://mickgould.net/about-mick/ Mick Gould]] as instructors on his movies.
* The armored car robbery is also just as much as CrowningMomentOfAwesome as it is an EstablishingCharacterMoment for each member of the crew.
* Neil [[spoiler: killing Van Zant and Waingro]] especially how horrible they were.
* Neil's threat to Van Zant is a BadassBoast delivered about as emotionlessly as possible; "I'm talking to an empty phone... because there is a dead man on the other end of this line." (MicDrop)